Metal-Olefin Compounds. VIII. The Crystal Structure of a Norbornadiene-Silver Nitrate Complex, C7H8.2AgNO3

1966 ◽  
Vol 5 (8) ◽  
pp. 1399-1400 ◽  
Author(s):  
N. C. Baenziger ◽  
H. L. Haight ◽  
R. Alexander ◽  
J. R. Doyle
2006 ◽  
Vol 61 (1) ◽  
pp. 6-10 ◽  
Author(s):  
B. Djordjevic ◽  
O. Schuster ◽  
H. Schmidbaur

Bis(p-tolylsulfonylmethylisocyanide)silver nitrate is obtained from the reaction of the isocyanide ligand with silver nitrate in chloroform regardless of the applied ratio of the reactands (1:1 or 2:1). The crystal structure of the product has been determined. In the complex molecule with C2 symmetry, the nitrate anion is attached to the silver center as an η2-chelating ligand. Owing to this approach of the NO3 ligand, the RNC-Ag-CNR axis (R = 4-Me-C6H4-SO2-CH2) is bent [from 180 to 162.1(2)°], but the geometry of the nitrate is not significantly distorted, suggesting only weak coordinative bonding. The structure is thus intermediate between that of a molecular complex with a tetrahedral coordination and that of an ionic compound with linear coordination of the silver center.


1995 ◽  
Vol 5 (6) ◽  
pp. 218-219 ◽  
Author(s):  
Gennadii V. Shustov ◽  
Alexander B. Zolotoi ◽  
Sergei V. Konovalikhin ◽  
Lev O. Atovmyan ◽  
Remir G. Kostyanovsky

1998 ◽  
Vol 14 (2) ◽  
pp. 447-449 ◽  
Author(s):  
Masahiko MAEKAWA ◽  
Megumu MUNAKATA ◽  
Takayoshi KURODA-SOWA ◽  
Yusaku SUENAGA

Polyhedron ◽  
1992 ◽  
Vol 11 (1) ◽  
pp. 49-52 ◽  
Author(s):  
Dalius S. Sagatys ◽  
Raymond C. Bott ◽  
Graham Smith ◽  
Karl A. Byriel ◽  
Colin H.L. Kennard

2000 ◽  
Vol 51 (2) ◽  
pp. 115-123 ◽  
Author(s):  
Xia Li ◽  
Xiangjun Zheng ◽  
Linpei Jin ◽  
Shaozhe Lu ◽  
Shihua Huang

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