Crystal structure, absolute configuration, and circular dichroism of a cobalt(III) complex of an optically active triethylenetetramine homolog, (+)589-trans-((-)589-N,N'-bis((S)-2-amino-3-phenylpropyl)-trans-(R)-1,2-cyclohexanediamine-.delta..lambda..delta.)dichlorocobalt(III) perchlorate

1971 ◽  
Vol 10 (3) ◽  
pp. 558-565 ◽  
Author(s):  
June W. Turley ◽  
Robert G. Asperger
Keyword(s):  
Crystal Structure ◽  
Circular Dichroism ◽  
Absolute Configuration ◽  
Optically Active ◽  
Circular Dichroïsm

(1S,7S)-7-Methyl-6,9-diazatricyclo[6,3,0,01,6]tridecane-5,10-dione, a tricyclic spirodilactam containing non-planar amide groups: Synthesis, NMR, crystal structure, absolute configuration, electronic and vibrational circular dichroism

1988 ◽  
Vol 53 (11) ◽  
pp. 2447-2472 ◽  
Author(s):  
Petr Maloň ◽  
C. L. Barness ◽  
Miloš Buděšínský ◽  
Rina K. Dukor ◽  
Dick Van der Helm ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Circular Dichroism ◽  
Absolute Configuration ◽  
Optically Active ◽  
Vibrational Circular Dichroism ◽  
X Ray Diffraction ◽  
X Ray ◽  
Circular Dichroïsm ◽  
C Nmr ◽  
Active Precursor

The title spirocyclic dilactam (1S,7S)-7-methyl-6,9-diazatricyclo[6,3,0,01,6]tridecan-5,10-dione (I), a molecule designed to contain non-planar amide groups, has been synthesized from an optically active precursor of known absolute configuration. The relative and absolute configuration have been determined by X-ray diffraction. The conformation of the compound has been investigated by X-ray, 1H and 13C NMR, electronic and vibrational circular dichroism. The compound possesses moderately non-planar amide groups in the two rings of nonequal geometry. The electronic CD is dominated by inherent chirality of the amide chromophores. The dilactams I and II ((1S,6S)-6-methyl-5,8-diazatricyclo[6,3,0,01,5]undecan-4,9-dione – having five-membered rings) exhibit monosignate amide I VCD and strong VCD bands in the mid-ir region.

Absolute configuration determination of theanti-head-to-head photocyclodimer of anthracene-2-carboxylic acid through cocrystallization withL-prolinol

2013 ◽  
Vol 69 (11) ◽  
pp. 1411-1413 ◽  
Author(s):  
Yuko Kawanami ◽  
Hidekazu Tanaka ◽  
Jun-ichi Mizoguchi ◽  
Nobuko Kanehisa ◽  
Gaku Fukuhara ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Circular Dichroism ◽  
Carboxylic Acid ◽  
Absolute Configuration ◽  
Void Space ◽  
Circular Dichroism Spectra ◽  
The Absolute ◽  
Circular Dichroïsm ◽  
Hydrogen Bonded

The absolute configuration has been established of the enantiopureanti-head-to-head cyclodimer of anthracene-2-carboxylic acid (AC) cocrystallized with L-propinol and dichloromethane [systematic name: (S)-2-(hydroxymethyl)pyrrolidin-1-ium (5R,6S,11R,12S)-8-carboxy-5,6,11,12-tetrahydro-5,12:6,11-bis([1,2]benzeno)dibenzo[a,e][8]annulene-2-carboxylate dichloromethane monosolvate], C5H12NO+·C30H19O4−·CH2Cl2. In the crystal structure, the AC dimer interacts with L-prolinol through a nine-membered hydrogen-bonded ring [R22(9)], while the dichloromethane molecule is incorporated to fill the void space. The absolute configuration determined in this study verifies a recent assignment made by comparing theoreticalversusexperimental circular dichroism spectra.

The optically active 3-ferrocenylalanine and its application in peptide chemistry

1980 ◽  
Vol 45 (2) ◽  
pp. 435-441 ◽  
Author(s):  
Jan Pospíšek ◽  
Štefan Toma ◽  
Ivo Frič ◽  
Karel Bláha
Keyword(s):  
Circular Dichroism ◽  
Aspartic Acid ◽  
Peptide Synthesis ◽  
Absolute Configuration ◽  
Optically Active ◽  
Circular Dichroism Spectra ◽  
Peptide Chemistry ◽  
Conventional Methods ◽  
The Absolute ◽  
Circular Dichroïsm

Racemic 3-ferrocenylalanine was resolved in enantiomers using brucine. The absolute configuration was estimated by ozonolytic degradation of the N-trifluoroacetyl derivative of the (-)-enantiomer yielding D-aspartic acid. Diastereoisomeric cyclo(D-ferrocenylalanyl-L-prolyl) and cyclo-(L-3-ferrocenylalanyl-L-prolyl) were synthesized using conventional methods of peptide synthesis. Circular dichroism spectra of these cyclodipeptides are discussed and compared with spectra of the corresponding diastereoisomeric cyclodipeptides containing phenylalanine.

Novel approach to optically active enone-iron carbonyl complexes. Correlation between their absolute configuration and circular dichroism

1992 ◽  
Vol 11 (12) ◽  
pp. 4268-4275 ◽  
Author(s):  
Bruce R. Bender ◽  
Markus Koller ◽  
Anthony Linden ◽  
Alessandro Marcuzzi ◽  
Wolfgang Von Philipsborn
Keyword(s):  
Circular Dichroism ◽  
Absolute Configuration ◽  
Optically Active ◽  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
Novel Approach ◽  
Circular Dichroïsm

scholarly journals Redetermination and absolute configuration of berkeleydione

2015 ◽  
Vol 71 (4) ◽  
pp. o248-o248 ◽  
Author(s):  
Andrea Stierle ◽  
Donald Stierle ◽  
Daniel Decato
Keyword(s):  
Crystal Structure ◽  
Circular Dichroism ◽  
Absolute Configuration ◽  
Title Compound ◽  
Crystal Packing ◽  
The Absolute ◽  
Circular Dichroïsm

The crystal structure of the title compound, berkeleydione [systematic name; (5aS,7R,9S,11R,11aS)-methyl 9-hydroxy-1,1,5,7,9,11a-hexamethyl-14-methylidene-3,8,10-trioxo-1,3,4,5a,6,7,8,9,10,11,11a,12-dodecahydro-7,11-methanocycloocta[4,5]cyclohepta[1,2-c]pyran-11-carboxylate], C26H32O7, has been reported previously [Stierleet al.(2004).Org. Lett.6, 1049–1052]. However, the absolute configuration could not be determined from the data collected with MoKα radiation and has now been determined by refinement of the Flack parameter with data collected using CuKα radiation. It is in agreement with the previous circular dichroism assignment, and the crystal packing is similar to that described previously.

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