Novel Bispidine Ligands and Their First-Row Transition Metal Complexes: Trigonal Bipyramidal and Trigonal Prismatic Geometries

2009 ◽  
Vol 48 (14) ◽  
pp. 6604-6614 ◽  
Author(s):  
Peter Comba ◽  
Christina Haaf ◽  
Hubert Wadepohl
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Trigonal Bipyramidal ◽  
Trigonal Prismatic

scholarly journals Co-ordination behaviour of a novel tristhiourea tripodal ligand; structural variations in a series of transition metal complexes

2016 ◽  
Vol 45 (25) ◽  
pp. 10280-10288 ◽  
Author(s):  
Fawaz A. Saad ◽  
James C. Knight ◽  
Benson M. Kariuki ◽  
Angelo J. Amoroso
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Structural Variations ◽  
Tripodal Ligand ◽  
Trigonal Bipyramidal ◽  
Hydrogen Bond Donors

On coordination, L1 may form a symmetrical array of hydrogen bond donors, suitable for the binding of anions. Mn(ii) and Cd(ii), form symmetrical monocapped octahedral complexes. However Zn(ii) and Ni(ii) favours asymmetric trigonal bipyramidal and octahedral structures respectively.

Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy

2017 ◽  
Vol 56 (12) ◽  
pp. 6943-6951 ◽  
Author(s):  
Alexander A. Pavlov ◽  
Svetlana A. Savkina ◽  
Alexander S. Belov ◽  
Yulia V. Nelyubina ◽  
Nikolay N. Efimov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Trigonal Prismatic

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Density Functional Calculations of EPR Parameter g Tensors of Some Transition Metal Complexes

2011 ◽  
Vol 2 (2) ◽  
pp. 139-141
Author(s):  
Vinita Prajapati ◽  
◽  
P.L.Verma P.L.Verma ◽  
Dhirendra Prajapati ◽  
B.K.Gupta B.K.Gupta
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional Calculations ◽  
Density Functional

Synthesis, Characterization and in vitro Biological Evaluation of a New Schiff Base Derived from Drug and its Complexes with Transition Metal Ions

2018 ◽  
Vol 69 (7) ◽  
pp. 1678-1681
Author(s):  
Amina Mumtaz ◽  
Tariq Mahmud ◽  
M. R. J. Elsegood ◽  
G. W. Weaver
Keyword(s):  
Schiff Base ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Free Ligand ◽  
Transition Metal Ions ◽  
Biological Evaluation ◽  
Pyridoxal Hydrochloride

New series of copper (II), cobalt (II), zinc (II), nickel (II), manganese (II), iron (II) complexes of a novel Schiff base were prepared by the condensation of sulphadizine and pyridoxal hydrochloride. The ligand and metal complexes were characterized by utilizing different instrumental procedures like microanalysis, thermogravimetric examination and spectroscopy. The integrated ligand and transition metal complexes were screened against various bacteria and fungus. The studies demonstrated the enhanced activity of metal complexes against reported microbes when compared with free ligand.

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