Modeling the Magnetic Properties and Mössbauer Spectra of Multifunctional Magnetic Materials Obtained by Insertion of a Spin-Crossover Fe(III) Complex into Bimetallic Oxalate-Based Ferromagnets

2013 ◽  
Vol 52 (23) ◽  
pp. 13536-13545 ◽  
Author(s):  
S. M. Ostrovsky ◽  
O. S. Reu ◽  
A. V. Palii ◽  
M. Clemente-León ◽  
E. Coronado ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Materials ◽  
Mössbauer Spectra ◽  
Spin Crossover ◽  
Mossbauer Spectra

Towards Molecular Conductors with a Spin-Crossover Phenomenon:Crystal Structures, Magnetic Properties and Mössbauer Spectra of[Fe(salten)Mepepy][M(dmit)2] Complexes

2005 ◽  
Vol 2005 (16) ◽  
pp. 3261-3270 ◽  
Author(s):  
Christophe Faulmann ◽  
Stéphane Dorbes ◽  
Bénédicte Garreau de Bonneval ◽  
Gábor Molnár ◽  
Azzedine Bousseksou ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Mössbauer Spectra ◽  
Spin Crossover ◽  
Molecular Conductors ◽  
Mossbauer Spectra

Mössbauer spectra and magnetic properties of Tm0.65Sr0.35Fe x Mn1 − x O3 (x = 0.3, 0.35, 0.4)

2013 ◽  
Vol 49 (9) ◽  
pp. 939-942
Author(s):  
V. V. Parfenov ◽  
A. V. Pyataev ◽  
I. I. Nig’matullina ◽  
Sh. Z. Ibragimov
Keyword(s):  
Magnetic Properties ◽  
Mössbauer Spectra ◽  
Mossbauer Spectra

Local Spin Configurations of Fe Atoms in Microinhomogeneous PdMnxFe1-x Alloys

2009 ◽  
Vol 152-153 ◽  
pp. 49-53
Author(s):  
V.V. Serikov ◽  
N.M. Kleinerman ◽  
N.V. Volkova ◽  
N.I. Kourov
Keyword(s):  
Magnetic Properties ◽  
Intermetallic Compound ◽  
Curie Temperature ◽  
Mössbauer Spectra ◽  
Ferromagnetic Phase ◽  
Multiphase Medium ◽  
Mossbauer Spectra ◽  
Local Spin ◽  
Ferromagnetic Alloys ◽  
Intermediate Concentration

The Mössbauer spectra of PdMnxFe1-x alloys obtained at 80 K and at 300 K were studied in the 0.2 < x < 0.8 concentration range, in which there realizes a microinhomogeneous multiphase medium formed by isostructure phases of the constituent compositions: ferromagnetic PdFe (ТС=730 К) alloy undergoing atomic ordering and antiferromagnetic PdMn (TN=815 К) intermetallic compound. Magnetic properties studies evidence the presence of a third presumably noncollinear phase with its own ordering temperature lying below the Curie temperature of the ferromagnetic phase in the 0.2 < x < 0.8 concentration range. The Mössbauer spectra at 300 K exhibit a doublet for antiferromagnetic alloys (x > 0.8) and a sextet at Hhf ~350 kOe for ferromagnetic alloys (x < 0.2). In the intermediate concentration range several peaks 0 < Hhf < 350 kOe have been observed in the P(Hhf) curves, which result from microinhomogeneous multiphase state.

Preparation and characterization of iron oxide pillared montmorillonite

Clay Minerals ◽  
1988 ◽  
Vol 23 (4) ◽  
pp. 367-377 ◽  
Author(s):  
D. H. Doff ◽  
N. H. J. Gangas ◽  
J. E. M. Allan ◽  
J. M. D. Coey
Keyword(s):  
Magnetic Properties ◽  
Iron Oxide ◽  
Powder Diffraction ◽  
Mössbauer Spectra ◽  
Pillared Clay ◽  
Cross Linking ◽  
X Ray ◽  
Pillared Montmorillonite ◽  
Mossbauer Spectra

AbstractPillared smectites in which the pillars consist of iron oxide are expected to have interesting and unusual magnetic properties. Several possible routes by which such materials might be made have been investigated, namely intercalation of hydroxy-Fe(III) polycations, mixed hydroxy-Fe(III)/Al polycations, phenanthroline-Fe(II) cations, and trinuclear Fe(III) acetato cations into Na-montmorillonite. Only the last of these yielded a pillared clay (PILC) on calcination. The products have been characterized using X-ray powder diffraction and 57Fe Mössbauer spectroscopy. The precursor Fe-PILC has a d-spacing of 21 Å and expands to 23 Å on solvation with glycol. The calcined Fe-PILC has a d-spacing of 19 Å (gallery height 9·4 Å) and does not expand with glycol, confirming cross-linking of the layers. From Mössbauer spectra at 4·2 K it is estimated that there are of the order of some hundred Fe atoms per pillar.

scholarly journals Manganese/Yttrium Codoped Strontium Nanohexaferrites: Evaluation of Magnetic Susceptibility and Mossbauer Spectra

Nanomaterials ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 24 ◽  
Author(s):  
Munirah Almessiere ◽  
Yassine Slimani ◽  
Hakan Güngüneş ◽  
Abdulhadi Baykal ◽  
S.V. Trukhanov ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Mössbauer Spectra ◽  
Ac Susceptibility ◽  
Sol Gel ◽  
Hyperfine Magnetic Field ◽  
Analytical Techniques ◽  
Magnetic Interactions ◽  
Mossbauer Spectra

Manganese (Mn)- and yttrium (Y)-substituted Sr-nanohexaferrites (MYSNHFs) of composition Sr1−xMnxFe12−xYxO19 (with 0.0 ≤ x ≤ 0.5) were prepared by citrate sol-gel autocombustion method. As-prepared MYSNHFs were characterized via diverse analytical techniques to determine the influence of Mn and Y cosubstitution on their microstructures and magnetic properties. 57Fe Mössbauer spectra of the MYSNHFs were used to evaluate the variation in the line width, isomer shift, quadrupole splitting, and hyperfine magnetic field values. It was shown that the dopant ions could preferentially occupy the 12k, 4f2, and 2b sites. Furthermore, the observed shift in the blocking temperatures of the studied MYSNHFs towards lower values with rising Mn2+ and Y3+ contents was attributed to the overall particles size reduction. Meanwhile, the AC susceptibility of the proposed MYSNHFs revealed that the magnetic interactions were weakened with the increase in dopant contents which was ascribed to the replacement of both Sr2+ and Fe3+ ions by the Mn2+ and Y3+ dopants.

Mössbauer spectra and magnetic properties of iron nitrides

1994 ◽  
Vol 94 (1) ◽  
pp. 2067-2073 ◽  
Author(s):  
Qinian Qi ◽  
K. O'Donnell ◽  
E. Touchais ◽  
J. M. D. Coey
Keyword(s):  
Magnetic Properties ◽  
Mössbauer Spectra ◽  
Iron Nitrides ◽  
Mossbauer Spectra
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