Crystal Structure and Microwave Dielectric Behaviors of Ultra-Low-Temperature Fired x(Ag0.5Bi0.5)MoO4–(1 – x)BiVO4 (0.0 ≤ x ≤ 1.0) Solid Solution with Scheelite Structure

2014 ◽  
Vol 53 (17) ◽  
pp. 9222-9227 ◽  
Author(s):  
Di Zhou ◽  
Li-Xia Pang ◽  
Ze-Ming Qi
2002 ◽  
Vol 17 (5) ◽  
pp. 1112-1117 ◽  
Author(s):  
M. Avdeev ◽  
M. P. Seabra ◽  
V. M. Ferreira

The crystal structure of microwave dielectric ceramics in the (1 − x)La(Mg0.5Ti0.5)O3 (LMT)–xBaTiO3 (BT) (0 ≤ x ≤ 0.9) system has been refined by Rietveld method using x-ray powder diffraction data. LMT and BT were found to form a solid solution in the whole compositional range. The increase of BaTiO3 content results in the following sequence of structure transformations of those solid solutions: P21/n (a−a−c+, B-site ordered) → Pbnm (a−a−c+) → I4/mcm (a0a0c−) → Pm3m (a0a0a0). These structural changes are related to the disappearance of B-site cation ordering (x > 0.1), in-phase tilting (x > 0.3), and antiphase tilting (x > 0.5), respectively.


2017 ◽  
Vol 748 ◽  
pp. 137-142 ◽  
Author(s):  
Fei Wang ◽  
Chun Feng Yao ◽  
Qun Zeng ◽  
He Zhou ◽  
Zhi Yong Zhou

In this article, the low-firing Li2+xNb3xTi1-4xO3(x = 0.01, 0.02, 0.04, 0.06) ceramics with monoclinic structure have been obtained by the traditional solid solution method and their microwave dielectric properties were investigated in detail. The ceramics were finely densified at lower temperatures around 1100 °C and demonstrated favorable dielectric performances including relatively low permittivities (εr) ranging from 19 to 24, high Q×f values up to 60,000 GHz (fres = 7.89GHz) and small temperature coefficients of the resonate frequency (for x = 0.02, τf = 10.4 ppm/ °C; x = 0.06, τf = -11.5 ppm/ °C). Furthermore, the ceramics could be densified at around 900°C with adding low-amount of B2O3. Especially, the 1wt.% B2O3-doped Li2+xNb3xTi1-4xO3 (x = 0.06) ceramics was sintered well-densified at 900°C and presented good microwave dielectric properties with εr ∼ 22.2, Q×f ∼ 44,000 GHz. In addition, these ceramics have luminescence properties, which indicated that the ceramics would be applied in LTCC and/or luminescence applications as new luminescence LTCC (low temperature co-fired ceramics) materials.


1997 ◽  
Vol 12 (6) ◽  
pp. 1437-1440 ◽  
Author(s):  
Hyo-Jong Lee ◽  
Kug-Sun Hong ◽  
In-Tae Kim

The microwave dielectric characteristics and crystal structure of the Zn(NbxTa1−x)2O6 and Mg(NbxTa1−x)2O6 systems have been investigated. It was found that both systems exhibited a morphotropic phase transition. Based on the results it was suggested that permittivity and temperature coefficient of resonant frequency depend more on crystal structure rather than on chemical composition. It was also suggested that a two-phase mixture is better than a solid solution for achieving both high quality factor and good temperature stability.


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