Organometallic Compounds with Metal-Metal Bonds. IV. Pentacarbonylmanganese and Pentacarbonylrhenium Derivatives of Silicon, Germanium, Tin, and Lead. Preparation and Infrared and Nuclear Magnetic Resonance Studies

1966 ◽  
Vol 5 (12) ◽  
pp. 2217-2222 ◽  
Author(s):  
W. Jetz ◽  
P. B. Simons ◽  
J. A. J. Thompson ◽  
W. A. G. Graham
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Silicon Germanium ◽  
Organometallic Compounds ◽  
Magnetic Resonance Studies ◽  
Germanium Tin ◽  
Metal Metal ◽  
Metal Bonds ◽  
Derivatives Of ◽  
Nuclear Magnetic

13C Nuclear Magnetic Resonance Studies of Organometallic Compounds. IV. cis-Dimethylplatinum(II) Derivatives

1974 ◽  
Vol 52 (7) ◽  
pp. 1165-1170 ◽  
Author(s):  
Howard Charles Clark ◽  
Leo Ernest Manzer ◽  
John Edward Henry Ward
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Organometallic Compounds ◽  
Methyl Groups ◽  
Magnetic Resonance Studies ◽  
Trans Influence ◽  
13C Nuclear Magnetic Resonance ◽  
Cis And Trans ◽  
Derivatives Of ◽  
Nuclear Magnetic

Data derived from the 13C n.m.r. spectra of seven neutral cis-dimethylplatinum(II) derivatives of the type cis-(CH3)2PtL2 and cis-(CH3)2Pt(L—L) (where L and L—L are neutral donors) are discussed and compared with data derived from the 1H n.m.r. spectra of the complexes. Simultaneous variations in L or L—L reveal that the n.m.r. trans-influence rather than the n.m.r. cis-influence is dominant. The suggestion that the n.m.r. cis- and trans-influences may be additive is discussed. In contrast with data obtained by other workers, it is shown that the 1JCH values of the platinum methyl groups are essentially insensitive to variations in the remaining ligands.

13C Nuclear Magnetic Resonance Studies of Organometallic Compounds. III. cis-Methylplatinum(II) Derivatives

1974 ◽  
Vol 52 (4) ◽  
pp. 570-578 ◽  
Author(s):  
H. C. Clark ◽  
J. E. H. Ward
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Organometallic Compounds ◽  
Neutral Ligand ◽  
Magnetic Resonance Studies ◽  
13C Nuclear Magnetic Resonance ◽  
Related Series ◽  
Cis And Trans ◽  
Derivatives Of ◽  
Nuclear Magnetic

Eight new cis-methylplatinum(II) derivatives of the type DIARSPt(CH3)X (DIARS abbreviates o-phenylenebis(dimethylarsine), where X is an anionic substituent, and [DIARSPt(CH3)L]+PF6−, where L is a neutral ligand, have been prepared. Data derived from the 13C n.m.r. spectra of these complexes are discussed and compared with data derived from the 1H n.m.r. spectra of the complexes. Comparisons with the 13C n.m.r. parameters obtained from related series of trans-methylplatinum(II) derivatives reveal marked differences between the n.m.r. cis- and trans-influences. It appears that the n.m.r. cis-influence may in part be related to a ligand's "steric bulk".

13C Nuclear Magnetic Resonance Studies of Organometallic Compounds. V. Di- and Trimethylplatinum(IV) Derivatives

1974 ◽  
Vol 52 (10) ◽  
pp. 1973-1982 ◽  
Author(s):  
Howard Charles Clark ◽  
Leo Ernest Manzer ◽  
John Edward Henry Ward
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Organometallic Compounds ◽  
Methyl Groups ◽  
Magnetic Resonance Studies ◽  
13C Nuclear Magnetic Resonance ◽  
Cis And Trans ◽  
Nuclear Magnetic

The 13C n.m.r. parameters for thirteen di- and trimethylplatinum(IV) derivatives have been obtained. It is shown that the 13C shieldings and 1JPtC and 2JPtCH values of methyl groups both cis and trans to varied ligands consistently follow trends similar to those found for related methylplatinum(II) derivatives.

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