Ionothermal Syntheses of Six Three-Dimensional Zinc Metal−Organic Frameworks with 1-Alkyl-3-methylimidazolium Bromide Ionic Liquids as Solvents

2007 ◽  
Vol 46 (25) ◽  
pp. 10670-10680 ◽  
Author(s):  
Ling Xu ◽  
Eun-Young Choi ◽  
Young-Uk Kwon
Keyword(s):  
Ionic Liquids ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Zinc Metal ◽  
Metal Organic

Solvent-induced construction of two zinc metal–organic frameworks for highly selective detection of nitroaromatic explosives

CrystEngComm ◽  
2016 ◽  
Vol 18 (22) ◽  
pp. 4102-4108 ◽  
Author(s):  
Chuanqi Zhang ◽  
Yan Yan ◽  
Libo Sun ◽  
Zhiqiang Liang ◽  
Jiyang Li
Keyword(s):  
High Efficiency ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Tricarboxylic Acid ◽  
Nitroaromatic Compounds ◽  
Selective Detection ◽  
Nitroaromatic Explosives ◽  
Zinc Metal ◽  
Metal Organic

Two three-dimensional metal–organic frameworks 1 and 2 based on p-terphenyl-3,4′′,5-tricarboxylic acid (H3TPT) were synthesized by controlling the solvent media. These two MOFs exhibit high efficiency for the recyclable detection of nitroaromatic compounds.

scholarly journals Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation

2015 ◽  
Vol 792 ◽  
pp. 134-138 ◽  
Author(s):  
Andrew D. Burrows ◽  
Laura C. Fisher ◽  
Timothy J. Mays ◽  
Sean P. Rigby ◽  
Sharon E. Ashbrook ◽  
...  
Keyword(s):  
Bond Formation ◽  
Metal Organic Frameworks ◽  
Carbon Bond ◽  
Zinc Metal ◽  
Carbon Carbon Bond ◽  
Metal Organic

scholarly journals Four Novel d10 Metal-Organic Frameworks Incorporating Amino-Functionalized Carboxylate Ligands: Synthesis, Structures, and Fluorescence Properties

2021 ◽  
Vol 9 ◽  
Author(s):  
Wang Xie ◽  
Jie Wu ◽  
Xiaochun Hang ◽  
Honghai Zhang ◽  
Kang shen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Fluorescence Properties ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Quenching Effect ◽  
D10 Metal ◽  
Metal Organic ◽  
Point Symbol

By employment of amino-functionalized dicarboxylate ligands to react with d10 metal ions, four novel metal-organic frameworks (MOFs) were obtained with the formula of {[Cd(BCPAB)(μ2-H2O)]}n (1), {[Cd(BDAB)]∙2H2O∙DMF}n (2), {[Zn(BDAB)(BPD)0.5(H2O)]∙2H2O}n (3) and {[Zn(BDAB)(DBPB)0.5(H2O)]∙2H2O}n (4) (H2BCPAB = 2,5-bis(p-carbonylphenyl)-1-aminobenzene; H2BDAB = 1,2-diamino-3,6-bis(4-carboxyphenyl)benzene); BPD = (4,4′-bipyridine); DBPB = (E,E-2,5-dimethoxy-1,4-bis-[2-pyridin-vinyl]-benzene; DMF = N,N-dimethylformamide). Complex 1 is a three-dimensional (3D) framework bearing seh-3,5-Pbca nets with point symbol of {4.62}{4.67.82}. Complex 2 exhibits a 4,4-connected new topology that has never been reported before with point symbol of {42.84}. Complex 3 and 4 are quite similar in structure and both have 3D supramolecular frameworks formed by 6-fold and 8-fold interpenetrated 2D coordination layers. The structures of these complexes were characterized by single crystal X-ray diffraction (SC-XRD), thermal gravimetric analysis (TGA) and powder X-ray diffraction (PXRD) measurements. In addition, the fluorescence properties and the sensing capability of 2–4 were investigated as well and the results indicated that complex 2 could function as sensor for Cu2+ and complex 3 could detect Cu2+ and Ag+via quenching effect.

Construction of Three-Dimensional Cobalt(II)-Based Metal–Organic Frameworks by Synergy between Rigid and Semirigid Ligands

2012 ◽  
Vol 12 (11) ◽  
pp. 5529-5534 ◽  
Author(s):  
Weiting Yang ◽  
Min Guo ◽  
Fei-Yan Yi ◽  
Zhong-Ming Sun
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Metal Organic

Porous Ionic Liquids or Liquid Metal-Organic Frameworks?

2018 ◽  
Vol 130 (37) ◽  
pp. 12085-12088 ◽  
Author(s):  
Margarida Costa Gomes ◽  
Laure Pison ◽  
Ctirad Červinka ◽  
Agilio Padua
Keyword(s):  
Ionic Liquids ◽  
Liquid Metal ◽  
Metal Organic Frameworks ◽  
Metal Organic
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