New Type of Single Chain Magnet: Pseudo-One-Dimensional Chain of High-Spin Co(II) Exhibiting Ferromagnetic Intrachain Interactions

2013 ◽  
Vol 52 (11) ◽  
pp. 6559-6569 ◽  
Author(s):  
V. Tangoulis ◽  
M. Lalia-Kantouri ◽  
M. Gdaniec ◽  
Ch. Papadopoulos ◽  
V. Miletic ◽  
...  
Keyword(s):  
High Spin ◽  
Dimensional Chain ◽  
Single Chain ◽  
One Dimensional ◽  
New Type

scholarly journals Synthesis, Crystal Structure and Magnetic Properties of 1D Chain Complexes Based on Azo Carboxylate Oxime Ligand

2021 ◽  
Vol 7 (7) ◽  
pp. 105
Author(s):  
Min Zeng ◽  
Xi Chen ◽  
Hui-Zhong Kou
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
High Spin ◽  
Magnetic Measurements ◽  
Antiferromagnetic Coupling ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Chain Complexes ◽  
1D Chain ◽  
Oxime Ligand

Two carboxylate-bridged one-dimensional chain complexes, {[MnII(MeOH)2][FeIII(L)2]2}n (1) and {[MnII(DMF)2][MnIII(L)2]2·DMF}n (2) [H2L = ((2-carboxyphenyl)azo)-benzaldoxime], containing a low-spin [FeIII(L)2]− or [MnIII(L)2]− unit were synthesized. Magnetic measurements show that the adjacent high-spin MnII and low-spin MIII ions display weak antiferromagnetic coupling via the syn–anti carboxyl bridges, with J = −0.066(2) cm−1 for complex 1 and J = −0.274(2) cm−1 for complex 2.

Paramagnetic One-dimensional Chain Containing High-spin Manganese Atoms Showing Antiferromagnetic Interaction Through –Pt–Rh–Rh–Pt– Bonds

2021 ◽  
Author(s):  
Kazuhiro Uemura ◽  
Yusuke Aoki ◽  
Atsushi Takamori
Keyword(s):  
High Spin ◽  
Antiferromagnetic Interaction ◽  
Magnetic Interactions ◽  
Dimensional Chain ◽  
One Dimensional ◽  
1D Chain

To exploit the magnetic interactions of multiple metals, heterometallic one-dimensional (1D) chain containing three kinds of metals, Rh, Pt, and Mn, where [Rh2(O2CCH3)4] and [Pt2Mn(piam)4(NH3)4]2+ (piam = pivalamidate) are connected...

[{Mn(salen)CN}n]: The First One-Dimensional Chain with Alternating High-Spin and Low-Spin MnIII Centers Exhibits Metamagnetism

1999 ◽  
Vol 38 (1-2) ◽  
pp. 171-173 ◽  
Author(s):  
Naohide Matsumoto ◽  
Yukinari Sunatsuki ◽  
Hitoshi Miyasaka ◽  
Yuzo Hashimoto ◽  
Dominique Luneau ◽  
...  
Keyword(s):  
High Spin ◽  
Dimensional Chain ◽  
One Dimensional

Adiabatic large polarons in anisotropic molecular crystals

2011 ◽  
Vol 35 (1) ◽  
pp. 15-27
Author(s):  
Zoran Ivić ◽  
Željko Pržulj
Keyword(s):  
Energy Transfer ◽  
Effective Mass ◽  
Molecular Crystals ◽  
Single Chain ◽  
Proper Understanding ◽  
One Dimensional ◽  
Interchain Coupling ◽  
Large Polaron ◽  
The One

Adiabatic large polarons in anisotropic molecular crystals We study the large polaron whose motion is confined to a single chain in a system composed of the collection of parallel molecular chains embedded in threedimensional lattice. It is found that the interchain coupling has a significant impact on the large polaron characteristics. In particular, its radius is quite larger while its effective mass is considerably lighter than that estimated within the one-dimensional models. We believe that our findings should be taken into account for the proper understanding of the possible role of large polarons in the charge and energy transfer in quasi-one-dimensional substances.

