Four Coordination Polymers Based on Identical Eight-Connected Heptanuclear Clusters: Spin Canting, Spin Glass, Antiferromagnetism, and Gas Adsorption

2013 ◽  
Vol 52 (19) ◽  
pp. 11573-11579 ◽  
Author(s):  
Jia Li ◽  
Bao Li ◽  
Peng Huang ◽  
Hai-Yan Shi ◽  
Rong-Bin Huang ◽  
...  
Keyword(s):  
Spin Glass ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Spin Canting

Structural diversity and magnetic properties of six cobalt coordination polymers based on 2,2′-phosphinico-dibenzoate ligand

2016 ◽  
Vol 45 (48) ◽  
pp. 19500-19510 ◽  
Author(s):  
Zhao-Xi Wang ◽  
Lin-Fei Wu ◽  
Xuan Zhang ◽  
Feifei Xing ◽  
Ming-Xing Li
Keyword(s):  
Magnetic Properties ◽  
Spin Glass ◽  
Coordination Polymers ◽  
Magnetic Behavior ◽  
Structural Diversity ◽  
Antiferromagnetic Interaction ◽  
Spin Canting ◽  
1D Chain ◽  
Cobalt Coordination

Six novel cobalt–carboxylate–phosphinate coordination polymers exhibit 1D chain, 2D networks and 3D frameworks. With difference on their structures, the compounds show remarkable magnetic behavior diversity containing spin canting, spin glass, and antiferromagnetic interaction.

Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(ii) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand

CrystEngComm ◽  
2014 ◽  
Vol 16 (22) ◽  
pp. 4783-4795 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debraj Saha ◽  
Dilip Kumar Maity ◽  
Rajdip Dey ◽  
Debajyoti Ghoshal
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Luminescent Properties ◽  
Donor Ligand ◽  
X Ray

Directed adenine functionalization for creating complex architectures for material and biological applications

2017 ◽  
Vol 53 (35) ◽  
pp. 4748-4758 ◽  
Author(s):  
Balaram Mohapatra ◽  
Pratibha Pratibha ◽  
Sandeep Verma
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Bioactive Molecules ◽  
Biological Applications ◽  
Design Strategies ◽  
Feature Article ◽  
Complex Architectures ◽  
Adenine Derivatives

This feature article outlines design strategies for modified adenine derivatives to construct discrete metal complexes, ring-expanded skeletons, coordination polymers, MOFs, and capped nanoparticles, for applications in gas adsorption, as bioimaging agents and as bioactive molecules.

Two Coordination Polymers Constructed from Pentanuclear Zinc Clusters with Triazolate and Benzenecarboxylate Ligands: Selective Gas Adsorption

2018 ◽  
Vol 71 (3) ◽  
pp. 111 ◽  
Author(s):  
Wen-Wen Zhang ◽  
Yu-Ling Wang ◽  
Ying Liu ◽  
Qing-Yan Liu
Keyword(s):  
Porous Structure ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
3D Structure ◽  
Co2 Uptake ◽  
N2 Adsorption ◽  
Carboxylate Oxygen ◽  
Zinc Clusters ◽  
Solvent Molecules ◽  
3D Framework

Reactions of Zn(NO3)2·6H2O with 1,2,4-triazole (Htrz) and 1,3,5-benzenetricarboxylic acid (H3BTC) or 5-sulfoisophthalic acid (5-H3SIP) afforded two coordination polymers, {[Zn5(μ3-OH)2(trz)2(BTC)2(DMF)2]·x(solvent)}n (1) and {[Zn7(trz)8(5-SIP)2(H2O)4]·4(H2O)}n (2). Compound 1 has pentanuclear [Zn5(μ3-OH)2] clusters, which are linked by the triazolate ligands to give a 2D layer. The 2D layer is further bridged by BTC3− ligands to form a 3D framework. The 3D framework of 1 has 1D channels filled by solvent molecules. Desolvated 1 shows a moderate CO2 uptake and high CO2/CH4 and CO2/N2 adsorption selectivities due to its carboxylate oxygen decorated pore environment. Compound 2 contains a rare 3D zinc-triazolate framework constructed from a pentanuclear [Zn5(trz)8] cluster wherein the five zinc atoms are arranged linearly. The 3D zinc-triazolate substructure has 1D open channels filled by 5-SIP3− ligands, which interact with the zinc-triazolate framework through Zn–O bonds, leading to a non-porous 3D structure of 2. Introduction of BTC3− into the zinc-triazolate system gave the porous structure of 1. While a variation of BTC3−, 5-SIP3− was introduced into the zinc-triazolate system yielding a non-porous structure of 2, demonstrating that the secondary ligands play an important role in the formation of the final structures.

Structural diversity, gas adsorption and magnetic properties of three coordination polymers based on a rigid multicarboxylate ligand

CrystEngComm ◽  
2020 ◽  
Vol 22 (42) ◽  
pp. 7046-7053
Author(s):  
Lingling Gao ◽  
Yongjun Bian ◽  
Yuan Tian ◽  
Yongqiang Chen ◽  
Tuoping Hu
Keyword(s):  
Magnetic Properties ◽  
Benzoic Acid ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Structural Diversity ◽  
Acid Ligand

A pictogram: the gas adsorption and magnetic properties of three Co(ii) coordination polymers constructed from 3,5-di(2′,5′-dicarboxylphenyl)benzoic acid ligand have been explored.

Field-induced dynamic magnetic behaviour of a canted weak ferromagnetic chain material

2015 ◽  
Vol 2 (4) ◽  
pp. 403-408 ◽  
Author(s):  
Jun-Liang Liu ◽  
Guo-Zhang Huang ◽  
Ming-Liang Tong
Keyword(s):  
Magnetic Fields ◽  
Spin Glass ◽  
Magnetic Behaviour ◽  
Slow Relaxation ◽  
Spin Canting ◽  
Magnetic Chain ◽  
Ferromagnetic Chain ◽  
Weak Ferromagnetic

A 1-D [MnIII3O] based magnetic chain material amazingly exhibits the coexistence of spin-glass, spin-canting, and metamagnetic behaviours as well as slow relaxation of magnetization under different applied magnetic fields.

Six new coordination polymers based on a tritopic pyridyldicarboxylate ligand: structural, magnetic and sorption properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (33) ◽  
pp. 7790-7801 ◽  
Author(s):  
Tao Ding ◽  
Li-Di Ren ◽  
Xiao-Di Du ◽  
Li Quan ◽  
Zi-Wei Gao ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Adsorption Properties ◽  
Sorption Properties

Using a rigid ligand, pyridine-3,5-bis(phenyl-4-carboxylic) acid, six new coordination polymers have been synthesized and characterized, and their magnetic, photoluminescence and gas adsorption properties have been studied.

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