Oxygen Atom Transfer in the Oxidation of Aqueous Chromium(II) by Hydrogen Peroxide

1964 ◽  
Vol 3 (10) ◽  
pp. 1470-1472 ◽  
Author(s):  
Lawrence B. Anderson ◽  
Robert A. Plane
Keyword(s):  
Hydrogen Peroxide ◽  
Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

Photooxidation of Methane to Methanol by Perrhenate in Water under Ambient Conditions

2013 ◽  
Vol 68 (8) ◽  
pp. 891-894 ◽  
Author(s):  
Horst Kunkely ◽  
Arnd Vogler
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Oxygen Atom ◽  
Photocatalytic Oxidation ◽  
Atom Transfer ◽  
Ambient Conditions ◽  
Oxygen Atom Transfer ◽  
Oxidation Of Methane

The oxidation of methane to methanol takes place selectively by the photolysis of perrhenate in aqueous solution in the presence of methane. This photoreaction is formally an oxygen atom transfer. Because the reoxidation of the reduced perrhenate is accomplished with hydrogen peroxide the overall process can be viewed as photocatalytic oxidation of methane to methanol: CH4 + H2O2 → CH3OH+ H2O.

scholarly journals Oxygen Atom Transfer Catalysis by Dioxidomolybdenum(VI) Complexes of Pyridyl Aminophenolate Ligands

Polyhedron ◽  
2021 ◽  
pp. 115234
Author(s):  
Md. Kamal Hossain ◽  
Jörg A. Schachner ◽  
Matti Haukka ◽  
Michael G. Richmond ◽  
Nadia C. Mösch-Zanetti ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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