Mechanistic Insight into the Initiation Step of the Coupling Reaction of Oxetane or Epoxides and CO2Catalyzed by (salen)CrX Complexes

2008 ◽  
Vol 47 (21) ◽  
pp. 10000-10008 ◽  
Author(s):  
Donald J. Darensbourg ◽  
Adriana I. Moncada
Keyword(s):  
Coupling Reaction ◽  
Mechanistic Insight ◽  
Initiation Step ◽  
Insight Into

A Mechanistic Insight into the Cu(II)-Catalyzed C-N and C-O Coupling Reaction of Arylglyoxylic Acids with Isatins; A DFT Investigation

2019 ◽  
Vol 2019 (40) ◽  
pp. 6776-6782
Author(s):  
Andrea Bottoni ◽  
Matteo Calvaresi ◽  
Tainah D. Marforio ◽  
Gian Pietro Miscione
Keyword(s):  
Coupling Reaction ◽  
Mechanistic Insight ◽  
Insight Into

Reactivity and Mechanistic Insight into Visible-Light-Induced Aerobic Cross-Dehydrogenative Coupling Reaction by Organophotocatalysts

2011 ◽  
Vol 18 (2) ◽  
pp. 620-627 ◽  
Author(s):  
Qiang Liu ◽  
Ya-Nan Li ◽  
Hui-Hui Zhang ◽  
Bin Chen ◽  
Chen-Ho Tung ◽  
...  
Keyword(s):  
Visible Light ◽  
Coupling Reaction ◽  
Mechanistic Insight ◽  
Dehydrogenative Coupling ◽  
Insight Into

Mechanistic insight into the selective cyclization of arylnitrones to indolines via Rh(iii) catalyst: a theoretical study

RSC Advances ◽  
2016 ◽  
Vol 6 (28) ◽  
pp. 23265-23271 ◽  
Author(s):  
Tao Liu ◽  
Xiao-Wen Zheng ◽  
Ling-Li Han ◽  
Ya-Ping Li ◽  
Shu-Min Han ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Theoretical Study ◽  
Coupling Reaction ◽  
Dft Study ◽  
Reaction Conditions ◽  
Functional Theory ◽  
Mechanistic Insight ◽  
Insight Into

A density functional theory (DFT) study was performed to understand detailed mechanisms for the Rh(iii)-catalyzed coupling reaction of phenylnitrone with diphenylacetylene in different reaction conditions.

Reactivity and mechanistic insight into the cross coupling reaction between isochromans and β-keto esters through C–H bond activation under visible light irradiation

2016 ◽  
Vol 3 (4) ◽  
pp. 486-490 ◽  
Author(s):  
Ming Xiang ◽  
Qing-Yuan Meng ◽  
Xue-Wang Gao ◽  
Tao Lei ◽  
Bin Chen ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Bond Activation ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Keto Esters ◽  
Mechanistic Insight ◽  
Cross Coupling Reaction ◽  
Insight Into

The formation of a C(sp3)–C(sp3) bond next to an oxygen atom from two different C–H bonds is realized by oxidative photocatalysis.

scholarly journals Mechanistic insight into B(C6F5)3 catalyzed imine reduction with PhSiH3 under stoichiometric water conditions

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20961-20969
Author(s):  
Yunqing He ◽  
Wanli Nie ◽  
Ying Xue ◽  
Qishan Hu
Keyword(s):  
Mechanistic Insight ◽  
Excess Water ◽  
Water Conditions ◽  
Imine Reduction ◽  
Water Amount ◽  
Insight Into

Hydrosilylation or amination products? It depends on water amount and nucleophiles like excess water or produced/added amines.

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