Lower oxidation states of selenium.  2.  Potentiometric study involving tetravalent selenium, tetraselenium(2+), octaselenium(2+), and three other low oxidation states of selenium in a chloroaluminate melt

Rasmus. Fehrmann; Niels J. Bjerrum

doi:10.1021/ic50174a054

Lower oxidation states of selenium. 2. Potentiometric study involving tetravalent selenium, tetraselenium(2+), octaselenium(2+), and three other low oxidation states of selenium in a chloroaluminate melt

Inorganic Chemistry ◽

10.1021/ic50174a054 ◽

1977 ◽

Vol 16 (8) ◽

pp. 2089-2094 ◽

Cited By ~ 7

Author(s):

Rasmus. Fehrmann ◽

Niels J. Bjerrum

Keyword(s):

Oxidation States ◽

Potentiometric Study ◽

Lower Oxidation ◽

Chloroaluminate Melt

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ChemInform Abstract: LOWER OXIDATION STATES OF SELENIUM. 2. POTENTIOMETRIC STUDY INVOLVING TETRAVALENT SELENIUM, TETRASELENIUM(2+), OCTASELENIUM(2+), AND THREE OTHER LOW OXIDATION STATES OF SELENIUM IN A CHLOROALUMINATE MELT

Chemischer Informationsdienst ◽

10.1002/chin.197746036 ◽

1977 ◽

Vol 8 (46) ◽

pp. no-no

Author(s):

R. FEHRMANN ◽

N. J. BJERRUM

Keyword(s):

Oxidation States ◽

Potentiometric Study ◽

Lower Oxidation ◽

Chloroaluminate Melt

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Lower oxidation states in gallium halides

10.31274/rtd-180813-15014 ◽

1956 ◽

Author(s):

Richard K. McMullan

Keyword(s):

Oxidation States ◽

Lower Oxidation

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ChemInform Abstract: LOWER OXIDATION STATES OF SULFUR. 1. SPECTROPHOTOMETRIC STUDY OF THE SULFUR-CHLORINE SYSTEM IN MOLTEN SODIUM CHLORIDE-ALUMINUM CHLORIDE (37-63 MOL *) AT 150°C

Chemischer Informationsdienst ◽

10.1002/chin.197831011 ◽

1978 ◽

Vol 9 (31) ◽

Author(s):

R. FEHRMANN ◽

N. J. BJERRUM ◽

F. W. POULSEN

Keyword(s):

Sodium Chloride ◽

Aluminum Chloride ◽

Spectrophotometric Study ◽

Oxidation States ◽

Molten Sodium ◽

Lower Oxidation

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ChemInform Abstract: LOWER OXIDATION STATES OF SELENIUM PART 1, SPECTROPHOTOMETRIC STUDY OF THE SELENIUM-SELENIUM TETRACHLORIDE SYSTEM IN A MOLTEN NACL-ALCL3 EUTECTIC MIXTURE AT 150 DEGREES

Chemischer Informationsdienst ◽

10.1002/chin.197546004 ◽

1975 ◽

Vol 6 (46) ◽

pp. no-no

Author(s):

R. FEHRMANN ◽

N. J. BJERRUM ◽

H. A. ANDREASEN

Keyword(s):

Eutectic Mixture ◽

Spectrophotometric Study ◽

Oxidation States ◽

Lower Oxidation

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Lower oxidation states of bismuth. Bi82+ formed in aluminum chloride-sodium chloride melts

Inorganic Chemistry ◽

10.1021/ic50057a005 ◽

1967 ◽

Vol 6 (11) ◽

pp. 1968-1972 ◽

Cited By ~ 45

Author(s):

Niels J. Bjerrum ◽

George Pedro Smith

Keyword(s):

Sodium Chloride ◽

Aluminum Chloride ◽

Oxidation States ◽

Chloride Melts ◽

Lower Oxidation

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The prediction of metal-to-metal bonding in transition metal binary and related compounds

Australian Journal of Chemistry ◽

10.1071/ch9641191 ◽

1964 ◽

Vol 17 (11) ◽

pp. 1191 ◽

Cited By ~ 11

Author(s):

JC Sheldon

Keyword(s):

Transition Metal ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Valence State ◽

Oxidation States ◽

Metal Bonding ◽

Binary Oxides ◽

Lower Oxidation ◽

D Orbitals ◽

Related Compounds

The evidence for, and the factors determining, the formation of metal-to-metal (m-m) bonds in transition metal oxides, sulphides, halides, and related complexes are discussed. It is proposed that when metals of high preferred valence state are constrained to low formal oxidation states, m-m bonds will form to allow the metal to exercise a higher valency. It is assumed that (n-l)d orbitals are used for such bonds and predictions of the feasibility of m-m bonding are possible by the comparison of the size of such orbitals with the expected inter-metal distances in polymeric metal oxides and halides. It is concluded that binary oxides and halides (excepting fluorides) of the lower oxidation states of Zr, Hf, Nb, Ta, Mo, W, and Re and of a few neighbouring elements will display m-m bonds.

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Lower Oxidation States of f Elements: III. Properties of Low-Valence Lanthanide and Actinide Compounds in the Solid State and in Various Solvents

Radiochemistry ◽

10.1007/s11137-005-0113-7 ◽

2005 ◽

Vol 47 (5) ◽

pp. 423-439 ◽

Cited By ~ 4

Author(s):

N. B. Mikheev ◽

S. A. Kulyukhin ◽

A. N. Kamenskaya ◽

N. A. Konovalova ◽

I. A. Rumer

Keyword(s):

Solid State ◽

Oxidation States ◽

Lower Oxidation

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ChemInform Abstract: ELECTRON-TRANSFER KINETICS OF TRANSITION-METAL COMPLEXES IN LOWER OXIDATION STATES PART 3, ELECTROCHEMICAL RATE CONSTANTS FOR THE FE(II)/FE(I) REDOX SYSTEMS

Chemischer Informationsdienst ◽

10.1002/chin.197532351 ◽

1975 ◽

Vol 6 (32) ◽

pp. no-no

Author(s):

TETSUO SAJI ◽

TAMAKI YAMADA ◽

SHIGERU AOYAGUI

Keyword(s):

Electron Transfer ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Rate Constants ◽

Oxidation States ◽

Redox Systems ◽

Electron Transfer Kinetics ◽

Kinetics Of ◽

Lower Oxidation

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Oxides of rare-earth elements in lower oxidation states

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00954002 ◽

1986 ◽

Vol 35 (9) ◽

pp. 1778-1780

Author(s):

K. I. Slovetskaya ◽

Yu. S. Khodakov ◽

A. M. Rubinshtein ◽

Kh. M. Minachev

Keyword(s):

Rare Earth ◽

Rare Earth Elements ◽

Oxidation States ◽

Lower Oxidation

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Physicochemical properties of uranium in lower oxidation states

Radiochemistry ◽

10.1134/s1066362206060014 ◽

2006 ◽

Vol 48 (6) ◽

pp. 535-551 ◽

Cited By ~ 5

Author(s):

S. A. Kulyukhin ◽

N. B. Mikheev ◽

A. N. Kamenskaya ◽

N. A. Konovalova ◽

I. A. Rumer

Keyword(s):

Physicochemical Properties ◽

Oxidation States ◽

Lower Oxidation

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