Direct evaluation of dipolar nuclear magnetic resonance shifts from single-crystal magnetic susceptibilities. Paramagnetic anisotropy of dichlorobis(triphenylphosphine)cobalt(II) and -nickel(II)

1971 ◽  
Vol 10 (10) ◽  
pp. 2190-2194 ◽  
Author(s):  
William D. Horrocks ◽  
Edward S. Greenberg
1985 ◽  
Vol 40 (2) ◽  
pp. 126-130 ◽  
Author(s):  
N. Weiden ◽  
H. Rager

The angular dependence of the chemical shift of the 29Si nuclear magnetic resonance has been measured in a synthetic single crystal of Mg2SiO4 (space group Pbnm, Z = 4). The measurements were performed at room temperature at a frequency of 39.758 MHz using the FT-NMR technique. The eigenvalues of the shift tensor with respect to 29Si in TMS are δx = - 38.8 ppm, δv = -55.3 ppm and δz = - 95.4 ppm, with the eigenvector y parallel to c and the eigenvector z forming an angle of 7.5° with a. The results show clearly the influence of the individual S i - O bonds on the chemical shift tensor. The chemical shift along the S i -O bond depends in good approximation exponentially on the S i - O bond distance.


2019 ◽  
Vol 90 (4) ◽  
pp. 043903 ◽  
Author(s):  
Tonči Cvitanić ◽  
Marin Lukas ◽  
Mihael S. Grbić

1996 ◽  
Vol 8 (25) ◽  
pp. 4597-4602 ◽  
Author(s):  
Ae Ran Lim ◽  
Sung Ho Choh ◽  
Se Young Jeong

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