Iron Carbonyl Thiocarbonyls: Effect of Substituting a Thiocarbonyl Group for a Carbonyl Group in Mononuclear and Binuclear Iron Carbonyl Derivatives

2009 ◽  
Vol 48 (5) ◽  
pp. 1974-1988 ◽  
Author(s):  
Zhong Zhang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
R. Bruce King ◽  
Henry F. Schaefer
Keyword(s):  
Carbonyl Group ◽  
Iron Carbonyl ◽  
Carbonyl Derivatives ◽  
Binuclear Iron

Methylborabenzene ligands in binuclear iron carbonyl derivatives: High spin states and iron–iron multiple bonding

2013 ◽  
Vol 747 ◽  
pp. 106-112 ◽  
Author(s):  
Jianlin Chen ◽  
Shaoling Chen ◽  
Zhiguo Liu ◽  
Hao Feng ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
High Spin ◽  
Iron Carbonyl ◽  
Spin States ◽  
High Spin States ◽  
Multiple Bonding ◽  
Carbonyl Derivatives ◽  
Iron Iron ◽  
Binuclear Iron

Diverse bonding modes of the tetramethyleneethane ligand in binuclear iron carbonyl derivatives

2013 ◽  
Vol 37 (3) ◽  
pp. 709-716 ◽  
Author(s):  
Huidong Li ◽  
Hao Feng ◽  
Weiguo Sun ◽  
Qunchao Fan ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Derivatives ◽  
Binuclear Iron

The facile coupling of carbon monochalcogenides to ethenedichalcogenone ligands in binuclear iron carbonyl derivatives: a theoretical study

2014 ◽  
Vol 38 (9) ◽  
pp. 4282-4289 ◽  
Author(s):  
Zhong Zhang ◽  
Liang Pu ◽  
Qian-shu Li ◽  
R. Bruce King
Keyword(s):  
Theoretical Study ◽  
Iron Carbonyl ◽  
Electron Donors ◽  
Carbonyl Derivatives ◽  
Binuclear Iron

The lowest energy Fe2(CO)n(CE)2 structures (E = S, Se, Te; n = 7, 6) do not have separate CE ligands but instead have coupled C2E2 ligands functioning as four to six-electron donors to the pair of iron atoms.

STRUCTURAL AND SOLVENT EFFECTS ON THE n → π*(′U ← ′A) TRANSITIONS IN ALIPHATIC CARBONYL DERIVATIVES: EVIDENCE FOR HYPERCONJUGATION IN THE ELECTRONICALLY EXCITED STATES OF MOLECULES

1960 ◽  
Vol 38 (12) ◽  
pp. 2508-2513 ◽  
Author(s):  
C. N. R. Rao ◽  
G. K. Goldman ◽  
A. Balasubramanian
Keyword(s):  
Hydrogen Bonding ◽  
Carbonyl Group ◽  
Excited States ◽  
Solvent Effects ◽  
Electronically Excited States ◽  
Carbonyl Derivatives ◽  
Alkyl Groups ◽  
Electronically Excited

The n → π* transition of the carbonyl group has been studied in solvents of varying degree of polarity and hydrogen-bonding ability, in a number of aliphatic carbonyl derivatives. Evidence for hyperconjugation of the alkyl groups in the electronically excited states of molecules has been presented.

Coupling of trifluoromethyl isocyanide ligands in binuclear iron carbonyl complexes

2014 ◽  
Vol 166 ◽  
pp. 34-43 ◽  
Author(s):  
Guoliang Li ◽  
Lihua Liu ◽  
Jing Wang ◽  
Qian-shu Li ◽  
Yaoming Xie ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Isocyanide Ligands ◽  
Binuclear Iron
Sign in / Sign up

Export Citation Format

Share Document