Design of One-Dimensional Coordination Networks from a Macrocyclic {3d-4f} Single-Molecule Magnet Precursor Linked by [W(CN)8]3– Anions

2013 ◽  
Vol 52 (23) ◽  
pp. 13685-13691 ◽  
Author(s):  
Sébastien Dhers ◽  
Humphrey L. C. Feltham ◽  
Rodolphe Clérac ◽  
Sally Brooker
2020 ◽  
Vol 44 (18) ◽  
pp. 7270-7276 ◽  
Author(s):  
Guo Peng ◽  
Yue Chen ◽  
Bo Li

Four one-dimensional lanthanide coordination polymers constructed from Ln2 dimers showing single molecule magnet behavior and photoluminescence are reported.


2018 ◽  
Vol 71 (7) ◽  
pp. 527
Author(s):  
Yufeng Jia ◽  
Hongfeng Li ◽  
Peng Chen ◽  
Ting Gao ◽  
Wenbin Sun ◽  
...  

A series of lanthanide-based self-assembling complexes constructed from Schiff base and β-diketonate ligands have been synthesised by the same method. They are one dimensional complexes ({[Ln(H2L)(tta)2(OAc)]·0.5H2O}n (Ln = Eu (1), Gd (2), Dy (3), Yb (4)); H2L = N,N′-bis(salicylidene)butane-1,4-diamine, tta = 2-thenoyltrifluoroacetone). Complexes 1 and 4 exhibit characteristic metal-centred emission in the solid state. The lifetimes and quantum yields of luminescence were also determined. Magnetic analysis reveals that complex 3 exhibits field-induced single-molecule magnet (SMM) behaviour with an energy barrier of 24.07 K.


2018 ◽  
Vol 98 ◽  
pp. 127-131 ◽  
Author(s):  
Qiao-Qiao Long ◽  
Zhao-Bo Hu ◽  
Hui-Sheng Wang ◽  
Cheng-Ling Yin ◽  
Yong Chen ◽  
...  

Author(s):  
Yunxia Qu ◽  
Ze-Yu Ruan ◽  
Guo-Zhang Huang ◽  
Yan-Cong Chen ◽  
Yang Liu ◽  
...  

One-dimensional (1D) magnetic materials are intriguing due to their low densities, structural and chemical versatility. Herein a Dy(III) coordination polymer with significant single-molecule magnet behaviors has been constructed with strongly...


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