Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands

2009 ◽  
Vol 48 (13) ◽  
pp. 6251-6260 ◽  
Author(s):  
Bennett P. Greenwood ◽  
Scott I. Forman ◽  
Gerard T. Rowe ◽  
Chun-Hsing Chen ◽  
Bruce M. Foxman ◽  
...  
Keyword(s):  
Redox Activity ◽  
Metal Interactions ◽  
Metal Metal ◽  
Early Late

Electronic Factors Affecting Metal−Metal Interactions in Early/Late Heterobimetallics: Substituent Effects in Zirconium/Platinum Bis(phosphinoamide) Complexes†

2010 ◽  
Vol 29 (21) ◽  
pp. 5179-5186 ◽  
Author(s):  
Benjamin G. Cooper ◽  
Claudia M. Fafard ◽  
Bruce M. Foxman ◽  
Christine M. Thomas
Keyword(s):  
Substituent Effects ◽  
Factors Affecting ◽  
Metal Interactions ◽  
Metal Metal ◽  
Early Late

Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)

2012 ◽  
Vol 41 (26) ◽  
pp. 8111 ◽  
Author(s):  
Deirdra A. Evers ◽  
Alia H. Bluestein ◽  
Bruce M. Foxman ◽  
Christine M. Thomas
Keyword(s):  
Metal Interactions ◽  
Heterobimetallic Complexes ◽  
Metal Metal ◽  
Group 5 ◽  
Early Late

scholarly journals Heterobimetallic lanthanide‐coinage metal compounds featuring possible metal‐metal interactions in the exited state

2021 ◽  
Author(s):  
Peter Werner Roesky ◽  
Milena Dahlen ◽  
Niklas Reinfandt ◽  
Chengyu Jin ◽  
Michael T. Gamer ◽  
...  
Keyword(s):  
Metal Compounds ◽  
Coinage Metal ◽  
Metal Interactions ◽  
Metal Metal

Tuning metal–metal interactions for cooperative small molecule activation

2021 ◽  
Author(s):  
Qiuran Wang ◽  
Sam H. Brooks ◽  
Tianchang Liu ◽  
Neil C. Tomson
Keyword(s):  
Small Molecule ◽  
Small Molecule Activation ◽  
Feature Article ◽  
Metal Interactions ◽  
Recent Advances ◽  
Metal Metal

This Feature Article describes recent advances in the design of multinucleating ligands that support small molecule activation chemistry.

scholarly journals Effect of Metal−Metal Interactions on Electron Transfer:  an STM Study of One-Dimensional Metal String Complexes

2004 ◽  
Vol 108 (3) ◽  
pp. 959-964 ◽  
Author(s):  
Shu-Yi Lin ◽  
I-Wen Peter Chen ◽  
Chun-hsien Chen ◽  
Ming-Hsun Hsieh ◽  
Chen-Yu Yeh ◽  
...  
Keyword(s):  
Electron Transfer ◽  
One Dimensional ◽  
Metal Interactions ◽  
Metal Metal

Metal-Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands

2016 ◽  
Vol 128 (7) ◽  
pp. 2452-2456 ◽  
Author(s):  
Daniël L. J. Broere ◽  
Dieuwertje K. Modder ◽  
Eva Blokker ◽  
Maxime A. Siegler ◽  
Jarl Ivar van der Vlugt
Keyword(s):  
Redox Active Ligands ◽  
Metal Interactions ◽  
Heterobimetallic Complexes ◽  
Redox Active ◽  
Metal Metal

Mixed Metal Oxide Interfaces: An Experimental and Theoretical Assessment of Secondary Metal Influences in Metal Impregnated Aluminas

1994 ◽  
Vol 368 ◽  
Author(s):  
M. Malaty ◽  
D. Singh ◽  
R. Schaeffer ◽  
S. Jansen ◽  
S. Lawrence
Keyword(s):  
Photoelectron Spectroscopy ◽  
Theoretical Calculations ◽  
Mixed Metal Oxide ◽  
X Ray Diffraction ◽  
Paramagnetic Resonance ◽  
X Ray ◽  
Mixed Metal ◽  
Metal Interactions ◽  
Metal Metal ◽  
Bimetallic System

ABSTRACTStudies of the mixed-metal interface in metal impregnated alumina have indicated the possibility of much metal-metal and metal-substrate interaction. Studies were carried out on NiCu/Al2O3 system which was evaluated to develop a better understanding of the forces that drive modification of the catalytic selectivity of Ni in the presence of Cu. Electron Paramagnetic Resonance (EPR), Powder X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction (XRD) and theoretical calculations were carried out on this bimetallic system, using Ni,Ag/Al2O3 as a reference as Ni shows negligible electron perturbation on co-adsorbance with Ag onto alumina. XRD results indicate that gross modification of the electronic fields of Ni and Cu are due to direct coupling and intercalation into the alumina matrix. As a result of this phenomena, these materials may form a good base for the development of novel ceramics based on mixed-metal interactions where the intermetallic perturbations are driven by the substrate effects.

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