Bent's rule: energetics, electronegativity, and the structures of nonmetal fluorides

1981 ◽  
Vol 20 (11) ◽  
pp. 4033-4035 ◽  
Author(s):  
James E. Huheey
Keyword(s):  
Bent’S Rule

Bent’s Rule

2016 ◽  
Author(s):  
Vladimir I. Minkin
Keyword(s):  
Bent’S Rule

Bent's Rule and the Structure of Transition Metal Compounds

1996 ◽  
Vol 35 (7) ◽  
pp. 2097-2099 ◽  
Author(s):  
V. Jonas ◽  
C. Boehme ◽  
G. Frenking
Keyword(s):  
Transition Metal ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Bent’S Rule

scholarly journals Hybridization Trends for Main Group Elements and Expanding the Bent’s Rule Beyond Carbon: More than Electronegativity

2014 ◽  
Vol 118 (20) ◽  
pp. 3663-3677 ◽  
Author(s):  
Igor V. Alabugin ◽  
Stefan Bresch ◽  
Mariappan Manoharan
Keyword(s):  
Main Group ◽  
Main Group Elements ◽  
Bent’S Rule

Stereochemistry of six coordinate organotin(IV) compounds with bidentate ligands

1979 ◽  
Vol 57 (17) ◽  
pp. 2223-2229 ◽  
Author(s):  
J. S. Tse ◽  
T. K. Sham ◽  
G. M. Bancroft
Keyword(s):  
Bidentate Ligand ◽  
Bidentate Ligands ◽  
Electronic Effects ◽  
Bite Size ◽  
Bond Angles ◽  
Bent’S Rule

Extended ligand–ligand repulsion calculations have been applied to a number of six coordinate organotin complexes of the type RR′Sn(bidentate)2 (R, R′ = Me, Ph, Cl). Qualitatively, the calculations readily predict the decrease in the R—Sn—R′ angle with decrease in bite size of the bidentate ligand. The steric calculations are generally successful in predicting both the cis–trans preference of the R groups and the bond angles about the Sn atom. For the Me2Sn complexes, electronic effects (as expressed by Bent's rule) sometimes have to be used in conjunction with the steric calculations to rationalize the observed stereochemistry.

SEARCHING FOR NEW MEMBERS OF C70 HOMOFULLERENES BY FIRST-PRINCIPLES COMPUTATIONS: BENT'S RULE AT WORK ON C70 SURFACE

2013 ◽  
Vol 12 (01) ◽  
pp. 1250097 ◽  
Author(s):  
JIACHENG FENG ◽  
FENGYU LI ◽  
PENG JIN ◽  
YUNLONG LIAO ◽  
ZHONGFANG CHEN
Keyword(s):  
First Principles ◽  
Density Functional ◽  
Membered Ring ◽  
Solution Phase ◽  
Functional Theory ◽  
New Members ◽  
High Thermodynamic Stability ◽  
Standard Solution ◽  
Phase Chemistry ◽  
Bent’S Rule

We carried out systematic density functional theory computations to search for new members of C70 homofullerenes inspired by the Bent's rule. By substituting CH2 by CF2 , we identified five experimentally accessible C70 homofullerenes, among which one member has different bonding character as its CH2 counterpart (where the closed three-membered ring is formed by CH2 addition). This unique C70 homofullerene is expected to be synthesized very smoothly using the standard solution phase chemistry, due to its high thermodynamic stability and the rather high local reactivity of the carbon bond attached to the CF2 addend.

scholarly journals BENT'S RULE CONTEXTUALIZES HYDROGEN BOND STRENGTH IN TRIMOLECULAR CLUSTERS

Química Nova ◽  
2014 ◽  
Vol 37 (4) ◽  
Author(s):  
Ives T. O. Santos ◽  
Danilo G. Rego ◽  
Boaz G. Oliveira
Keyword(s):  
Hydrogen Bond ◽  
Bond Strength ◽  
Hydrogen Bond Strength ◽  
Bent’S Rule
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