Substitution Reactions of Oxalato Complex Ions. XI. Kinetics of the Anation of Aquopentaamminecobalt(III) Ion by Oxalate in Aqueous Acidic Solution

Rudi. van Eldik; Gordon M. Harris

doi:10.1021/ic50154a062

Substitution Reactions of Oxalato Complex Ions. XI. Kinetics of the Anation of Aquopentaamminecobalt(III) Ion by Oxalate in Aqueous Acidic Solution

Inorganic Chemistry ◽

10.1021/ic50154a062 ◽

1975 ◽

Vol 14 (12) ◽

pp. 3138-3138

Author(s):

Rudi. van Eldik ◽

Gordon M. Harris

Keyword(s):

Acidic Solution ◽

Complex Ions ◽

Substitution Reactions ◽

Aqueous Acidic Solution ◽

Kinetics Of

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Substitution reactions of oxalato complex ions. XI. Kinetics of the anation of aquopentaamminecobalt(III) ion by oxalate in aqueous acidic solution

Inorganic Chemistry ◽

10.1021/ic50143a003 ◽

1975 ◽

Vol 14 (1) ◽

pp. 10-14 ◽

Cited By ~ 35

Author(s):

Rudi. Van Eldik ◽

Gordon M. Harris

Keyword(s):

Acidic Solution ◽

Complex Ions ◽

Substitution Reactions ◽

Aqueous Acidic Solution ◽

Kinetics Of

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ChemInform Abstract: SUBSTITUTION REACTIONS OF OXALATO COMPLEX IONS PART 11, KINETICS OF THE ANATION OF AQUOPENTAAMMINECOBALT(III) ION BY OXALATE IN AQUEOUS ACIDIC SOLUTION

Chemischer Informationsdienst ◽

10.1002/chin.197511426 ◽

1975 ◽

Vol 6 (11) ◽

Author(s):

RUDI VAN ELDIK ◽

GORDON M. HARRIS

Keyword(s):

Acidic Solution ◽

Complex Ions ◽

Substitution Reactions ◽

Aqueous Acidic Solution ◽

Kinetics Of

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Substitution reactions of oxalato complex ions. 12. Kinetics of the anation of diaquobis(ethylenediamine)cobalt(III) ion by oxalate in aqueous acidic solution. Nitrate ion catalysis of a cobalt(III) substitution reaction

Inorganic Chemistry ◽

10.1021/ic50197a055 ◽

1979 ◽

Vol 18 (7) ◽

pp. 1997-2001 ◽

Cited By ~ 18

Author(s):

Rudi Van Eldik ◽

Gordon M. Harris

Keyword(s):

Substitution Reaction ◽

Acidic Solution ◽

Complex Ions ◽

Substitution Reactions ◽

Nitrate Ion ◽

Aqueous Acidic Solution ◽

Kinetics Of

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ChemInform Abstract: SUBSTITUTION REACTIONS OF OXALATO COMPLEX IONS. 12. KINETICS OF THE ANATION OF DIAQUOBIS(ETHYLENEDIAMINE)COBALT(III) ION BY OXALATE IN AQUEOUS ACIDIC SOLUTION. NITRATE ION CATALYSIS OF A COBALT(III) SUBSTITUTION REACTION

Chemischer Informationsdienst ◽

10.1002/chin.197942324 ◽

1979 ◽

Vol 10 (42) ◽

Author(s):

R. VAN ELDIK ◽

G. M. HARRIS

Keyword(s):

Substitution Reaction ◽

Acidic Solution ◽

Complex Ions ◽

Substitution Reactions ◽

Nitrate Ion ◽

Aqueous Acidic Solution ◽

Kinetics Of

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The kinetics of the anation reaction of aquopentaamminecobalt(III) by formate in aqueous acidic solution

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)85751-5 ◽

1975 ◽

Vol 14 ◽

pp. 259-262 ◽

Cited By ~ 15

Author(s):

P.R. Joubert ◽

R. Van Eldik

Keyword(s):

Acidic Solution ◽

Aqueous Acidic Solution ◽

Kinetics Of ◽

Anation Reaction

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Substitution reactions of oxalato complex ions. VI. The kinetics of the anation reaction of cis-bis(oxalato)diaquochromium(III) ion with oxalate ion in aqueous solution

Inorganic Chemistry ◽

10.1021/ic50050a015 ◽

1967 ◽

Vol 6 (4) ◽

pp. 706-711 ◽

Cited By ~ 26

Author(s):

Hartwig Kelm ◽

Gordon McLeod Harris

Keyword(s):

Aqueous Solution ◽

Complex Ions ◽

Substitution Reactions ◽

Kinetics Of ◽

Oxalate Ion ◽

Anation Reaction

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The Kinetics of the Anation Reaction of Aquopentaamminerhodium(III) lon by Oxalate in Aqueous Acidic Solution

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.19754160111 ◽

1975 ◽

Vol 416 (1) ◽

pp. 88-96 ◽

Cited By ~ 5

Author(s):

R. van Eldik

Keyword(s):

Acidic Solution ◽

Aqueous Acidic Solution ◽

Kinetics Of ◽

Anation Reaction

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ChemInform Abstract: THE KINETICS OF THE ANATION REACTION OF AQUOPENTAAMMINECOBALT(III) BY ACETATE IN AQUEOUS ACIDIC SOLUTION

Chemischer Informationsdienst ◽

10.1002/chin.197519370 ◽

1975 ◽

Vol 6 (19) ◽

Author(s):

P. R. JOUBERT ◽

R. VAN ELDIK

Keyword(s):

Acidic Solution ◽

Aqueous Acidic Solution ◽

Kinetics Of ◽

Anation Reaction

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ChemInform Abstract: KINETICS OF THE ANATION OF DIAQUABIS(ETHYLENEDIAMINE)COBALT(III) BY OXALIC ACID IN AQUEOUS ACIDIC SOLUTION. PRESSURE AND MEDIUM EFFECTS

Chemischer Informationsdienst ◽

10.1002/chin.198133296 ◽

1981 ◽

Vol 12 (33) ◽

Author(s):

R. VAN ELDIK

Keyword(s):

Oxalic Acid ◽

Acidic Solution ◽

Medium Effects ◽

Aqueous Acidic Solution ◽

Kinetics Of

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Volumes of activation for the aquation of Co(NH3)5Cl2+ and Cr(NH3)5NCS2+ complex ions in solution

Canadian Journal of Chemistry ◽

10.1139/v70-149 ◽

1970 ◽

Vol 48 (6) ◽

pp. 910-912 ◽

Cited By ~ 9

Author(s):

D. L. Gay ◽

Robert Nalepa

Keyword(s):

Acidic Solution ◽

Complex Ions ◽

Aqueous Acidic Solution

The volumes of activation for the aquation of Co(NH3)5Cl2+ and Cr(NH3)5NCS2+ in aqueous acidic solution (0.1 M HClO4) have been measured and found to be −7.5 ± 1 and −8.6 ± 1 ml/mole, respectively. These values are more consistent with an SN1 than an SN2 pathway for the aquation of both of these complexes.

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