Some metal halide-phosphorus halide-alkyl halide complexes. 4. Bis(tert-butyltrichlorophosphonio)tri-.mu.-chloro-hexachloro-triangulo-trirhenium(III) hexachlororhenate(IV)

1976 ◽  
Vol 15 (8) ◽  
pp. 2003-2005 ◽  
Author(s):  
Joseph I. Bullock ◽  
Frederick W. Parrett ◽  
Nicholas J. Taylor
Keyword(s):  
Alkyl Halide ◽  
Metal Halide ◽  
Halide Complexes

Some Metal Halide – Phosphorus Halide – Alkyl Halide Complexes. Part III. The µ-Trihalohexahalodimetallate Ions of Titanium and Zirconium

1974 ◽  
Vol 52 (16) ◽  
pp. 2880-2888 ◽  
Author(s):  
Joseph I. Bullock ◽  
Frederick W. Parrett ◽  
Nicholas J. Taylor
Keyword(s):  
Vibrational Spectroscopy ◽  
Titanium Tetrachloride ◽  
Alkyl Halide ◽  
Metal Halide ◽  
The Other ◽  
Butyl Chloride ◽  
Halide Complexes ◽  
Titanium Tetrabromide

Titanium tetrachloride reacts rapidly with trichloro-, tribromo- and methyldichlorophosphine in the presence of t-butyl chloride to give compounds containing a phosphonium cation R1R2PX2+ (R1 = t-butyl, R2 = chloride, bromide, or methyl, X = chloride or bromide) and the principal metal-containing anion, Ti2Cl9−. For tribromophosphine and t-butyl chloride a stoichiometric product, [ButPBr3][Ti2Cl9] was obtained which was characterized using vibrational spectroscopy. The other reactions gave non-stoichiometric materials, the sublimates of which may contain higher polymeric anions whilst the residues contained TiCl5− along with the parent dimeric anion.Zirconium tetrachloride and titanium tetrabromide reacted in a similar way to give the new ions Zr2Cl9− and Ti2Br9− in stoichiometric reactions.

scholarly journals The Stability of Metal Halide Complexes in Aqueous Solution. III. The Chloride, Bromide, and Iodide Complexes of Bismuth.

1957 ◽  
Vol 11 ◽  
pp. 1111-1130 ◽  
Author(s):  
Sten Ahrland ◽  
Ingmar Grenthe ◽  
Olof Theander ◽  
J. Schliack ◽  
L. Reio
Keyword(s):  
Aqueous Solution ◽  
Metal Halide ◽  
Halide Complexes ◽  
The Stability

Far-Infrared Spectra of Kaolinite/Alkali Metal Halide Complexes

1997 ◽  
pp. 211-212
Author(s):  
Kirk H. Michaelian ◽  
Kelly L. Akers ◽  
Shuliang L. Zhang ◽  
Shmuel Yariv ◽  
Isaak Lapides
Keyword(s):  
Alkali Metal ◽  
Infrared Spectra ◽  
Far Infrared ◽  
Alkali Metal Halide ◽  
Metal Halide ◽  
Halide Complexes ◽  
Far Infrared Spectra
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