Structural and Spectroscopic Impact of Tuning the Stereochemical Activity of the Lone Pair in Lead(II) Cyanoaurate Coordination Polymers via Ancillary Ligands

2008 ◽  
Vol 47 (14) ◽  
pp. 6353-6363 ◽  
Author(s):  
Michael J. Katz ◽  
Vladimir K. Michaelis ◽  
Pedro M. Aguiar ◽  
Renante Yson ◽  
Haiyan Lu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Lone Pair ◽  
Ancillary Ligands ◽  
Stereochemical Activity

On the consequences of the stereochemical activity of the Bi(iii) 6s2 lone pair in cyclen-based complexes. The [Bi(DO3A)] case

2018 ◽  
Vol 47 (39) ◽  
pp. 13830-13842 ◽  
Author(s):  
Rosa Pujales-Paradela ◽  
Aurora Rodríguez-Rodríguez ◽  
Antonella Gayoso-Padula ◽  
Isabel Brandariz ◽  
Laura Valencia ◽  
...  
Keyword(s):  
Lone Pair ◽  
Spatial Arrangement ◽  
Stereochemical Activity

The spatial arrangement of donor atoms in Bi(iii) cyclen derivatives modulates the orientation and activity of the 6s2 lone pair.

Reversible stimulus-responsive coordination polymers mainly involving conversion between the lone-pair–π and cation–π interactions

2020 ◽  
Vol 73 (5) ◽  
pp. 854-866
Author(s):  
Qing-Qing Yan ◽  
Bin Li ◽  
Wei-Peng Jiang ◽  
Ying-Bo Xu ◽  
Zhi-Qiang Xu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Lone Pair ◽  
Π Interactions ◽  
Stimulus Responsive

Flexible N-Donor Ligands Direct the Structural Characteristics of CoII Complexes: Syntheses, Structures, and Magnetic Properties

2019 ◽  
Vol 72 (5) ◽  
pp. 341 ◽  
Author(s):  
Yu-Ting Yang ◽  
Chang-Zheng Tu ◽  
Xiao-Lin Xu ◽  
Li-Li Xu ◽  
Bang-Ling Yan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Structural Characteristics ◽  
Donor Ligands ◽  
X Ray Diffraction ◽  
Thermal Stabilities ◽  
Ancillary Ligands ◽  
X Ray ◽  
Elemental Analyses ◽  
Bilayered Structure

Solvothermal reactions of 3,3′,5,5′-biphenyltetracarboxylic acid (H4BPTC) and cobalt(ii) ions in the presence of two different flexible N-donor ancillary ligands afford two novel coordination polymers, {[Co(BPTC)0.5(bix)]·H2O}n (1), {[Co(BPTC)0.5(bpp)]·3H2O}n (2) (bix=1,4-bis(imidazol-1-ylmethyl)benzene; bpp=1,3-bis(4-pyridyl)propane). Their structures have been determined by elemental analyses, IR spectra, single-crystal X-ray diffraction analyses, and powder X-ray diffraction. The pillared layered framework of 1 can be simplified to a (4,6)-connected net with a Schläfli symbol of (44·62)(44·69·82). Complex 2 manifests a bilayered structure, and can be simplified to a (4,4)-connected net with a Schläfli symbol of (55·8)(54·62). The thermal stabilities of both complexes and the magnetic behaviours of 1 are also discussed.

Bis(pyridyl) ancillary ligands modulated uninodal 4-, 5- and 6-connected Cd(ii) coordination polymers based on 3,4-thiophenedicarboxylate linker

CrystEngComm ◽  
2013 ◽  
Vol 15 (14) ◽  
pp. 2745 ◽  
Author(s):  
Zhao-Hao Li ◽  
Li-Ping Xue ◽  
Shi-Hui Li ◽  
Jian-Ge Wang ◽  
Bang-Tun Zhao ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Ancillary Ligands

scholarly journals Correlating structure and electronic band-edge properties in organolead halide perovskites nanoparticles

2016 ◽  
Vol 18 (22) ◽  
pp. 14933-14940 ◽  
Author(s):  
Qiushi Zhu ◽  
Kaibo Zheng ◽  
Mohamed Abdellah ◽  
Alexander Generalov ◽  
Dörthe Haase ◽  
...  
Keyword(s):  
Lattice Strain ◽  
Lone Pair ◽  
Band Edge ◽  
Electronic Band ◽  
Halide Perovskites ◽  
Organolead Halide ◽  
Stereochemical Activity

Lattice strain modifies the subtle stereochemical activity of the Pb2+ lone-pair in organolead halide perovskites (OHLP) nanoparticles.

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