Reactions of aminophosphines with carbon dioxide, carbonyl sulfide, and carbon disulfide. Crystal and molecular structure of a seven-coordinate tris(dithiocarbamato) complex of phosphorus(III)

R. W. Light; L. D. Hutchins; R. T. Paine; C. F. Campana

doi:10.1021/ic50214a008

Reactions of aminophosphines with carbon dioxide, carbonyl sulfide, and carbon disulfide. Crystal and molecular structure of a seven-coordinate tris(dithiocarbamato) complex of phosphorus(III)

Inorganic Chemistry ◽

10.1021/ic50214a008 ◽

1980 ◽

Vol 19 (12) ◽

pp. 3597-3604 ◽

Cited By ~ 33

Author(s):

R. W. Light ◽

L. D. Hutchins ◽

R. T. Paine ◽

C. F. Campana

Keyword(s):

Molecular Structure ◽

Carbon Dioxide ◽

Carbon Disulfide ◽

Crystal And Molecular Structure ◽

Carbonyl Sulfide

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ChemInform Abstract: REACTIONS OF AMINOPHOSPHINES WITH CARBON DIOXIDE, CARBONYL SULFIDE, AND CARBON DISULFIDE. CRYSTAL AND MOLECULAR STRUCTURE OF A SEVEN-COORDINATE TRIS(DITHIOCARBAMATO) COMPLEX OF PHOSPHORUS(III)

Chemischer Informationsdienst ◽

10.1002/chin.198110064 ◽

1981 ◽

Vol 12 (10) ◽

Author(s):

R. W. LIGHT ◽

L. D. HUTCHINS ◽

R. T. PAINE ◽

C. F. CAMPANA

Keyword(s):

Molecular Structure ◽

Carbon Dioxide ◽

Carbon Disulfide ◽

Crystal And Molecular Structure ◽

Carbonyl Sulfide

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Application of significant structure theory to the correlation of thermodynamic properties of carbon dioxide, carbonyl sulfide, and carbon disulfide in terms of the respective molecular parameters

The Journal of Physical Chemistry ◽

10.1021/j100854a007 ◽

1968 ◽

Vol 72 (8) ◽

pp. 2730-2737 ◽

Cited By ~ 16

Author(s):

Melvin E. Zandler ◽

James A. Watson ◽

Henry Eyring

Keyword(s):

Carbon Dioxide ◽

Thermodynamic Properties ◽

Carbon Disulfide ◽

Carbonyl Sulfide ◽

Structure Theory ◽

Molecular Parameters ◽

Significant Structure Theory ◽

Significant Structure

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ChemInform Abstract: HIGH-PRESSURE INTERACTION OF PHOSPHORUS TRIFLUORIDE WITH CARBON DIOXIDE, CARBON DISULFIDE, AND CARBONYL SULFIDE

Chemischer Informationsdienst ◽

10.1002/chin.197537138 ◽

1975 ◽

Vol 6 (37) ◽

pp. no-no

Author(s):

ARNULF P. HAGEN ◽

BILL W. CALLAWAY

Keyword(s):

Carbon Dioxide ◽

High Pressure ◽

Carbon Disulfide ◽

Carbonyl Sulfide

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Carbon Dioxide, Carbonyl Sulfide, Carbon Disulfide, Isocyanates, Isothiocyanates, Carbodiimides, and Their Selenium, Tellurium, and Phosphorus Analogues (Update 2014)

Knowledge Updates 2014/3 ◽

10.1055/sos-sd-118-00330 ◽

2014 ◽

Keyword(s):

Carbon Dioxide ◽

Carbon Disulfide ◽

Carbonyl Sulfide

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ChemInform Abstract: USE OF THE MULTIPLE-SCATTERING METHOD FOR CALCULATING THE ASYMMETRY PARAMETER IN THE ANGLE-RESOLVED PHOTOELECTRON SPECTROSCOPY OF NITROGEN, CARBON MONOXIDE, CARBON DIOXIDE, CARBONYL SULFIDE, AND CARBON DISULFIDE

Chemischer Informationsdienst ◽

10.1002/chin.198030043 ◽

1980 ◽

Vol 11 (30) ◽

Author(s):

F. A. GRIMM ◽

T. A. CARLSON ◽

W. B. DRESS ◽

P. AGRON ◽

J. O. THOMSON ◽

...

