Ligand exchange in ferrocene with a .eta.1 ligand: Carbon monoxide. A bridge between ferrocene and cyclopentadienyl-iron-dicarbonyl chemistry

Enrique Roman; Didier Astruc

doi:10.1021/ic50201a072

Ligand exchange in ferrocene with a .eta.1 ligand: Carbon monoxide. A bridge between ferrocene and cyclopentadienyl-iron-dicarbonyl chemistry

Inorganic Chemistry ◽

10.1021/ic50201a072 ◽

1979 ◽

Vol 18 (11) ◽

pp. 3284-3285 ◽

Cited By ~ 15

Author(s):

Enrique Roman ◽

Didier Astruc

Keyword(s):

Carbon Monoxide ◽

Ligand Exchange

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ChemInform Abstract: LIGAND EXCHANGE IN FERROCENE WITH A η1 LIGAND: CARBON MONOXIDE. A BRIDGE BETWEEN FERROCENE AND CYCLOPENTADIENYL-IRON-DICARBONYL CHEMISTRY

Chemischer Informationsdienst ◽

10.1002/chin.198008317 ◽

1980 ◽

Vol 11 (8) ◽

Author(s):

E. ROMAN ◽

D. ASTRUC

Keyword(s):

Carbon Monoxide ◽

Ligand Exchange

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Carbon Monoxide Ligand-Exchange Reaction of Triruthenium Cluster Complexes Induced by Photosensitized Electron Transfer: A New Type of Photoactive CO Color Sensor

Inorganic Chemistry ◽

10.1021/ic060751n ◽

2006 ◽

Vol 45 (16) ◽

pp. 6114-6116 ◽

Cited By ~ 19

Author(s):

Mitsunari Itou ◽

Yasuyuki Araki ◽

Osamu Ito ◽

Hiroaki Kido

Keyword(s):

Carbon Monoxide ◽

Electron Transfer ◽

Exchange Reaction ◽

Ligand Exchange ◽

Ligand Exchange Reaction ◽

Cluster Complexes ◽

Color Sensor ◽

New Type

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Carbon monoxide release properties and molecular structures of phenylthiolatomanganese(i) carbonyl complexes of the type [(OC)4Mn(μ-S-aryl)]2

Dalton Transactions ◽

10.1039/c4dt03567d ◽

2015 ◽

Vol 44 (7) ◽

pp. 3020-3033 ◽

Cited By ~ 15

Author(s):

Ralf Mede ◽

Vaneza Paola Lorett-Velásquez ◽

Moritz Klein ◽

Helmar Görls ◽

Michael Schmitt ◽

...

Keyword(s):

Carbon Monoxide ◽

Ligand Exchange ◽

Molecular Structures ◽

Carbonyl Complexes

Arylthiolatomanganese(i) tetracarbonyls form dimers or trimers and show a two-step CO release, triggered by ligand exchange and irradiation.

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Low-valent oxo compounds. 5. Low-valent rhenium oxo alkoxide complexes. Synthesis, characterization, structure, and ligand exchange and carbon monoxide insertion reactions

Organometallics ◽

10.1021/om00099a006 ◽

1988 ◽

Vol 7 (9) ◽

pp. 1930-1938 ◽

Cited By ~ 19

Author(s):

Torsten K. G. Erikson ◽

Jeffrey C. Bryan ◽

James M. Mayer

Keyword(s):

Carbon Monoxide ◽

Ligand Exchange ◽

Insertion Reactions ◽

Low Valent ◽

Oxo Compounds

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a-6-Isomerie der Cyano-aquo-Corrinoide

Zeitschrift für Naturforschung B ◽

10.1515/znb-1968-0608 ◽

1968 ◽

Vol 23 (6) ◽

pp. 804-812 ◽

Cited By ~ 2

Author(s):

Wilhelm Friedrich ◽

Matthäus Moskophidis

Keyword(s):

Carbon Monoxide ◽

Phosphoric Acid ◽

Aqueous Medium ◽

Ligand Exchange ◽

Acid Group ◽

Carboxyl Groups ◽

Carbonic Acids ◽

Cobyric Acid ◽

Ph Range

The isomerisation of the a and b forms of several acid cyano-aquo-corrinoids (with one to four carboxyl groups or one phosphoric acid group) in aqueous medium was investigated. The reaction is accelerated by light, heat, anions (e.g. acetate ion) and carbon monoxide. For all cyano-aquo-corrinoids with carboxyl groups investigated the equilibrium a ⇄ b shifts in the direction a → b when the carboxyls dissociate; in the case of carbonic acids prepared from cobyric acid, the shift grows with the number of the carboxyls. On the contrary, the cyano-aquo-corrinoids with a phosphoric acid group (cobinamide phosphate and its three isomers) exist as a mixture of about 55 per cent a form and about 45 per cent b form in the entire pH range (2.5 to 9) investigated. It is shown that the isomerisation of the cyano-aquo-corrinoids follows the known rules of ligand exchange (and of the connected reactions, such as steric change, racemisation, and disproportionation) for cobalt (III) complexes.

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