Organometallic gallium(I) anions prepared by a reductive elimination reaction

O. T. Beachley; Randall G. Simmons

doi:10.1021/ic50212a041

Organometallic gallium(I) anions prepared by a reductive elimination reaction

Inorganic Chemistry ◽

10.1021/ic50212a041 ◽

1980 ◽

Vol 19 (10) ◽

pp. 3042-3046 ◽

Cited By ~ 14

Author(s):

O. T. Beachley ◽

Randall G. Simmons

Keyword(s):

Reductive Elimination ◽

Elimination Reaction

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Reductive elimination reaction of β-nitrosulfones via one electron transfer process. A new synthetic method for the preparation ofα,β-unsaturated nitriles and esters

Tetrahedron Letters ◽

10.1016/s0040-4039(01)85389-2 ◽

1978 ◽

Vol 19 (8) ◽

pp. 763-764 ◽

Cited By ~ 11

Author(s):

Noboru Ono ◽

Rui Tamura ◽

Jun-ichi Hayami ◽

Aritsune Kaji

Keyword(s):

Electron Transfer ◽

Transfer Process ◽

Reductive Elimination ◽

Synthetic Method ◽

Elimination Reaction ◽

Electron Transfer Process

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Theoretical Study of the Structure, Bonding Nature, and Reductive Elimination Reaction of Pd(XH3)(η3-C3H5)(PH3) (X = C, Si, Ge, Sn). Hypervalent Behavior of Group 14 Elements

Organometallics ◽

10.1021/om990296l ◽

1999 ◽

Vol 18 (20) ◽

pp. 4015-4026 ◽

Cited By ~ 21

Author(s):

Bishajit Biswas ◽

Manabu Sugimoto ◽

Shigeyoshi Sakaki

Keyword(s):

Theoretical Study ◽

Reductive Elimination ◽

Elimination Reaction ◽

Group 14 ◽

Group 14 Elements

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Aluminum(2P)-silane complex and photoreversible oxidative addition/reductive elimination reaction Al(2P){SiH4} .tautm. SiH3AlH. 2. Al(2P){SiH4} .tautm. SiH3AlH reaction

The Journal of Physical Chemistry ◽

10.1021/j100160a003 ◽

1991 ◽

Vol 95 (7) ◽

pp. 2623-2628 ◽

Cited By ~ 4

Author(s):

Michael A. Lefcourt ◽

Geoffrey A. Ozin

Keyword(s):

Oxidative Addition ◽

Reductive Elimination ◽

Elimination Reaction

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Interplay of water and a supramolecular capsule for catalysis of reductive elimination reaction from gold

Nature Communications ◽

10.1038/s41467-019-14251-6 ◽

2020 ◽

Vol 11 (1) ◽

Cited By ~ 8

Author(s):

Valerie Vaissier Welborn ◽

Wan-Lu Li ◽

Teresa Head-Gordon

Keyword(s):

Reductive Elimination ◽

Elimination Reaction

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A reexamination of the reactions of Ga(CH2SiMe3)3 and In(CH2SiMe3)3 with alkali-metal hydrides. The search for a reductive-elimination reaction

Inorganic Chemistry ◽

10.1021/ic00167a004 ◽

1983 ◽

Vol 22 (25) ◽

pp. 3683-3691 ◽

Cited By ~ 41

Author(s):

R. B. Hallock ◽

O. T. Beachley ◽

Yong Ji Li ◽

William Michael Sanders ◽

Melvyn Rowen Churchill ◽

...

Keyword(s):

Alkali Metal ◽

Metal Hydrides ◽

Reductive Elimination ◽

Elimination Reaction

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Mechanism of reductive elimination. Reaction of alkylpalladium(II) complexes with tetraorganotin, organolithium, and Grignard reagents. Evidence for palladium(IV) intermediacy

Journal of the American Chemical Society ◽

10.1021/ja00511a031 ◽

1979 ◽

Vol 101 (17) ◽

pp. 4981-4991 ◽

Cited By ~ 126

Author(s):

D. Milstein ◽

J. K. Stille

Keyword(s):

Reductive Elimination ◽

Grignard Reagents ◽

Elimination Reaction

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ChemInform Abstract: Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction to Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone.

ChemInform ◽

10.1002/chin.199849112 ◽

2010 ◽

Vol 29 (49) ◽

pp. no-no

Author(s):

J. F. HARTWIG

Keyword(s):

Reductive Elimination ◽

Elimination Reaction ◽

New Type

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REACTION MECHANISM STUDIES: 2. REDUCTIVE ELIMINATION OF 1,2-DIHALIDES WITH LITHIUM ALUMINUM HYDRIDE

Canadian Journal of Chemistry ◽

10.1139/v64-202 ◽

1964 ◽

Vol 42 (6) ◽

pp. 1294-1314 ◽

Cited By ~ 20

Author(s):

J. F. King ◽

R. G. Pews

Keyword(s):

Reaction Mechanism ◽

Lithium Aluminum Hydride ◽

General Scheme ◽

Aluminum Hydride ◽

Reductive Elimination ◽

Lithium Aluminum ◽

Elimination Reaction ◽

Complex Hydrides ◽

Steric Factors ◽

Related Compounds

1,2-Dibromides and bromohydrin p-toluenesulphonates of favorable geometry are readily reduced by lithium aluminum hydride in good yield to the corresponding olefin. Small quantities of water are found to have a temporaryacceleratingeffect on the reduction. The normal course of the reaction is a trans elimination, but when steric factors inhibit this, then substitution or cis elimination reactions may occur. It is shown that the cis elimination in the case of cis-1,2-dibromocyclohexane cannot involve reduction to the monobromide followed by dehydrobromination to the olefin. The reaction of some other 1,2-dihalides and related compounds with lithium aluminum hydride, and the reaction of a 1,2-dibromide with a number of other complex hydrides are reported.A general scheme for the mechanism of the olefin-forming elimination reaction is proposed. The limits that this study places on the possible positions of the reductive elimination of 1,2-dibromides with lithium aluminum hydride within this general scheme are discussed.

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