Accessibility of manganese oxidation states. Control by pentaaza macrocyclic ligands

1977 ◽  
Vol 16 (3) ◽  
pp. 540-544 ◽  
Author(s):  
James C. Dabrowiak ◽  
Laurence A. Nafie ◽  
Philip S. Bryan ◽  
Andrew T. Torkelson
1977 ◽  
Vol 8 (21) ◽  
pp. no-no
Author(s):  
J. C. DABROWIAK ◽  
L. A. NAFIE ◽  
P. S. BRYAN ◽  
A. T. TORKELSON

2020 ◽  
Vol 27 (6) ◽  
pp. 1823-1835
Author(s):  
Nelly Couzon ◽  
Laurence Bois ◽  
Clémentine Fellah ◽  
Cristian Loestean ◽  
Fernand Chassagneux ◽  
...  

2021 ◽  
Vol 28 (1) ◽  
pp. 311-311
Author(s):  
Nelly Couzon ◽  
Laurence Bois ◽  
Clémentine Fellah ◽  
Cristian Leostean ◽  
Fernand Chassagneux ◽  
...  

1990 ◽  
Vol 68 (1) ◽  
pp. 79-81 ◽  
Author(s):  
Joaquin F. Perez-Benito ◽  
Enrique Brillas ◽  
Conchita Arias

An iodimetric technique has been developed to quantitatively analyze the oxidants present in organic solutions. Addition of excess tetrabutylammonium iodide and excess glacial acetic acid results in the formation of tetrabutylammonium triiodide, whose concentration can be measured spectrophotometrically at 295 or 365 nm. Application of this technique to the determination of the final oxidation state of manganese in permanganate reactions in methylene chloride solutions is described. The equilibrium constant for formation of tetrabutylammonium triiodide in methylene chloride has been measured: K = (3.48 ± 0.12) × 104 at 25.0 °C. Keywords: iodimetric determinations, manganese oxidation states, methylene chloride, quaternary ammonium permanganate, quaternary ammonium triiodide.


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