Electron-Transfer-Catalyzed Rearrangement of Unsymmetrically Substituted Diiron Dithiolate Complexes Related to the Active Site of the [FeFe]-Hydrogenases

2007 ◽  
Vol 46 (23) ◽  
pp. 9863-9872 ◽  
Author(s):  
Salah Ezzaher ◽  
Jean-François Capon ◽  
Frédéric Gloaguen ◽  
François Y. Pétillon ◽  
Philippe Schollhammer ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Active Site ◽  
Dithiolate Complexes ◽  
Diiron Dithiolate Complexes

On the electrochemistry of diiron dithiolate complexes related to the active site of the [FeFe]H2ase

2008 ◽  
Vol 11 (8) ◽  
pp. 842-851 ◽  
Author(s):  
Jean-François Capon ◽  
Frédéric Gloaguen ◽  
François Y. Pétillon ◽  
Philippe Schollhammer ◽  
Jean Talarmin
Keyword(s):  
Active Site ◽  
Dithiolate Complexes ◽  
Diiron Dithiolate Complexes

Electrochemical Synthesis of Mono- and Disubstituted Diiron Dithiolate Complexes as Models for the Active Site of Iron-Only Hydrogenases

2007 ◽  
Vol 2007 (32) ◽  
pp. 5062-5068 ◽  
Author(s):  
Didier Morvan ◽  
Jean-François Capon ◽  
Frederic Gloaguen ◽  
Philippe Schollhammer ◽  
Jean Talarmin
Keyword(s):  
Active Site ◽  
Electrochemical Synthesis ◽  
Dithiolate Complexes ◽  
Diiron Dithiolate Complexes

Effect of the S-to-S bridge on the redox properties and H2activation performance of diiron complexes related to the [FeFe]-hydrogenase active site

2016 ◽  
Vol 45 (44) ◽  
pp. 17687-17696 ◽  
Author(s):  
Minglun Cheng ◽  
Mei Wang ◽  
Dehua Zheng ◽  
Licheng Sun
Keyword(s):  
Active Site ◽  
Redox Properties ◽  
Dithiolate Complexes ◽  
Diiron Dithiolate Complexes

Studies on diiron dithiolate complexes containing the same PNP ligand but different S-to-S bridges demonstrate that changing the S-to-S bridge can considerably alter the H2activation performance of [FeFe]-hydrogenase models.

Pendant bases as proton transfer relays in diiron dithiolate complexes inspired by [Fe–Fe] hydrogenase active site

2008 ◽  
Vol 693 (17) ◽  
pp. 2828-2834 ◽  
Author(s):  
Zhen Wang ◽  
Wenfeng Jiang ◽  
Jianhui Liu ◽  
Weina Jiang ◽  
Yu Wang ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Active Site ◽  
Dithiolate Complexes ◽  
Diiron Dithiolate Complexes
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