Local and cooperative Jahn-Teller interactions of copper(2+) in host lattices with tetragonally compressed octahedra. Spectroscopic and structural investigation of the mixed crystals K(Rb)2Zn1-xCuxF4

D. Reinen; S. Krause

doi:10.1021/ic50223a002

Local and cooperative Jahn-Teller interactions of copper(2+) in host lattices with tetragonally compressed octahedra. Spectroscopic and structural investigation of the mixed crystals K(Rb)2Zn1-xCuxF4

Inorganic Chemistry ◽

10.1021/ic50223a002 ◽

1981 ◽

Vol 20 (9) ◽

pp. 2750-2759 ◽

Cited By ~ 62

Author(s):

D. Reinen ◽

S. Krause

Keyword(s):

Structural Investigation ◽

Mixed Crystals ◽

Jahn Teller ◽

Host Lattices

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ChemInform Abstract: LOCAL AND COOPERATIVE JAHN-TELLER INTERACTIONS OF COPPER(2+) IN HOST LATTICES WITH TETRAGONALLY COMPRESSED OCTAHEDRA. SPECTROSCOPIC AND STRUCTURAL INVESTIGATION OF THE MIXED CRYSTALS K(RB)2ZN1-XCUXF4

Chemischer Informationsdienst ◽

10.1002/chin.198147002 ◽

1981 ◽

Vol 12 (47) ◽

Author(s):

D. REINEN ◽

S. KRAUSE

Keyword(s):

Structural Investigation ◽

Mixed Crystals ◽

Jahn Teller ◽

Host Lattices

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Structure and Jahn-Teller effect in mixed crystals Rb2Cr1−xMnxCl4: A single-crystal neutron diffraction study and spectroscopic results

Journal of Solid State Chemistry ◽

10.1016/0022-4596(80)90427-2 ◽

1980 ◽

Vol 34 (3) ◽

pp. 289-299 ◽

Cited By ~ 29

Author(s):

G. Münninghoff ◽

W. Treutmann ◽

E. Hellner ◽

G. Heger ◽

D. Reinen

Keyword(s):

Neutron Diffraction ◽

Single Crystal ◽

Diffraction Study ◽

Neutron Diffraction Study ◽

Mixed Crystals ◽

Teller Effect ◽

Jahn Teller ◽

Jahn Teller Effect

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Jahn-Teller and Reorientation Effects in the ESR Spectrum of the Self-Trapped Holes in Mixed Crystals AgBr1-xClx. II

Journal of the Physical Society of Japan ◽

10.1143/jpsj.44.1901 ◽

1978 ◽

Vol 44 (6) ◽

pp. 1901-1908 ◽

Cited By ~ 8

Author(s):

Mitsuo Yamaga ◽

Hide Yoshioka

Keyword(s):

The Self ◽

Mixed Crystals ◽

Esr Spectrum ◽

Jahn Teller

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Eu(ii) luminescence in the perovskite host lattices KMgH3, NaMgH3 and mixed crystals LiBaxSr1−xH3

Journal of Materials Chemistry C ◽

10.1039/c4tc00644e ◽

2014 ◽

Vol 2 (24) ◽

pp. 4799-4804 ◽

Cited By ~ 20

Author(s):

N. Kunkel ◽

A. Meijerink ◽

M. Springborg ◽

H. Kohlmann

Keyword(s):

Red Shift ◽

Mixed Crystals ◽

Emission Energy ◽

Host Lattices ◽

Bright Luminescence

Bright luminescence is observed for the perovskite KMgH3:Eu2+ and a wide red shift in the emission energies of Eu(ii) in NaMgH3. In LiBaxSr1−xH3:Eu2+ the emission energy depends on the value of x.

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The influence of local distortions on the static and dynamic properties of copper and silver eightfold-coordinated Jahn-Teller complexes in mixed crystals with a fluorite-type structure

Physics of the Solid State ◽

10.1134/1.1501340 ◽

2002 ◽

Vol 44 (8) ◽

pp. 1471-1479

Author(s):

V. A. Ulanov ◽

M. M. Zaripov ◽

E. P. Zheglov

Keyword(s):

Dynamic Properties ◽

Mixed Crystals ◽

Type Structure ◽

Fluorite Type ◽

Jahn Teller ◽

Local Distortions

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Electronic structure of low-spin ferric porphyrins: a single-crystal EPR and structural investigation of the influence of axial ligand orientation and the effects of pseudo-Jahn-Teller distortion

Journal of the American Chemical Society ◽

10.1021/ja00245a019 ◽

1987 ◽

Vol 109 (11) ◽

pp. 3301-3308 ◽

Cited By ~ 45

Author(s):

Robert Quinn ◽

Joan Selverstone Valentine ◽

Marianne P. Byrn ◽

Charles E. Strouse

Keyword(s):

Electronic Structure ◽

Single Crystal ◽

Structural Investigation ◽

Axial Ligand ◽

Teller Distortion ◽

Jahn Teller ◽

Ligand Orientation ◽

Jahn Teller Distortion

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Jahn-Teller and Reorientation Effects in the ESR Spectrum of the Self-Trapped Holes in Mixed Crystals AgBr1-xClx

Journal of the Physical Society of Japan ◽

10.1143/jpsj.44.154 ◽

1978 ◽

Vol 44 (1) ◽

pp. 154-161 ◽

Cited By ~ 18

Author(s):

Mitsuo Yamaga ◽

Yoshikazu Hayashi ◽

Hide Yoshioka

Keyword(s):

The Self ◽

Mixed Crystals ◽

Esr Spectrum ◽

Jahn Teller

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ChemInform Abstract: Jahn-Teller Distortions of Transition Metal Ions in Tetrahedral Coordination. - The Structures of Cat(M(II)(NCS)4) (M(II): Co, Ni, Cu) and of Mixed Crystals M(II)Cr2O4 (M(II): Zn-Ni, Zn-Cu, Cu-Ni) of the Spinel Type.

ChemInform ◽

10.1002/chin.198737012 ◽

1987 ◽

Vol 18 (37) ◽

Author(s):

D. REINEN ◽

R. ALLMANN ◽

G. BAUM ◽

B. JAKOB ◽

U. KASCHUBA ◽

...

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Transition Metal Ions ◽

Mixed Crystals ◽

Tetrahedral Coordination ◽

Spinel Type ◽

Jahn Teller

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Tieftemperatur-Remissionsspektren oktaedrisch koordinierter Cu2+ -Ionen im Ligandenfeldbereich / Low temperature reflectance spectra of octahedrally coordinated Cu2+-ions in solids

Zeitschrift für Naturforschung A ◽

10.1515/zna-1973-3-421 ◽

1973 ◽

Vol 28 (3-4) ◽

pp. 464-471 ◽

Cited By ~ 17

Author(s):

J. Grefer ◽

D. Reinen

Keyword(s):

Reflectance Spectra ◽

Ligand Field ◽

Teller Distortion ◽

Square Planar ◽

Jahn Teller ◽

Jahn Teller Effect ◽

Field Formalism ◽

Field Reflectance ◽

Host Lattices ◽

Overlap Model

AbstractThe ligand field reflectance spectra of octahedrally coordinated Cu2+-ions in different host lattices and at different temperature (300 °K - 4 °K) are critically compared. Especially the band shifts with decreasing temperature are analysed with respect to transitions from a dynamical to a static Jahn-Teller effect (macroscopic Jahn -Teller distortion of the lattice). In addition the square planar coordination of Cu2+ is discussed and alternative descriptions in the crystal field formalism and the angular overlap model are given.

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