Reversible addition of carbon monoxide to tertiary phosphine complexes of cobalt(II) and their reduction to cobalt(I) carbonyl derivatives

1970 ◽  
Vol 9 (7) ◽  
pp. 1733-1737 ◽  
Author(s):  
Mario Bressan ◽  
Benedetto Corain ◽  
Pierluigi Rigo ◽  
Aldo Turco
Keyword(s):  
Carbon Monoxide ◽  
Tertiary Phosphine ◽  
Carbonyl Derivatives ◽  
Phosphine Complexes ◽  
Reversible Addition

The Stereospecific Synthesis of Neutral and Cationic Tertiary Phosphine Complexes of Platinum(II)

1974 ◽  
Vol 52 (4) ◽  
pp. 692-695 ◽  
Author(s):  
Keith R. Dixon ◽  
Kenneth C. Moss ◽  
Martin A. R. Smith
Keyword(s):  
Synthetic Methods ◽  
Stereospecific Synthesis ◽  
Tertiary Phosphine ◽  
Phosphine Complexes ◽  
Square Planar ◽  
Cleavage Reactions ◽  
Cis And Trans

Stereospecific synthetic methods for the preparation of complexes of the type cis- and trans[PtClL(PEt3)2]+ and cis-[PtClX(PEt3)2] have been developed. Preparations of complexes where L = py, PPh3, PClPh2, or P(OPh)3 and X = SCN, NO2, NO3, N3, NCO, or Br are described and it is shown that bridge cleavage reactions in square planar platinum(II) complexes occur with retention of stereo chemistry.

Sign in / Sign up

Export Citation Format

Share Document