Keyword(s):

Carbon Dioxide ◽

Carbon Monoxide ◽

Multiple Scattering ◽

Carbon Disulfide ◽

Photoelectron Spectroscopy ◽

Asymmetry Parameter ◽

Carbonyl Sulfide ◽

Scattering Method ◽

The Asymmetry ◽

Multiple Scattering Method

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Cycloadditions XX. Crystal and molecular structure of the adduct from 3-diazobutanone and carbon disulfide

Journal of the American Chemical Society ◽

10.1021/ja01023a025 ◽

1968 ◽

Vol 90 (21) ◽

pp. 5800-5805 ◽

Cited By ~ 22

Author(s):

Jon A. Kapecki ◽

John E. Baldwin ◽

Iain C. Paul

Keyword(s):

Molecular Structure ◽

Carbon Disulfide ◽

Crystal And Molecular Structure

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Oxidative addition of carbon dioxide, epoxides, and related molecules to WCl2(PMePh2)4 yielding tungsten(IV) oxo, imido, and sulfido complexes. Crystal and molecular structure of W(O)Cl2(CO)(PMePh2)2

Journal of the American Chemical Society ◽

10.1021/ja00243a047 ◽

1987 ◽

Vol 109 (9) ◽

pp. 2826-2828 ◽

Cited By ~ 69

Author(s):

Jeffrey C. Bryan ◽

Steven J. Geib ◽

Arnold L. Rheingold ◽

James M. Mayer

Keyword(s):

Molecular Structure ◽

Carbon Dioxide ◽

Crystal And Molecular Structure ◽

Oxidative Addition

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ChemInform Abstract: On Chalcogenolates. Part 176. Reaction of Acetamidine with Carbon Disulfide. Part 5. Crystal and Molecular Structure of N-Acetimidoyl Dithiocarbamic Acid

ChemInform ◽

10.1002/chin.198727059 ◽

1987 ◽

Vol 18 (27) ◽

Author(s):

W. EUL ◽

G. KIEL ◽

G. GATTOW

Keyword(s):

Molecular Structure ◽

Carbon Disulfide ◽

Crystal And Molecular Structure ◽

Dithiocarbamic Acid

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Product Class 2: Carbon Dioxide, Carbonyl Sulfide, Carbon Disulfide, Isocyanates, Isothiocyanates, Carbodiimides, and Their Selenium, Tellurium, and Phosphorus Analogues

Category 3, Compounds with Four and Three Carbon Heteroatom Bonds ◽

10.1055/sos-sd-018-00070 ◽

2005 ◽

Keyword(s):

Carbon Dioxide ◽

Carbon Disulfide ◽

Carbonyl Sulfide ◽

Product Class

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Preparation and structure of 4-(dimethylamino)thiopivalophenone – intermolecular interactions in the crystal

Zeitschrift für Naturforschung B ◽

10.1515/znb-2019-0113 ◽

2019 ◽

Vol 74 (11-12) ◽

pp. 825-831

Author(s):

Jürgen Voss ◽

Dirk Buddensiek ◽

Gunadi Adiwidjaja

Keyword(s):

Molecular Structure ◽

Carbon Disulfide ◽

Quantum Chemical ◽

Electron Distribution ◽

Significant Contribution ◽

Crystal And Molecular Structure ◽

Resonance Structure ◽

X Ray Diffraction ◽

Torsion Angles ◽

X Ray

Abstract4-(Dimethylamino)thiopivalophenone was prepared from 4-bromo-N,N-dimethylaniline, pivalonitrile and carbon disulfide. Its crystal and molecular structure was determined by single-crystal X-ray diffraction. The experimentally determined bond distances, bond angles and torsion angles are indicative of a significant contribution of a dipolar (“quinodimethane”) resonance structure to the electron distribution in the molecule. Quantum chemical calculations corroborate these results. The calculations, furthermore, provide an explanation of the arrangement of the molecules in the crystal.

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