Homogeneous Catalytic Dehydrogenation/Dehydrocoupling of Amine-Borane Adducts by the Rh(I) Wilkinson’s Complex Analogue RhCl(PHCy2)3(Cy = cyclohexyl)

2009 ◽  
Vol 48 (6) ◽  
pp. 2429-2435 ◽  
Author(s):  
Matthew E. Sloan ◽  
Timothy J. Clark ◽  
Ian Manners
Keyword(s):  
Catalytic Dehydrogenation ◽  
Complex Analogue

Pt@Cu/C Core-Shell Catalysts for Hydrogen Production Through Catalytic Dehydrogenation of Decalin

2016 ◽  
Vol 26 (1) ◽  
pp. 17-21
Author(s):  
Ji Yeon Kang ◽  
Gihoon Lee ◽  
Yeojin Jeong ◽  
Hyon Bin Na ◽  
Ji Chul Jung
Keyword(s):  
Hydrogen Production ◽  
Core Shell ◽  
Catalytic Dehydrogenation

scholarly journals Thermodynamic and Kinetic Considerations Regarding the Prospects for a Dual-Purpose Hydrogen Extraction and Separation Membrane

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2136
Author(s):  
Karl Sohlberg
Keyword(s):  
Hydrogen Production ◽  
Hydrogen Abstraction ◽  
Hydrogen Gas ◽  
Catalytic Dehydrogenation ◽  
Dual Purpose ◽  
Physical Separation ◽  
Extraction And Separation ◽  
Separation Membrane ◽  
Hydrocarbon Sources ◽  
Critical Materials

Extraction of hydrogen from hydrocarbons is a logical intermediate-term solution for the escalating worldwide demand for hydrogen. This work explores the possibility of using a single membrane to accomplish both the catalytic dehydrogenation and physical separation of hydrogen gas as a possible way to improve the efficiency of hydrogen production from hydrocarbon sources. The present analysis shows that regions of pressure/temperature space exist for which the overall process is thermodynamically spontaneous (ΔG < 0). Each step in the process is based on known physics. The rate of hydrogen production is likely to be controlled by the barrier to hydrogen abstraction, with the density of H-binding sites also playing a role. A critical materials issue will be the strength of the oxide/metal interface.

Catalytic dehydrogenation of amines to imines and the in-situ reduction of sulfoxides into sulfides

2021 ◽  
Author(s):  
Xixi Liu ◽  
Yanxin Wang ◽  
Bo Li ◽  
Bing Liu ◽  
Wei Wang ◽  
...  
Keyword(s):  
Catalytic Dehydrogenation ◽  
In Situ Reduction

Dynamic Modeling of CATOFIN® Fixed-Bed Iso-Butane Dehydrogenation Reactor for Operational Optimization

2016 ◽  
Vol 14 (1) ◽  
pp. 491-515 ◽  
Author(s):  
Zeeshan Nawaz
Keyword(s):  
Coke Formation ◽  
Fixed Bed ◽  
Process Intensification ◽  
Operating Conditions ◽  
Catalytic Dehydrogenation ◽  
Heating Rates ◽  
Reactor Model ◽  
Fuel Gas ◽  
Bed Temperature ◽  
Operational Optimization

AbstractThe catalytic dehydrogenation of iso-butane to iso-butylene is an equilibrium limited endothermic reaction and requires high temperature. The catalyst deactivates quickly, due to deposition of carbonaceous species and countered by periodic regeneration. The reaction-engineering constraints are tied up with operation and/or technology design features. CATOFIN® is a sophisticated commercialized technology for propane/iso-butane dehydrogenation using multiple adiabatic fixed-bed reactors having Cr2O3/Al2O3 as catalyst, that undergo cyclic operations (~18–30m); dehydrogenation, regeneration, evacuation, purging and reduction. It is always a concern, how to maintain CATOFIN® reactor at an optimum production, while overcoming gradual decrease of heat in catalyst bed and deactivation. A homogeneous one-dimensional dynamic reactor model for a commercial CATOFIN® fixed-bed iso-butane dehydrogenation reactor is developed in an equation oriented (EO) platform Aspen Custom Modeler (ACM), for operational optimization and process intensification. Both reaction and regeneration steps were modeled and results were validated. The model predicts the dynamic behavior and demonstrates the extent of catalyst utilization with operating conditions and time, coke formation and removal, etc. The model computes optimum catalyst bed temperature profiles, feed rate, pre-heating, rates for reaction and regeneration, fuel gas requirement, optimum catalyst amount, overall cycle time optimization, and suggest best operational philosophy.

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