Novel reactions of metal-metal bonds. Addition of sulfur dioxide and sulfur to dichlorobis(bis(diphenylphosphino)methane)dipalladium and the oxidation of coordinated sulfide

1979 ◽  
Vol 18 (11) ◽  
pp. 2996-3003 ◽  
Author(s):  
Alan L. Balch ◽  
Linda S. Benner ◽  
Marilyn M. Olmstead
Keyword(s):  
Sulfur Dioxide ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Reactivity of metal–metal bonds. IV. The reaction of sulfur dioxide with compounds containing Sn—Sn and Sn—Mn bonds

1968 ◽  
Vol 46 (4) ◽  
pp. 643-647 ◽  
Author(s):  
N. A. D. Carey ◽  
H. C. Clark
Keyword(s):  
Sulfur Dioxide ◽  
Metal Bond ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
New Compounds ◽  
Metal Bonds ◽  
Bimetallic Compounds

The reactions of sulfur dioxide with the compounds R6Sn2 and R3SnMn(CO)5 (R = CH3 or C6H5) have been studied. In all cases the evidence indicates that the metal–metal bond has been cleaved. With the ditins the new compounds R3Sn•SO2 (R = CH3 or C6H5) and R3Sn•2SO2 (R = C6H5) were obtained, while the mixed bimetallic compounds gave R3SnMn(CO)5•2.5SO2 (R = CH3 or C6H5) and R3SnMn(CO)5•1.5SO2 (R = CH3). The possible structures of these derivatives are discussed.

Compounds with Unbridged Dative Metal−Metal Bonds of Formula (R3P)2(OC)3OsW(CO)5and Related Complexes

2000 ◽  
Vol 19 (24) ◽  
pp. 5049-5062 ◽  
Author(s):  
Faming Jiang ◽  
Hilary A. Jenkins ◽  
Kumar Biradha ◽  
Harry B. Davis ◽  
Roland K. Pomeroy ◽  
...  
Keyword(s):  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Metal–metal bonds between elements of Groups IVAand IVB

1968 ◽  
Vol 0 (5) ◽  
pp. 260-261 ◽  
Author(s):  
R. S. P. Coutts ◽  
P. C. Wailes
Keyword(s):  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds
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