X-ray photoelectron spectra of inorganic molecules.  X.  Binding energy shifts within the series of metal-metal bonded dimers Re2X6-n(PR3)2+n, where X = chlorine or bromine and n = 0, 1, or 2

J. R. Ebner; R. A. Walton

doi:10.1021/ic50151a062

X-ray photoelectron spectra of inorganic molecules. X. Binding energy shifts within the series of metal-metal bonded dimers Re2X6-n(PR3)2+n, where X = chlorine or bromine and n = 0, 1, or 2

Inorganic Chemistry ◽

10.1021/ic50151a062 ◽

1975 ◽

Vol 14 (9) ◽

pp. 2289-2291 ◽

Cited By ~ 21

Author(s):

J. R. Ebner ◽

R. A. Walton

Keyword(s):

Binding Energy ◽

Photoelectron Spectra ◽

X Ray ◽

Metal Metal ◽

Inorganic Molecules

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Binding energy shifts in the x-ray photoelectron spectra of a series of related Group IVa compounds

The Journal of Physical Chemistry ◽

10.1021/j100626a023 ◽

1973 ◽

Vol 77 (7) ◽

pp. 964-969 ◽

Cited By ~ 208

Author(s):

Wayne E. Morgan ◽

John R. Van Wazer

Keyword(s):

Binding Energy ◽

Photoelectron Spectra ◽

X Ray ◽

Group Iva ◽

Related Group

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X-ray photoelectron spectra of inorganic molecules XXlX. The characterization of mixed phosphido-phosphine and phosphido-phosphite complexes of transition metal carbonyl clusters using X-ray photoelectron spectroscopy

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(00)81880-x ◽

1980 ◽

Vol 202 (4) ◽

pp. C105-C107 ◽

Cited By ~ 8

Author(s):

Jay K. Kouba ◽

Janelle L. Pierce ◽

Richard A. Walton

Keyword(s):

Transition Metal ◽

Photoelectron Spectroscopy ◽

Metal Carbonyl ◽

Photoelectron Spectra ◽

Carbonyl Clusters ◽

X Ray ◽

Metal Carbonyl Clusters ◽

Inorganic Molecules

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X-ray photoelectron spectra of inorganic molecules—XV[1,2]. Complexes of thallium(III) chloride

Journal of Inorganic and Nuclear Chemistry ◽

10.1016/0022-1902(77)80079-1 ◽

1977 ◽

Vol 39 (3) ◽

pp. 549-550 ◽

Cited By ~ 6

Author(s):

R.A. Walton

Keyword(s):

Photoelectron Spectra ◽

X Ray ◽

Inorganic Molecules

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X-ray photoelectron spectra of inorganic molecules. 12. Chlorine 2p binding energies of dinuclear chloro anions and mononuclear chloro cations of the transition metals

Inorganic Chemistry ◽

10.1021/ic50166a014 ◽

1976 ◽

Vol 15 (12) ◽

pp. 3014-3018 ◽

Cited By ~ 26

Author(s):

J. R. Ebner ◽

D. L. McFadden ◽

D. R. Tyler ◽

R. A. Walton

Keyword(s):

Transition Metals ◽

Binding Energies ◽

Photoelectron Spectra ◽

X Ray ◽

Inorganic Molecules

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ChemInform Abstract: THE X-RAY PHOTOELECTRON SPECTRA OF INORGANIC MOLECULES PART 7, MANGANESE COMPLEXES OF NITROGEN AND OXYGEN DONOR MOLECULES

Chemischer Informationsdienst ◽

10.1002/chin.197348383 ◽

1973 ◽

Vol 4 (48) ◽

pp. no-no

Author(s):

J. SHEETS ◽

D. G. TISLEY ◽

R. A. WALTON

Keyword(s):

Photoelectron Spectra ◽

Manganese Complexes ◽

X Ray ◽

Oxygen Donor ◽

Inorganic Molecules

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X-ray photoelectron spectra of inorganic molecules. 28. Sulfur 2p binding energies of molybdenum complexes believed to contain a coordinated partial disulfide bond

