Nanosecond CO Photodissociation and Excited-State Character of [Ru(X)(X′)(CO)2(N,N′-diisopropyl-1,4-diazabutadiene)] (X = X′ = Cl or I; X = Me, X′ = I; X = SnPh3, X′ = Cl) Studied by Time-Resolved Infrared Spectroscopy and DFT Calculations

2008 ◽  
Vol 47 (10) ◽  
pp. 4236-4242 ◽  
Author(s):  
Anders Gabrielsson ◽  
Mike Towrie ◽  
Stanislav Záliš ◽  
Antonín Vlček
Keyword(s):  
Infrared Spectroscopy ◽  
Excited State ◽  
Dft Calculations ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy

scholarly journals Excited States and Intermediates by Time-Resolved Infrared Spectroscopy

1999 ◽  
Vol 19 (1-4) ◽  
pp. 245-251 ◽  
Author(s):  
J. J. Turner ◽  
M. W. George ◽  
I. P. Clark ◽  
I. G. Virrels
Keyword(s):  
Infrared Spectroscopy ◽  
Excited State ◽  
Charge Transfer ◽  
Excited States ◽  
Fast Time ◽  
Time Resolved ◽  
Excited Species ◽  
Charge Transfer Transitions ◽  
Time Resolved Infrared Spectroscopy ◽  
Kinetics Of

For coordination compounds containing CO or CN groups, fast time-resolved infrared spectroscopy (TRIR) provides a convenient method of probing excited states and intermediates. TRIR has proved particularly powerful for probing the structure and kinetics of organometallic intermediates. The interpretation is particularly straightforward when combined with IR data from matrix isolation experiments, although there can be some subtle differences. In excited state studies, shifts in ν(CO) and ν(CN) frequencies, from ground to excited state, are sensitive to the changes in electron distribution on excitation, thus allowing the distinction between charge-transfer and non-charge-transfer transitions. Subtle effects on excited state ν(CO) band positions occur with change from fluid to rigid solvent-“infrared rigidochromism”. There is often a change in ν(CO) band width on excitation; this can be interpreted in terms of specific interactions between the excited species and the solvent. This paper presents some of our recent work in this area.

scholarly journals Direct Visualization of Excited-State Symmetry Breaking Using Ultrafast Time-Resolved Infrared Spectroscopy

2016 ◽  
Vol 138 (13) ◽  
pp. 4643-4649 ◽  
Author(s):  
Bogdan Dereka ◽  
Arnulf Rosspeintner ◽  
Zhiquan Li ◽  
Robert Liska ◽  
Eric Vauthey
Keyword(s):  
Infrared Spectroscopy ◽  
Excited State ◽  
Symmetry Breaking ◽  
Direct Visualization ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy

scholarly journals Long-Lived Excited-State Dynamics of i-Motif Structures Probed by Time-Resolved Infrared Spectroscopy

ChemPhysChem ◽  
2016 ◽  
Vol 17 (9) ◽  
pp. 1281-1287 ◽  
Author(s):  
Páraic M. Keane ◽  
Frederico R. Baptista ◽  
Sarah P. Gurung ◽  
Stephen J. Devereux ◽  
Igor V. Sazanovich ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Excited State ◽  
Time Resolved ◽  
Excited State Dynamics ◽  
Time Resolved Infrared Spectroscopy

scholarly journals Back Cover: Long-Lived Excited-State Dynamics of i-Motif Structures Probed by Time-Resolved Infrared Spectroscopy (ChemPhysChem 9/2016)

ChemPhysChem ◽  
2016 ◽  
Vol 17 (9) ◽  
pp. 1388-1388
Author(s):  
Páraic M. Keane ◽  
Frederico R. Baptista ◽  
Sarah P. Gurung ◽  
Stephen J. Devereux ◽  
Igor V. Sazanovich ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Excited State ◽  
Time Resolved ◽  
Excited State Dynamics ◽  
Back Cover ◽  
Time Resolved Infrared Spectroscopy
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