Electron transfer through organic structural units. XVII. Reductions of pentaaminecobalt(III) complexes with hexaammineruthenium(II). Partition of the reduction of carboxylatocobalt(III) complexes into outer- and inner-sphere paths

1974 ◽  
Vol 13 (11) ◽  
pp. 2647-2651 ◽  
Author(s):  
Fu-Ren F. Fan ◽  
Edwin S. Gould
Keyword(s):  
Electron Transfer ◽  
Structural Units ◽  
Inner Sphere

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO2 via Through‐Space Electronic Conjugation

2021 ◽  
Author(s):  
Shelby L. Hooe ◽  
Juan J. Moreno ◽  
Amelia G. Reid ◽  
Emma N. Cook ◽  
Charles Machan
Keyword(s):  
Electron Transfer ◽  
Homogeneous Reduction ◽  
Inner Sphere ◽  
Reduction Of Co2
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