Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3= (S)P[N(Me)NCH−C6H3-2-OH-3-OMe]3]: A 3d−4f Family of Single-Molecule Magnets

2009 ◽  
Vol 48 (3) ◽  
pp. 1148-1157 ◽  
Author(s):  
Vadapalli Chandrasekhar ◽  
Balasubramanian Murugesa Pandian ◽  
Jagadese J. Vittal ◽  
Rodolphe Clérac
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnets ◽  
Trinuclear Complexes

Strictly linear trinuclear Dy–Ca/Mg–Dy single-molecule magnets: the impact of long-range f–f ferromagnetic interactions on suppressing quantum tunnelling of magnetization leading to slow magnetic relaxation

2017 ◽  
Vol 46 (25) ◽  
pp. 8259-8268 ◽  
Author(s):  
Wan-Ying Zhang ◽  
Yong-Mei Tian ◽  
Hong-Feng Li ◽  
Peng Chen ◽  
Yi-Quan Zhang ◽  
...  
Keyword(s):  
Long Range ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Single Molecule Magnets ◽  
Quantum Tunnelling ◽  
Trinuclear Complexes ◽  
Slow Magnetic Relaxation ◽  
Ferromagnetic Interactions ◽  
The Impact

A series of linear trinuclear complexes Ln2M(OQ)8 [Ln(iii) = Dy and Er, M(ii) = Ca and Mg] were structurally and magnetically investigated.

Slow magnetic relaxation of light lanthanide-based linear LnZn2 trinuclear complexes

2015 ◽  
Vol 44 (41) ◽  
pp. 18276-18283 ◽  
Author(s):  
Chika Takehara ◽  
Poh Ling Then ◽  
Yumiko Kataoka ◽  
Motohiro Nakano ◽  
Tomoo Yamamura ◽  
...  
Keyword(s):  
Single Molecule ◽  
Magnetic Relaxation ◽  
Lanthanide Ions ◽  
Single Molecule Magnets ◽  
Trinuclear Complexes ◽  
Light Lanthanide ◽  
Slow Magnetic Relaxation

Four isostructural Zn(ii)–Ln(iii)–Zn(ii) trinuclear complexes were synthesized using light lanthanide ions as magnetic centers, of which Ce(iii) and Nd(iii) complexes behaved as single-molecule magnets.

scholarly journals Trinuclear Complexes Derived fromR/SSchiff Bases - Chiral Single-Molecule Magnets

2016 ◽  
Vol 2017 (6) ◽  
pp. 991-998 ◽  
Author(s):  
Albert Escuer ◽  
Julia Mayans ◽  
Merce Font-Bardia ◽  
Lorenzo Di Bari ◽  
Marcin Górecki
Keyword(s):  
Single Molecule ◽  
Single Molecule Magnets ◽  
Trinuclear Complexes

scholarly journals Front Cover: Trinuclear Complexes Derived from R/S Schiff Bases - Chiral Single-Molecule Magnets (Eur. J. Inorg. Chem. 6/2017)

2017 ◽  
Vol 2017 (6) ◽  
pp. 989-989
Author(s):  
Albert Escuer ◽  
Julia Mayans ◽  
Merce Font-Bardia ◽  
Lorenzo Di Bari ◽  
Marcin Górecki
Keyword(s):  
Schiff Bases ◽  
Single Molecule ◽  
Single Molecule Magnets ◽  
Front Cover ◽  
Trinuclear Complexes

scholarly journals Cadmium-Inspired Self-Polymerization of {LnIIICd2} Units: Structure, Magnetic and Photoluminescent Properties of Novel Trimethylacetate 1D-Polymers (Ln = Sm, Eu, Tb, Dy, Ho, Er, Yb)

