Reactions of gaseous inorganic negative ions. V. Dissociative electron capture and ion-molecule reactions in methylfluorosilanes

1974 ◽  
Vol 13 (6) ◽  
pp. 1491-1495 ◽  
Author(s):  
John G. Dillard
Keyword(s):  
Electron Capture ◽  
Negative Ions ◽  
Dissociative Electron Capture ◽  
Ion Molecule Reactions

Negative Ionen durch Elektronenstoß an einigen organischen Schwefelverbindungen

1966 ◽  
Vol 21 (8) ◽  
pp. 1251-1259 ◽  
Author(s):  
K. Jäger ◽  
A. Henglein
Keyword(s):  
Electron Impact ◽  
Electron Capture ◽  
Chemical Reactions ◽  
Hydrogen Sulphide ◽  
Negative Ions ◽  
Ion Source ◽  
Ionization Efficiency ◽  
Dissociative Electron Capture ◽  
Negative Ion ◽  
Electron Affinities

Negative ion formation by electron impact has been studied in hydrogen sulphide, methylmercaptan, phenylmercaptan, benzylmercaptan, allylmercaptan, dimethylthioether, dimethyldisulphide and diallyldisulpbide. Appearance potentials, ionization efficiency curves and the kinetic energies of negative ions were measured by using a Fox ion source. The energies of various dissociative electron capture processses are discussed and electron affinities of some radicals of the types RS and RS2 are derived. Two chemical reactions of the CH2S- ion with dimethyldisulphide have been detected.

Ion–Molecule Reactions of Negative Ions. I. Negative Ions of Sulfur

1968 ◽  
Vol 48 (5) ◽  
pp. 2349-2352 ◽  
Author(s):  
John G. Dillard ◽  
J. L. Franklin
Keyword(s):  
Negative Ions ◽  
Ion Molecule Reactions

scholarly journals Dissociative and non-dissociative electron capture by keV diatomic molecular ions from noble gases

2009 ◽  
Vol 194 (10) ◽  
pp. 102019
Author(s):  
Nora G Johnson ◽  
Wania Wolff ◽  
A M Sayler ◽  
J McKenna ◽  
B Gaire ◽  
...  
Keyword(s):  
Electron Capture ◽  
Noble Gases ◽  
Molecular Ions ◽  
Dissociative Electron Capture

scholarly journals <i>D</i> region ion-neutral coupled chemistry within a whole atmosphere chemistry-climate model

2016 ◽  
Author(s):  
Tamás Kovács ◽  
John M. C. Plane ◽  
Wuhu Feng ◽  
Tibor Nagy ◽  
Martyn P. Chipperfield ◽  
...  
Keyword(s):  
Climate Model ◽  
Negative Ions ◽  
Reaction Scheme ◽  
Solar Proton ◽  
Proton Event ◽  
Test Case ◽  
Neutral Species ◽  
Ion Molecule Reactions ◽  
D Region ◽  
The Impact

Abstract. This study presents a new ion-neutral chemical model coupled into the Whole Atmosphere Community Climate Model (WACCM). The ionospheric D region (altitudes ~ 50–90 km) chemistry is based on the Sodankylä Ion and Neutral Chemistry (SIC) model, a 1-dimensional model containing 306 ion-neutral and ionrecombination reactions of neutral species, positive and negative ions, and electrons. The SIC mechanism was reduced using the Simulation Error Minimization Connectivity Method (SEM-CM) to produce a reaction scheme of 181 ion-molecule reactions. This scheme describes the concentration profiles at altitudes between 20 km and 120 km of a set of major neutral species (HNO3, O3, H2O2, NO, NO2, HO2, OH, N2O5) and ions (O2+, O4+, NO+, NO+(H2O), O2+(H2O), H+(H2O), H+(H2O)2, H+(H2O)3, H+(H2O)4, O3−, NO2−, O−, O2, OH−, O2−(H2O), O2−(H2O)2, O4−, CO3−, CO3−(H2O), CO4−, HCO3−, NO2−, NO3−, NO3−(H2O), NO3(H2O)2, NO3−(HNO3), NO3−(HNO3)2, Cl−, ClO−), which agree with the full SIC mechanism within a 5 % tolerance. Four 3D model simulations were then performed, using the impact of the January 2005 Solar Proton Event (SPE) on D region HOx and NOx chemistry as a test case of four different model versions: the standard WACCM (no negative ions and a very limited set of positive ions); WACCM-SIC (standard WACCM with the full SIC chemistry of positive and negative ions); WACCM-D (standard WACCM with a heuristic reduction of the SIC chemistry, recently used to examine HNO3 formation following an SPE); and WACCM-rSIC (standard WACCM with a reduction of SIC chemistry using the SEM-CM Method). Standard WACCM misses the HNO3 enhancement during the SPE, while the full and reduced model versions predict significant NOx, HOx and HNO3 enhancements in the mesosphere during solar proton events. The SEM-CM reduction also identifies the important ion-molecule reactions that affect the partitioning of odd nitrogen (NOx), odd hydrogen (HOx), and O3 in the stratosphere and mesosphere.

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