Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes

2008 ◽  
Vol 47 (22) ◽  
pp. 10378-10388 ◽  
Author(s):  
Eric D. Cline ◽  
Samantha E. Adamson ◽  
Stefan Bernhard
Keyword(s):  
Hydrogen Production ◽  
Catalytic System ◽  
Rhodium Complexes ◽  
Photoinduced Hydrogen Production

scholarly journals Iridium Complex Catalyzed Hydrogen Production from Glucose and Various Monosaccharides

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 891
Author(s):  
Ken-ichi Fujita ◽  
Takayoshi Inoue ◽  
Toshiki Tanaka ◽  
Jaeyoung Jeong ◽  
Shohichi Furukawa ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Catalytic System ◽  
Catalytic Reaction ◽  
Hydrogen Gas ◽  
Water Soluble ◽  
Starting Material ◽  
Iridium Complex ◽  
Production Of Hydrogen ◽  
Bipyridine Ligand

A new catalytic system has been developed for hydrogen production from various monosaccharides, mainly glucose, as a starting material under reflux conditions in water in the presence of a water-soluble dicationic iridium complex bearing a functional bipyridine ligand. For example, the reaction of D-glucose in water under reflux for 20 h in the presence of [Cp*Ir(6,6′-dihydroxy-2,2′-bipyridine)(H2O)][OTf]2 (1.0 mol %) (Cp*: pentamethylcyclopentadienyl, OTf: trifluoromethanesulfonate) resulted in the production of hydrogen gas in 95% yield. In the present catalytic reaction, it was experimentally suggested that dehydrogenation of the alcoholic moiety at 1-position of glucose proceeded.

PHOTOINDUCED HYDROGEN PRODUCTION BY QUADRACOMPONENT SYSTEM

1986 ◽  
pp. 135-138
Author(s):  
Li Yao-zhong ◽  
Jin Li ◽  
Zhu Shu-guang ◽  
Zhao Hua-ming
Keyword(s):  
Hydrogen Production ◽  
Photoinduced Hydrogen Production

scholarly journals Photoinduced hydrogen production with photosensitization of Zn chlorophyll analog dimer as a photosynthetic special pair model

2015 ◽  
Vol 40 (15) ◽  
pp. 5313-5318 ◽  
Author(s):  
Masaharu Kondo ◽  
Shuichi Ishigure ◽  
Yuko Maki ◽  
Takehisa Dewa ◽  
Mamoru Nango ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Special Pair ◽  
Pair Model ◽  
Photoinduced Hydrogen Production
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