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4296
Author(s):  
Maxim A. Shmelev ◽  
Ruslan A. Polunin ◽  
Natalia V. Gogoleva ◽  
Igor S. Evstifeev ◽  
Pavel N. Vasilyev ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Luminescence Decay ◽  
Decay Kinetics ◽  
Single Molecule Magnets ◽  
Excitation Spectra ◽  
Magnetization Relaxation ◽  
Trinuclear Complexes ◽  
Applied External Magnetic Field ◽  
Luminescence Decay Kinetics

A series of heterometallic carboxylate 1D polymers of the general formula [LnIIICd2(piv)7(H2O)2]n·nMeCN (LnIII = Sm (1), Eu (2), Tb (3), Dy (4), Ho (5), Er (6), Yb (7); piv = anion of trimethylacetic acid) was synthesized and structurally characterized. The use of CdII instead of ZnII under similar synthetic conditions resulted in the formation of 1D polymers, in contrast to molecular trinuclear complexes with LnIIIZn2 cores. All complexes 1–7 are isostructural. The luminescent emission and excitation spectra for 2–4 have been studied, the luminescence decay kinetics for 2 and 3 was measured. Magnetic properties of the complexes 3–5 and 7 have been studied; 4 and 7 exhibited the properties of field-induced single-molecule magnets in an applied external magnetic field. Magnetic properties of 4 and 7 were modelled using results of SA-CASSCF/SO-RASSI calculations and SINGLE_ANISO procedure. Based on the analysis of the magnetization relaxation and the results of ab initio calculations, it was found that relaxation in 4 predominantly occurred by the sum of the Raman and QTM mechanisms, and by the sum of the direct and Raman mechanisms in the case of 7.

scholarly journals Trinuclear Complexes Derived from R/S Schiff Bases - Chiral Single-Molecule Magnets

2017 ◽  
Vol 2017 (6) ◽  
pp. 990-990
Author(s):  
Albert Escuer ◽  
Julia Mayans ◽  
Merce Font-Bardia ◽  
Lorenzo Di Bari ◽  
Marcin Górecki
Keyword(s):  
Schiff Bases ◽  
Single Molecule ◽  
Single Molecule Magnets ◽  
Trinuclear Complexes

Seeking Magneto-Structural Correlations in Easily Tailored Pentagonal Bipyramid Dy(III) Single-Ion Magnets

2019 ◽  
Author(s):  
Guo-Zhang Huang ◽  
Ze-Yu Ruan ◽  
Jie-Yu Zheng ◽  
Yan-Cong Chen ◽  
Si-Guo Wu ◽  
...  
Keyword(s):  
Single Molecule ◽  
Structural Engineering ◽  
Magnetic Hysteresis ◽  
Sweep Rate ◽  
Coordination Bond ◽  
Pentagonal Bipyramid ◽  
Single Molecule Magnets ◽  
Crystal Field Theory ◽  
Bond Angles ◽  
Axial Coordination

<p><a></a>Controlling molecular magnetic anisotropy via structural engineering is delicate and fascinating, especially for single-molecule magnets (SMMs). Herein a family of dysprosium single-ion magnets (SIMs) sitting in pentagonal bipyramid geometry have been synthesized with the variable-size terminal ligands and counter anions, through which the subtle coordination geometry of Dy(III) can be finely tuned based on the size effect. The effective energy barrier (Ueff) successfully increases from 439 K to 632 K and the magnetic hysteresis temperature (under a 200 Oe/s sweep rate) raises from 11 K to 24 K. Based on the crystal-field theory, a semi-quantitative magneto-structural correlation deducing experimentally for the first time is revealed that the Ueff is linearly proportional to the structural-related value S2<sup>0</sup> corresponding to the axial coordination bond lengths and the bond angles. Through the evaluation of the remanent magnetization from hysteresis, quantum tunneling of magnetization (QTM) is found to exhibit negative correlation with the structural-related value S<sub>tun</sub> corresponding to the axial coordination bond angles.<br></p>

Correlating Blocking Temperatures in Single Molecule Magnets with Raman Relaxation

