Application of the Donor–Acceptor Concept to Intercept Low Oxidation State Group 14 Element Hydrides using a Wittig Reagent as a Lewis Base

2014 ◽  
Vol 53 (16) ◽  
pp. 8662-8671 ◽  
Author(s):  
Anindya K. Swarnakar ◽  
Sean M. McDonald ◽  
Kelsey C. Deutsch ◽  
Paul Choi ◽  
Michael J. Ferguson ◽  
...  
Keyword(s):  
Oxidation State ◽  
Lewis Base ◽  
Group 14 ◽  
Donor Acceptor ◽  
Low Oxidation State ◽  
State Group ◽  
Wittig Reagent

Transition metal-mediated donor–acceptor coordination of low-oxidation state Group 14 element halides

2016 ◽  
Vol 45 (14) ◽  
pp. 6071-6078 ◽  
Author(s):  
Anindya K. Swarnakar ◽  
Michael J. Ferguson ◽  
Robert McDonald ◽  
Eric Rivard
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Bond Activation ◽  
Main Group ◽  
Group Element ◽  
Group 14 ◽  
Acidic Group ◽  
Main Group Element ◽  
Donor Acceptor ◽  
State Group

The main group element triggered C–H bond activation of a Rh-bound Cp ligand is reported. The key aspect of this transformation is the presence of a highly Lewis acidic Group 14 element site.

New horizons in low oxidation state group 2 metal chemistry

2021 ◽  
Author(s):  
Sjoerd Harder ◽  
Bastian Rösch
Keyword(s):  
Oxidation State ◽  
State Of The Art ◽  
Reducing Agents ◽  
Metal Chemistry ◽  
New Horizons ◽  
Low Valent ◽  
Low Oxidation State ◽  
Group 2 ◽  
State Group

Since the seminal report on Mg in the +I oxidation state in 2007, low-valent complexes featuring a MgI-MgI bond developed from trophy molecules to state-of-the-art reducing agents. Despite increasing interest...

Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

2015 ◽  
Vol 51 (33) ◽  
pp. 7128-7131 ◽  
Author(s):  
Deepak Dange ◽  
Amelia Davey ◽  
Joseph A. B. Abdalla ◽  
Simon Aldridge ◽  
Cameron Jones
Keyword(s):  
Oxidation State ◽  
Reducing Agent ◽  
Amido Group ◽  
Group 15 ◽  
Low Oxidation State ◽  
State Group

The first examples of an amido-distibene and a boryl dibismuthene (see picture) have been prepared by reaction of a lithium boryl complex with extremely bulky amido-group 15 dihalide precursor compounds.

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