Inorganic Chemistry ◽

10.1021/ic50219a058 ◽

1981 ◽

Vol 20 (5) ◽

pp. 1614-1616 ◽

Cited By ~ 11

Author(s):

W. S. Mialki ◽

E. I. Stiefel ◽

A. E. Bruce ◽

R. A. Walton

Keyword(s):

Disulfide Bond ◽

Binding Energies ◽

Photoelectron Spectra ◽

Molybdenum Complexes ◽

X Ray ◽

Inorganic Molecules

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The x-ray photoelectron spectra of inorganic molecules. 24. Satellite structure in the x-ray photoelectron spectra of metal complexes of alkyl isocyanides

Journal of the American Chemical Society ◽

10.1021/ja00512a075 ◽

1979 ◽

Vol 101 (18) ◽

pp. 5453-5454 ◽

Cited By ~ 7

Author(s):

Patrick Brant ◽

William S. Mialki ◽

Richard A. Walton

Keyword(s):

Metal Complexes ◽

Photoelectron Spectra ◽

Satellite Structure ◽

X Ray ◽

Alkyl Isocyanides ◽

Inorganic Molecules

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The X-ray photoelectron spectra of inorganic molecules. XI1. Fluorine 1s binding energies in metal fluorides

Journal of Solid State Chemistry ◽

10.1016/s0022-4596(76)80016-3 ◽

1976 ◽

Vol 17 (4) ◽

pp. 447-449 ◽

Cited By ~ 10

Author(s):

J.R. Ebner ◽

D.L. McFadden ◽

R.A. Walton

Keyword(s):

Binding Energies ◽

Photoelectron Spectra ◽

X Ray ◽

Metal Fluorides ◽

Inorganic Molecules

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X-ray photoelectron spectra of inorganic molecules. 22. Halogen core electron binding energies of low oxidation state molybdenum bromide and molybdenum iodide clusters and niobium and tantalum chlorides containing the [M6Cl12]n+ cores

Inorganic Chemistry ◽

10.1021/ic50192a063 ◽

1979 ◽

Vol 18 (2) ◽

pp. 484-488 ◽

Cited By ~ 24

Author(s):

S. A. Best ◽

R. A. Walton

Keyword(s):

Oxidation State ◽

Binding Energies ◽

Photoelectron Spectra ◽

Core Electron ◽

X Ray ◽

Low Oxidation State ◽

Inorganic Molecules ◽

Electron Binding Energies ◽

Electron Binding

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X-Ray Photoelectron Spectroscopic Studies of Palladium Dispersed on Carbon Surfaces Modified by Ion Beams and Plasmatic Oxidation

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19950383 ◽

1995 ◽

Vol 60 (3) ◽

pp. 383-392 ◽

Cited By ~ 18

Author(s):

Zdeněk Bastl

Keyword(s):

Binding Energy ◽

Photoelectron Spectroscopy ◽

Surface Coverage ◽

Spectroscopic Studies ◽

Core Level ◽

Graphite Surface ◽

Photoelectron Spectra ◽

Surface Layers ◽

X Ray ◽

Core Level Binding Energy

The effects of ion bombardment and r.f. plasma oxidation of graphite surfaces on subsequent growth and electronic properties of vacuum deposited palladium clusters have been investigated by methods of X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy with X-ray excitation (XAES). Due to the significantly increased density of surface defects on which the nucleation process occurs the bulk value of the Pd 3d core level binding energy is achieved at higher surface coverage by palladium on bombarded surfaces than on ordered graphite. Angle resolved photoelectron spectra of oxidized graphite surfaces reveal significant embedding of oxygen in graphite surface layers. The C 1s and O 1s photoelectron spectra are consistent with presence of two major oxygen species involving C-O and C=O type linkages which are not homogeneously distributed within the graphite surface layers. Two effects were observed on oxidized surfaces: an increase of palladium dispersion and interaction of the metal clusters with surface oxygen groups. Using the simple interpretation of the modified Auger parameter the relaxation and chemical shift contributions to the measured Pd core level shifts are estimated. In the region of low surface coverage by palladium the effect of palladium-oxygen interaction on Pd core level binding energy exceeds the effects of increased dispersity.

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