Spin Frustration and Long-Range Ordering in an AlB2-like Metal-Organic Framework with Unprecedented N,N,N-Tris-tetrazol-5-yl-amine Ligand

2009 ◽  
Vol 48 (10) ◽  
pp. 4536-4541 ◽  
Author(s):  
Xian-Ming Zhang ◽  
Tao Jiang ◽  
Hai-Shun Wu ◽  
Ming-Hua Zeng
2019 ◽  
Vol 55 (17) ◽  
pp. 2521-2524 ◽  
Author(s):  
Jiayan Zhang ◽  
Louis Longley ◽  
Hao Liu ◽  
Christopher W. Ashling ◽  
Philip A. Chater ◽  
...  

A pronounced enthalpy release occurs around 1.38Tg in the prototypical metal–organic framework glass formed from ZIF-4 [Zn(C3H3N2)2], but there is no sign for any crystallization (i.e., long-range ordering) taking place.


2020 ◽  
Vol 11 (21) ◽  
pp. 9045-9050
Author(s):  
Qi Sun ◽  
Zixi Yin ◽  
Shiping Wang ◽  
Chunyi Zhao ◽  
Jing Leng ◽  
...  

2017 ◽  
Vol 19 (43) ◽  
pp. 29084-29091
Author(s):  
J. Alberto Rodríguez-Velamazán ◽  
Olivier Roubeau ◽  
Roberta Poloni ◽  
Elsa Lhotel ◽  
Elías Palacios ◽  
...  

Long-range magnetic ordering is demonstrated in {Ni(pyrazine)[Pt(CN)4]}, which opens new perspectives for multifunctionality in this class of porous coordination compounds.


2015 ◽  
Vol 51 (22) ◽  
pp. 4627-4630 ◽  
Author(s):  
Jiong-Peng Zhao ◽  
Song-De Han ◽  
Xue Jiang ◽  
Jian Xu ◽  
Ze Chang ◽  
...  

A 3D magnetically frustrated MOF was successfully constructed from the augmentation on the vertices of a simple 3-connected underlying net. This MOF features a unique interpenetrating geometric spin frustration framework.


2017 ◽  
Vol 46 (38) ◽  
pp. 12771-12774 ◽  
Author(s):  
Jun-Li Wang ◽  
Yan Bai ◽  
Hui Pan ◽  
Guang-Shui Zheng ◽  
Dong-Bin Dang

A beautiful 3D nickel(ii)–organic framework possessing one type of rare polyhedral cage has been synthesized based on H3BTC and bpp ligands. Long-range magnetic ordering is observed in the framework.


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