Inner-sphere electron-transfer reactions of cobalt(III). Nonbridging ligand effects, activation energies, and precursor complex formation

1970 ◽  
Vol 9 (1) ◽  
pp. 23-29 ◽  
Author(s):  
Ramesh C. Patel ◽  
Richard E. Ball ◽  
John F. Endicott ◽  
R. Graham Hughes
Keyword(s):  
Electron Transfer ◽  
Complex Formation ◽  
Activation Energies ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Ligand Effects ◽  
Precursor Complex ◽  
Inner Sphere

Single vs double bridging in inner-sphere electron transfer reactions

Polyhedron ◽  
1992 ◽  
Vol 11 (5) ◽  
pp. 517-521 ◽  
Author(s):  
Soontaree Benjarvongkulchai ◽  
Roderick D. Cannon
Keyword(s):  
Electron Transfer ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Inner Sphere

Quantum theory of inner sphere electron transfer reactions

1970 ◽  
Vol 23 (7) ◽  
pp. 1287 ◽  
Author(s):  
PP Schmidt
Keyword(s):  
Electron Transfer ◽  
Transition State ◽  
Bond Formation ◽  
Transfer Reactions ◽  
Reaction Sequence ◽  
Electron Transfer Reactions ◽  
Bond Forming ◽  
Inner Sphere ◽  
Franck Condon ◽  
Activated Complex

This paper reports a theory of inner sphere electron transfer reactions for which, in addition to the electron transfer, there is bond formation and/or destruction. We assume that steps in the reaction sequence which involve bond synthesis take place in intermediate activated complex states. The problem of inner sphere electron transfer is large and complicated. The theory described applies to one aspect of the problem, namely, the dynamics of simultaneous electron transfer and bond break in the transition state complex. However, we assume the intermediate complex exists in steady state equilibrium with the reactants. The theory developed in this paper reveals features important in the unimolecular decay of the transition state. In particular, the importance of the Franck-Condon restrictions on bond forming and breaking steps is demonstrated.

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