Electrocatalytic Hydrogen Evolution from Water by a Series of Iron Carbonyl Clusters

2013 ◽  
Vol 52 (21) ◽  
pp. 12847-12854 ◽  
Author(s):  
An D. Nguyen ◽  
M. Diego Rail ◽  
Maheswaran Shanmugam ◽  
James C. Fettinger ◽  
Louise A. Berben
Keyword(s):  
Hydrogen Evolution ◽  
Iron Carbonyl ◽  
Carbonyl Clusters

scholarly journals Electron Transfer Mediated by Iron Carbonyl Clusters Enhance Light‐Driven Hydrogen Evolution in Water by Quantum Dots

ChemSusChem ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 3252-3260
Author(s):  
Chuanshuai Li ◽  
Ahibur Rahaman ◽  
Weihua Lin ◽  
Hassan Mourad ◽  
Jie Meng ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Electron Transfer ◽  
Hydrogen Evolution ◽  
Iron Carbonyl ◽  
Carbonyl Clusters

Synthesis and reactivity of iron carbonyl clusters containing alkynethiolate ligands

2005 ◽  
Vol 358 (5) ◽  
pp. 1521-1530 ◽  
Author(s):  
Alberto Cabrera ◽  
Esther Delgado ◽  
Cesar Pastor ◽  
Miguel A. Maestro ◽  
Félix Zamora
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Clusters

Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

2011 ◽  
Vol 396-398 ◽  
pp. 2485-2488
Author(s):  
Bao Hua Zhu ◽  
Guo Hua Xu ◽  
Zhi Wei Xia
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Excellent Yield ◽  
Ruthenium Carbonyl ◽  
Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

scholarly journals Structures, Interconversions, and Spectroscopy of Iron Carbonyl Clusters with an Interstitial Carbide: Localized Metal Center Reduction by Overall Cluster Oxidation

2017 ◽  
Vol 56 (13) ◽  
pp. 7575-7575
Author(s):  
Subramaniam Kuppuswamy ◽  
Joshua D. Wofford ◽  
Chris Joseph ◽  
Zhu-Lin Xie ◽  
Azim K. Ali ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Metal Center ◽  
Carbonyl Clusters ◽  
Interstitial Carbide
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