2018 ◽  
Author(s):  
Marcus J. Giansiracusa ◽  
Andreas Kostopoulos ◽  
George F. S. Whitehead ◽  
David Collison ◽  
Floriana Tuna ◽  
...  
Keyword(s):  
Relaxation Time ◽  
Single Molecule ◽  
Energy Barrier ◽  
Thermal Relaxation ◽  
Relaxation Mechanism ◽  
Blocking Temperature ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Key Parameter

We report a six coordinate DyIII single-molecule magnet<br>(SMM) with an energy barrier of 1110 K for thermal relaxation of<br>magnetization. The sample shows no retention of magnetization<br>even at 2 K and this led us to find a good correlation between the<br>blocking temperature and the Raman relaxation regime for SMMs.<br>The key parameter is the relaxation time (𝜏<sub>switch</sub>) at the point where<br>the Raman relaxation mechanism becomes more important than<br>Orbach.

A Combined Spin-Flip and IP/EA Approach for Handling Spin and Spatial Degeneracies: Application to Double Exchange Systems

2018 ◽  
Author(s):  
Shannon Houck ◽  
Nicholas Mayhall
Keyword(s):  
Single Molecule ◽  
Double Exchange ◽  
Computational Effort ◽  
Strongly Correlated ◽  
Single Molecule Magnets ◽  
New Approach ◽  
Spin Flip ◽  
Model Hamiltonian ◽  
Simultaneous Existence ◽  
Exchange Parameters

<div>Many multiconfigurational systems, such as single-molecule magnets, are difficult to study using traditional computational methods due to the simultaneous existence of both spin and spatial degeneracies. In this work, a new approach termed n-spin-flip Ionization Potential/Electron Affinity (<i>n</i>SF-IP or <i>n</i>SF-EA) is introduced which combines the spin-flip method of Anna Krylov with particle-number changing IP/EA methods. We demonstrate the efficacy of the approach by applying it to the strongly-correlated N<sub>2</sub><sup>+</sup> as well as several double exchange systems. We also demonstrate that when these systems are well-described by a double exchange model Hamiltonian, only 1SF-IP/EA is required to extract the double exchange parameters and accurately predict energies for the low-spin states. This significantly reduces the computational effort for studying such systems. The effects of including additional excitations (using a RAS-<i>n</i>SF-IP/EA scheme) are also examined, with particular emphasis on hole and particle excitations.</div>

A Combined Spin-Flip and IP/EA Approach for Handling Spin and Spatial Degeneracies: Application to Double Exchange Systems

2018 ◽  
Author(s):  
Shannon Houck ◽  
Nicholas Mayhall
Keyword(s):  
Single Molecule ◽  
Double Exchange ◽  
Computational Effort ◽  
Strongly Correlated ◽  
Single Molecule Magnets ◽  
New Approach ◽  
Spin Flip ◽  
Model Hamiltonian ◽  
Simultaneous Existence ◽  
Exchange Parameters

<div>Many multiconfigurational systems, such as single-molecule magnets, are difficult to study using traditional computational methods due to the simultaneous existence of both spin and spatial degeneracies. In this work, a new approach termed n-spin-flip Ionization Potential/Electron Affinity (<i>n</i>SF-IP or <i>n</i>SF-EA) is introduced which combines the spin-flip method of Anna Krylov with particle-number changing IP/EA methods. We demonstrate the efficacy of the approach by applying it to the strongly-correlated N<sub>2</sub><sup>+</sup> as well as several double exchange systems. We also demonstrate that when these systems are well-described by a double exchange model Hamiltonian, only 1SF-IP/EA is required to extract the double exchange parameters and accurately predict energies for the low-spin states. This significantly reduces the computational effort for studying such systems. The effects of including additional excitations (using a RAS-<i>n</i>SF-IP/EA scheme) are also examined, with particular emphasis on hole and particle excitations.</div>

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