Volatility, High Thermal Stability, and Low Melting Points in Heavier Alkaline Earth Metal Complexes Containing Tris(pyrazolyl)borate Ligands

2009 ◽  
Vol 48 (12) ◽  
pp. 5303-5312 ◽  
Author(s):  
Mark J. Saly ◽  
Mary Jane Heeg ◽  
Charles H. Winter
Keyword(s):  
Thermal Stability ◽  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
High Thermal Stability ◽  
Alkaline Earth Metal ◽  
Melting Points

C–H and C–F coordination of arenes in neutral alkaline earth metal complexes

2021 ◽  
Author(s):  
Jacob S. McMullen ◽  
Alison J. Edwards ◽  
Jamie Hicks
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Calcium Complexes ◽  
Group 2 ◽  
Rare Group

A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feaure rare group 2 metal···aromatic...

Alkali and alkaline-earth metal complexes of different nuclearities with azamacrocyclic pendant-arms ligands

2009 ◽  
Vol 362 (9) ◽  
pp. 3351-3356 ◽  
Author(s):  
Luis Botana ◽  
Rufina Bastida ◽  
Alejandro Macías ◽  
Paulo Pérez-Lourido ◽  
Laura Valencia
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Pendant Arms

Highly Lewis acidic cationic alkaline earth metal complexes

2018 ◽  
Vol 54 (63) ◽  
pp. 8685-8688 ◽  
Author(s):  
Jürgen Pahl ◽  
Steffen Brand ◽  
Holger Elsen ◽  
Sjoerd Harder
Keyword(s):  
Metal Complexes ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal

“Naked” cationic β-diketiminate Mg and Ca complexes possess high Lewis acidities and bind strongly to neutral benzene or alkyne ligands.

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