Effect of an In-Plane Ligand on the Electronic Structures of Bromo-Bridged Nano-Wire Ni−Pd Mixed-Metal Complexes, [Ni1−xPdx(bn)2Br]Br2(bn = 2S,3S-Diaminobutane)

2009 ◽  
Vol 48 (15) ◽  
pp. 7446-7451 ◽  
Author(s):  
Mari Sasaki ◽  
Hashen Wu ◽  
Daisuke Kawakami ◽  
Shinya Takaishi ◽  
Takashi Kajiwara ◽  
...  
1988 ◽  
Vol 43 (8) ◽  
pp. 927-932 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Michael Gaß ◽  
Ulf Zucha ◽  
Brigitte Eisenmann

AbstractSeveral fortuitous preparations and high yield rational syntheses for [(Me3P)2M(PMe2)]: (1: M = Co; 2: M = Ni) are described. 1 crystallizes in the space group P1̄ (no. 2); a = 975.6(5). b = 943.6(5), c - 904.2(5) pm. α= 63.8(1)°, β = 79.1(1)°, γ = 72.8(1)°. Mixed metal complexes L2Co(PR2)2NiL2 (L = PMe3; R = Me, Ph) evaded detection giving symmetric products exclusively. An improved synthesis of LiP(C6H5)2·dioxane is also described.


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