Protonic complexes of oxo ligands with tetrachloroauric acid

1970 ◽  
Vol 9 (5) ◽  
pp. 1284-1286 ◽  
Author(s):  
Richard A. Potts
Keyword(s):  
Oxo Ligands

scholarly journals Dichloridodi-μ2-hydroxido-di-μ3-oxido-octaphenyltetratin(IV) dimethyl sulfoxide disolvate

2013 ◽  
Vol 69 (2) ◽  
pp. m91-m91 ◽  
Author(s):  
Shahrbano Foladi ◽  
Parivash Khazaei ◽  
Jafar Attar Gharamaleki ◽  
Behrouz Notash ◽  
Mohammad Kazem Rofouei
Keyword(s):  
Hydrogen Bonds ◽  
Dimethyl Sulfoxide ◽  
Trigonal Bipyramidal ◽  
Title Molecule ◽  
Solvent Molecules ◽  
Distorted Trigonal Bipyramidal ◽  
Oxo Ligands

In the centrosymmetric tetranuclear title molecule, [Sn4(C6H5)8Cl2O2(OH)2]·2C2H6OS, the two independent tinIVatoms show distorted trigonal–bipyramidal SnC2O3and SnC2O2Cl coordination geometries. The four tinIVatoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn2O2squares. The solvent molecules are linked to the tetranuclear moleculeviaO–H...O hydrogen bonds.

Pentamethylcyclopentadienyl-Vanadium Complexes Containing Halogeno- and Oxo-Ligands

1987 ◽  
Vol 42 (12) ◽  
pp. 1520-1526 ◽  
Author(s):  
Max Herberhold ◽  
Walter Kremnitz ◽  
Markus Kuhnlein ◽  
Manfred L. Ziegler ◽  
Karl Brunn
Keyword(s):  
Crystal Structure ◽  
Mass Spectra ◽  
High Yield ◽  
Vanadium Complexes ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bond Lengths ◽  
Oxygen Bond ◽  
Single Bonds ◽  
Oxo Ligands

AbstractA simple and high-yield preparation of the pentamethylcyclopentadienyl vanadium(IV) trihalides Cp*VX3 (X = CL, Br, I) from Cp*V(CO)4 as well as their conversion into the oxo-vanadium(V) compounds Cp*VOX2 (X = CL, Br) and [Cp*VOX]2(μ-O) (X = CL, Br, I) are described. The equilibrium between the two fluoride species Cp*VOF2 and [Cp*VOF]2(μ-O) has also been investigated. The complexes are characterized by their NMR (51V, l3C, 1H), IR, and mass spectra. The crystal structure of the binuclear chloro-oxo complex [Cp*VOCl]2(μ-O) has been determined by X-ray diffraction. The molecules contain two [Cp*VOCl] units combined via a bent oxo bridge (V-O-V angle of 142.2(2)°). The vanadium-oxygen bond lengths are 157.6(8) and 179.4(1) pm for the terminal and the bridging oxo ligands, respectively, corresponding to double and single bonds.

scholarly journals M(VI) Oxidation State Stabilization in Iron, Cobalt and Nickel Heteroligand Metal Chelates Containing 3,7,11,15-Tetraazaporphine and Two Axial Oxo Ligands: Quantum-Chemical Simulation

2020 ◽  
Vol 21 (4) ◽  
pp. 1494 ◽  
Author(s):  
Oleg V. Mikhailov ◽  
Denis V. Chachkov
Keyword(s):  
Oxidation State ◽  
Quantum Chemical ◽  
Density Functional ◽  
Chemical Elements ◽  
Basis Set ◽  
Chemical Calculation ◽  
Deprotonated Form ◽  
Iron Cobalt ◽  
Cobalt And Nickel ◽  
Oxo Ligands

The quantum-chemical calculation of iron, cobalt and nickel heteroligand complexes with the double deprotonated form of (NNNN)-donor atomic ligand—3,7,11,15-tetraazaporphine—and two oxo ligands has been carried out. Data on the structural and standard thermodynamic parameters, NBO analysis and multiplicity of the ground states of these complexes have been presented. The given calculation has been made by using the density functional theory (DFT) method with the OPBE/TZVP basis set. Based on the results of this calculation, the possibility of the existence of oxidation state VI for the chemical elements indicated above—unusual for iron and cobalt, and for nickel, unknown at all—has been shown.

scholarly journals Organo-gallium and indium complexes with dithiolate and oxo ligands: Synthesis, structures and applications

2011 ◽  
Vol 123 (2) ◽  
pp. 107-112 ◽  
Author(s):  
VIMAL K JAIN ◽  
AMEY WADAWALE ◽  
NISHA P KUSHWAH ◽  
MANOJ K PAL
Keyword(s):  
Indium Complexes ◽  
Oxo Ligands
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