Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction

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In combination with small and difficult to reduce rare-earth metals pdl′ undergoes CH-bond activations instead of sterically induced reductions to form dimeric complexes with a unique bridging six-membered metallacycle as the central structural motif.


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