Structural studies of precursor and partially oxidized conducting complexes. 13. A neutron diffraction and x-ray diffuse scattering study of the dimerized platinum chain in rubidium tetracyanoplatinate chloride (2:1:0.3) trihydrate, Rb2[Pt(CN)4]Cl0.3.3.0H2O

1978 ◽  
Vol 17 (4) ◽  
pp. 834-839 ◽  
Author(s):  
Jack M. Williams ◽  
Paul L. Johnson ◽  
Arthur J. Schultz ◽  
Christopher C. Coffey
Keyword(s):  
Neutron Diffraction ◽  
Diffuse Scattering ◽  
Structural Studies ◽  
X Ray ◽  
Scattering Study ◽  
Platinum Chain

An X-ray and Neutron Scattering Study of the Structure of Zinc Vanadate Glasses

2001 ◽  
Vol 56 (6-7) ◽  
pp. 478-488
Author(s):  
Uwe Hoppe ◽  
Rainer Kranold ◽  
Emil Gattef ◽  
Jörg Neuefeind ◽  
David A. Keen
Keyword(s):  
Neutron Diffraction ◽  
Coordination Number ◽  
Short Range ◽  
Short Range Order ◽  
X Ray ◽  
Coordination Numbers ◽  
Gaussian Functions ◽  
Scattering Study ◽  
Neutron Scattering Study ◽  
Vanadate Glasses

Abstract The short-range order of vitreous V20 5 and of three (Zn0)Jt(V20 5)1_x glasses with x = 0.2, 0.4, and 0.5 is studied by X-ray and neutron diffraction experiments where the change of the contrast allows to resolve the V -0 and Z n -0 correlations. The V -0 and the Z n -0 first-neighbor peaks are approximat­ ed by several Gaussian functions. In case of vitreous V20 5 two obvious V -0 distances exist which are related with V 0 4 and V 0 5 units. With ZnO additions the V -O coordination number decreases from 4.4 in vitreous V20 5 to 4.0 in the metavanadate glass where the strongest decrease of the fraction of V 0 5 units is found for glasses of * < 0.2. Dominantly, the V 0 5 groups are linked with the neighboring units by comers. The Z n-0 coordination numbers of the modified glasses are about five with closest dis­ tances of = 0.200 nm.

A High-Energy Monochromatic Laue (MonoLaue) X-ray Diffuse Scattering Study of KMnF3 using an Image Plate

1997 ◽  
Vol 30 (1) ◽  
pp. 16-20 ◽  
Author(s):  
A. Gibaud ◽  
D. Harlow ◽  
J. B. Hastings ◽  
J. P. Hill ◽  
D. Chapman
Keyword(s):  
Diffuse Scattering ◽  
High Energy ◽  
Experimental Conditions ◽  
X Ray ◽  
Image Plate ◽  
X Ray Scattering ◽  
Scattering Study ◽  
Diffraction Patterns ◽  
Ray Scattering

The technique of high-energy monochromatic Laue X-ray scattering using image plates to record the diffraction patterns is presented. A tunable wiggler beamline is used as an X-ray source. It is shown that such experimental conditions present many advantages over conventional tube sources and photographic films. A study of diffuse scattering in the perovskite compound KMnF3 is presented to illustrate this in a qualitative way.

scholarly journals Disorder in pentachloronitrobenzene, C6Cl5NO2: a diffuse scattering study

2007 ◽  
Vol 63 (4) ◽  
pp. 663-673 ◽  
Author(s):  
Lynne H. Thomas ◽  
T. Richard Welberry ◽  
Darren J. Goossens ◽  
Aidan P. Heerdegen ◽  
Matthias J. Gutmann ◽  
...  
Keyword(s):  
Diffuse Scattering ◽  
Short Range ◽  
Scattering Data ◽  
X Ray ◽  
Monte Carlo Computer Simulation ◽  
X Ray Scattering ◽  
Scattering Study ◽  
The Mean ◽  
Diffraction Patterns ◽  
Local Relaxation

Monte Carlo computer simulation has been used to interpret and model observed single-crystal diffuse X-ray scattering data for pentachloronitrobenzene, C6Cl5NO2. Each site in the crystal contains a molecule in one of six different basic orientations with equal probability. However, no short-range order amongst these different orientations has been detected. The strong, detailed and very distinctive diffraction patterns can be accounted for almost entirely on the assumption of random occupancy of each molecular site, but with very large local relaxation displacements that tend to increase the neighbouring distances for contacts involving NO2...NO2 and NO2...Cl with a corresponding reduction for those involving Cl...Cl. The results show that the mean NO2...NO2 distance is increased by ∼ 0.6 Å, compared with that given by the average structure determination.

X-ray diffuse scattering study of G.P. zones in Al-4 at.% Zn

1989 ◽  
Vol 37 (8) ◽  
pp. 2185-2195 ◽  
Author(s):  
D.R Haeffner ◽  
J.B Cohen
Keyword(s):  
Diffuse Scattering ◽  
X Ray ◽  
Scattering Study
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