Selective Fluorescence Sensing of Copper(II) and Water via Competing Imine Hydrolysis and Alcohol Oxidation Pathways Sensitive to Water Content in Aqueous Acetonitrile Mixtures

2014 ◽  
Vol 53 (6) ◽  
pp. 2953-2962 ◽  
Author(s):  
Kadarkaraisamy Mariappan ◽  
Madhubabu Alaparthi ◽  
Gerald Caple ◽  
Vinothini Balasubramanian ◽  
Mariah M. Hoffman ◽  
...  
Keyword(s):  
Water Content ◽  
Alcohol Oxidation ◽  
Fluorescence Sensing ◽  
Aqueous Acetonitrile

Anodic behaviour of limonene in low aqueous acetonitrile solutions of Cl−

1988 ◽  
Vol 66 (7) ◽  
pp. 1757-1762 ◽  
Author(s):  
J. A. Caram ◽  
M. E. Martins ◽  
E. G. Gros ◽  
C. M. Marschoff
Keyword(s):  
Water Content ◽  
Aqueous Acetonitrile ◽  
Pt Electrodes ◽  
Acetonitrile Solutions ◽  
Anodic Behaviour ◽  
Derivatives Of ◽  
Reaction Routes

The anodic behaviour of limonene on Pt electrodes was studied in LiCl solutions in acetonitrile with low water content. It was found that cis-6-acetamido-p-menth-1,8-diene is formed with acceptable yields. This compound is of interest as a potential intermediate for obtaining oxidation derivatives of limonene. Other products, among them the new compound 8-acetamido-2,4,8-trimethyl-4-chloromethyl-3-aza-bicyclo[3.3.1]non-2-ene, were identified. Reaction routes are proposed.

Colorimetric and ratiometric fluorescence sensing of water based on 9-methyl pyrido[3,4-b]indole-boron trifluoride complex

2019 ◽  
Vol 48 (6) ◽  
pp. 2086-2092 ◽  
Author(s):  
Toshiaki Enoki ◽  
Yousuke Ooyama
Keyword(s):  
Water Content ◽  
Boron Trifluoride ◽  
Fluorescent Sensor ◽  
High Water ◽  
High Water Content ◽  
Ratiometric Fluorescence ◽  
Fluorescence Sensing ◽  
Water Based ◽  
Ratiometric Fluorescence Sensing ◽  
Boron Trifluoride Complex

9-Methyl pyrido[3,4-b]indole-boron trifluoride complex 9-MP-BF3 was developed as a colorimetric and ratiometric fluorescent sensor for the detection of water from the low- to high-water-content regions in solvents.

ChemInform Abstract: Practical Cu(OAc)2/TEMPO-Catalyzed Selective Aerobic Alcohol Oxidation under Ambient Conditions in Aqueous Acetonitrile.

ChemInform ◽  
2014 ◽  
Vol 45 (32) ◽  
pp. no-no
Author(s):  
Jian-An Jiang ◽  
Jia-Lei Du ◽  
Zhan-Guo Wang ◽  
Zhong-Nan Zhang ◽  
Xi Xu ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Ambient Conditions ◽  
Aqueous Acetonitrile

Practical Cu(OAc)2/TEMPO-catalyzed selective aerobic alcohol oxidation under ambient conditions in aqueous acetonitrile

2014 ◽  
Vol 55 (10) ◽  
pp. 1677-1681 ◽  
Author(s):  
Jian-An Jiang ◽  
Jia-Lei Du ◽  
Zhan-Guo Wang ◽  
Zhong-Nan Zhang ◽  
Xi Xu ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Ambient Conditions ◽  
Aqueous Acetonitrile

Characterization of frozen hydrated biological specimens by low-loss EELS

1992 ◽  
Vol 50 (2) ◽  
pp. 1572-1573
Author(s):  
Songquan Sun ◽  
Richard D. Leapman
Keyword(s):  
Water Content ◽  
Direct Method ◽  
Internal Standard ◽  
Dry Weight ◽  
Dark Field ◽  
Protein Solutions ◽  
Subcellular Compartment ◽  
Differential Shrinkage ◽  
Electron Energy Loss

Analyses of ultrathin cryosections are generally performed after freeze-drying because the presence of water renders the specimens highly susceptible to radiation damage. The water content of a subcellular compartment is an important quantity that must be known, for example, to convert the dry weight concentrations of ions to the physiologically more relevant molar concentrations. Water content can be determined indirectly from dark-field mass measurements provided that there is no differential shrinkage between compartments and that there exists a suitable internal standard. The potential advantage of a more direct method for measuring water has led us to explore the use of electron energy loss spectroscopy (EELS) for characterizing biological specimens in their frozen hydrated state.We have obtained preliminary EELS measurements from pure amorphous ice and from cryosectioned frozen protein solutions. The specimens were cryotransfered into a VG-HB501 field-emission STEM equipped with a 666 Gatan parallel-detection spectrometer and analyzed at approximately −160 C.

STEM measurement of subcellular water distributions

1993 ◽  
Vol 51 ◽  
pp. 568-569
Author(s):  
R.D. Leapman ◽  
S.Q. Sun ◽  
S-L. Shi ◽  
R.A. Buchanan ◽  
S.B. Andrews
Keyword(s):  
Water Content ◽  
Internal Standard ◽  
Dry Weight ◽  
Dry Mass ◽  
Scanning Transmission Electron Microscope ◽  
Dark Field ◽  
Bulk Water ◽  
Inelastic Electron ◽  
Scanning Transmission ◽  
Annular Dark Field

Recent advances in rapid-freezing and cryosectioning techniques coupled with use of the quantitative signals available in the scanning transmission electron microscope (STEM) can provide us with new methods for determining the water distributions of subcellular compartments. The water content is an important physiological quantity that reflects how fluid and electrolytes are regulated in the cell; it is also required to convert dry weight concentrations of ions obtained from x-ray microanalysis into the more relevant molar ionic concentrations. Here we compare the information about water concentrations from both elastic (annular dark-field) and inelastic (electron energy loss) scattering measurements.In order to utilize the elastic signal it is first necessary to increase contrast by removing the water from the cryosection. After dehydration the tissue can be digitally imaged under low-dose conditions, in the same way that STEM mass mapping of macromolecules is performed. The resulting pixel intensities are then converted into dry mass fractions by using an internal standard, e.g., the mean intensity of the whole image may be taken as representative of the bulk water content of the tissue.

EFFECT OF WATER CONTENT ON PROPERTIES OF Na2O, 3SiO2 GLASSES

1982 ◽  
Vol 43 (C9) ◽  
pp. C9-455-C9-458 ◽  
Author(s):  
M. Takata ◽  
M. Tomozawa ◽  
J. Acocella ◽  
J. Molinelli ◽  
C. Y. Erwin ◽  
...  
Keyword(s):  
Water Content ◽  
Effect Of Water
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