Metal atom chemistry and surface chemistry. 1. Dioxygensilver Ag+,O2-, and tetraoxygensilver, Ag+,O4-, reactive intermediates in the silver atom-dioxygen system. Relevance to surface chemistry

D. McIntosh; G. A. Ozin

doi:10.1021/ic50167a014

Metal atom chemistry and surface chemistry. 1. Dioxygensilver Ag+,O2-, and tetraoxygensilver, Ag+,O4-, reactive intermediates in the silver atom-dioxygen system. Relevance to surface chemistry

Inorganic Chemistry ◽

10.1021/ic50167a014 ◽

1977 ◽

Vol 16 (1) ◽

pp. 59-63 ◽

Cited By ~ 53

Author(s):

D. McIntosh ◽

G. A. Ozin

Keyword(s):

Surface Chemistry ◽

Metal Atom ◽

Silver Atom ◽

Reactive Intermediates ◽

Atom Chemistry

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ChemInform Abstract: METAL ATOM CHEMISTRY AND SURFACE CHEMISTRY. 1. DIOXYGENSILVER AG+,O2-, AND TETRAOXYGENSILVER, AG+,O4-, REACTIVE INTERMEDIATES IN THE SILVER ATOM-DIOXYGEN SYSTEM. RELEVANCE TO SURFACE CHEMISTRY

Chemischer Informationsdienst ◽

10.1002/chin.197712036 ◽

1977 ◽

Vol 8 (12) ◽

pp. no-no

Author(s):

D. MCINTOSH ◽

G. A. OZIN

Keyword(s):

Surface Chemistry ◽

Metal Atom ◽

Silver Atom ◽

Reactive Intermediates ◽

Atom Chemistry

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Metal atom chemistry and surface chemistry: (carbon dioxide)silver, Ag(CO2). A localized bonding model for weakly chemisorbed carbon dioxide on bulk silver

Inorganic Chemistry ◽

10.1021/ic50184a016 ◽

1978 ◽

Vol 17 (6) ◽

pp. 1472-1476 ◽

Cited By ~ 35

Author(s):

Geoffrey A. Ozin ◽

Helmut Huber ◽

Douglas McIntosh

Keyword(s):

Carbon Dioxide ◽

Surface Chemistry ◽

Metal Atom ◽

Bulk Silver ◽

Atom Chemistry

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Metal atom chemistry and surface chemistry. 2. Carbonylsilver(I) superoxide (OC)Ag+,O2-, a localized bonding model for carbon monoxide on an oxidized silver surface

Inorganic Chemistry ◽

10.1021/ic50167a015 ◽

1977 ◽

Vol 16 (1) ◽

pp. 64-67 ◽

Cited By ~ 27

Author(s):

H. Huber ◽

G. A. Ozin

Keyword(s):

Carbon Monoxide ◽

Surface Chemistry ◽

Metal Atom ◽

Silver Surface ◽

Atom Chemistry

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Reactive Matrices; Metal Atom Chemistry and Surface Chemistry: Dinickel Monethylene, Ni2(C2H4)

Berichte der Bunsengesellschaft für physikalische Chemie ◽

10.1002/bbpc.19780820153 ◽

1978 ◽

Vol 82 (1) ◽

pp. 93-97 ◽

Cited By ~ 5

Author(s):

Geoffrey A. Ozin ◽

William J. Power

Keyword(s):

Surface Chemistry ◽

Metal Atom ◽

Atom Chemistry

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ChemInform Abstract: METAL ATOM CHEMISTRY AND SURFACE CHEMISTRY- (CARBON DIOXIDE)SILVER, AG(CO2). A LOCALIZED BONDING MODEL FOR WEAKLY CHEMISORBED CARBON DIOXIDE ON BULK SILVER

Chemischer Informationsdienst ◽

10.1002/chin.197837312 ◽

1978 ◽

Vol 9 (37) ◽

Author(s):

G. A. OZIN ◽

H. HUBER ◽

D. MCINTOSH

Keyword(s):

Carbon Dioxide ◽

Surface Chemistry ◽

Metal Atom ◽

Bulk Silver ◽

Atom Chemistry

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ChemInform Abstract: METAL ATOM CHEMISTRY AND SURFACE CHEMISTRY. 2. CARBONYLSILVER(I) SUPEROXIDE (OC)AG+,O2-, A LOCALIZED BONDING MODEL FOR CARBON MONOXIDE ON AN OXIDIZED SILVER SURFACE

Chemischer Informationsdienst ◽

10.1002/chin.197712037 ◽

1977 ◽

Vol 8 (12) ◽

pp. no-no

Author(s):

H. HUBER ◽

G. A. OZIN

Keyword(s):

Carbon Monoxide ◽

Surface Chemistry ◽

Metal Atom ◽

Silver Surface ◽

Atom Chemistry

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ChemInform Abstract: Metal Atom Chemistry. (η5-Cyclopentadienyl)metal and (η6-Arene) metal Fragments as Building Blocks for Transition Metal Clusters

ChemInform ◽

10.1002/chin.199745296 ◽

2010 ◽

Vol 28 (45) ◽

pp. no-no

Author(s):

J. J. SCHNEIDER

Keyword(s):

Transition Metal ◽

Metal Atom ◽

Metal Clusters ◽

Building Blocks ◽

Transition Metal Clusters ◽

Atom Chemistry ◽

Cyclopentadienyl Metal

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BONDING NATURE OF INTERCALATION COMPOUNDS M1/3TiS2 (M=TRANSITION-METAL ATOM, SILVER ATOM, ALKALI-METAL ATOM)

International Journal of Modern Physics B ◽

10.1142/s0217979293000792 ◽

1993 ◽

Vol 07 (01n03) ◽

pp. 374-378 ◽

Cited By ~ 1

Author(s):

Naoshi SUZUKI ◽

Tatsuya TESHIMA ◽

Kazuko MOTIZUKI

Keyword(s):

Transition Metal ◽

Alkali Metal ◽

Metal Atom ◽

Silver Atom ◽

Alkali Metal Atom ◽

Intercalation Compounds ◽

Energy Calculation ◽

Covalent Bonds ◽

Total Energy Calculation ◽

Cohesive Properties

Self-consistent LAPW band calculations have been carried out systematically for intercalation compounds M 1/3 TiS 2 (M=transition metal, silver, alkali metal) in order to clarify bonding nature between the guest atoms and the host TiS 2. In transition-metal intercalates the guest 3d states hybridize with the S 3p states as well as the Ti 3d states. As the result covalent bonds are formed between the guest 3d and S 3p states, conserving the covalent bonds between the Ti 3d and S 3p states of the host. In Ag 1/3 TiS 2 the Ag 4d states hybridize strongly with the S 3p state and destroy the host covalent bonds between the Ti 3d and S 3p states. In Li 1/3 TiS 2 and K 1/3 TiS 2 there is little hybridization between the guest 2s or 4s states and the host Ti 3d or S 3p states. Cohesive properties of M 1/3 TiS 2 compounds, including stacking structures of the guest atoms, are discussed on the basis of the total energy calculation.

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