scholarly journals Special Finite Elements with Adaptive Strain Field on the Example of One-Dimensional Elements

2021 ◽  
Vol 11 (2) ◽  
pp. 609
Author(s):  
Tadeusz Chyży ◽  
Monika Mackiewicz
Keyword(s):  
Finite Elements ◽  
Strain Field ◽  
Main Idea ◽  
Deformation Field ◽  
Geometrical Parameters ◽  
Single Element ◽  
One Dimensional ◽  
New Type ◽  
Self Adaptation ◽  
Adaptation Method

The conception of special finite elements called multi-area elements for the analysis of structures with different stiffness areas has been presented in the paper. A new type of finite element has been determined in order to perform analyses and calculations of heterogeneous, multi-coherent, and layered structures using fewer finite elements and it provides proper accuracy of the results. The main advantage of the presented special multi-area elements is the possibility that areas of the structure with different stiffness and geometrical parameters can be described by single element integrated in subdivisions (sub-areas). The formulation of such elements has been presented with the example of one-dimensional elements. The main idea of developed elements is the assumption that the deformation field inside the element is dependent on its geometry and stiffness distribution. The deformation field can be changed and adjusted during the calculation process that is why such elements can be treated as self-adaptive. The application of the self-adaptation method on strain field should simplify the analysis of complex non-linear problems and increase their accuracy. In order to confirm the correctness of the established assumptions, comparative analyses have been carried out and potential areas of application have been indicated.

A new one-dimensional CdIIcoordination polymer with a two-dimensional layered structure incorporating 2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole and benzene-1,2-dicarboxylate ligands

2016 ◽  
Vol 72 (6) ◽  
pp. 480-484 ◽  
Author(s):  
Qiu-Ying Huang ◽  
Xiao-Yi Lin ◽  
Xiang-Ru Meng
Keyword(s):  
Layered Structure ◽  
Room Temperature ◽  
Weak Interactions ◽  
Coordination Geometry ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Heterocyclic Ligand ◽  
Rich Variety ◽  
Solvent Molecules

The N-heterocyclic ligand 2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole (imb) has a rich variety of coordination modes and can lead to polymers with intriguing structures and interesting properties. In the coordination polymercatena-poly[[cadmium(II)-bis[μ-benzene-1,2-dicarboxylato-κ4O1,O1′:O2,O2′]-cadmium(II)-bis{μ-2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole}-κ2N2:N3;κ2N3:N2] dimethylformamide disolvate], {[Cd(C8H4O4)(C11H10N4)]·C3H7NO}n, (I), each CdIIion exhibits an irregular octahedral CdO4N2coordination geometry and is coordinated by four O atoms from two symmetry-related benzene-1,2-dicarboxylate (1,2-bdic2−) ligands and two N atoms from two symmetry-related imb ligands. Two CdIIions are connected by two benzene-1,2-dicarboxylate ligands to generate a binuclear [Cd2(1,2-bdic)2] unit. The binuclear units are further connected into a one-dimensional chain by pairs of bridging imb ligands. These one-dimensional chains are further connected through N—H...O hydrogen bonds and π–π interactions, leading to a two-dimensional layered structure. The dimethylformamide solvent molecules are organized in dimeric pairsviaweak interactions. In addition, the title polymer exhibits good fluorescence properties in the solid state at room temperature.

scholarly journals The magneto-elastica : from self-buckling to self-assembly

2014 ◽  
Vol 470 (2162) ◽  
pp. 20130609 ◽  
Author(s):  
Dominic Vella ◽  
Emmanuel du Pontavice ◽  
Cameron L. Hall ◽  
Alain Goriely
Keyword(s):  
Self Assembly ◽  
Permanent Magnets ◽  
Energy Estimates ◽  
Dimensional Chain ◽  
Elastic Rod ◽  
Straight Chain ◽  
One Dimensional ◽  
Vibration Dynamics ◽  
Magnetic Strength ◽  
A Chain

Spherical neodymium–iron–boron magnets are permanent magnets that can be assembled into a variety of structures owing to their high magnetic strength. A one-dimensional chain of these magnets responds to mechanical loadings in a manner reminiscent of an elastic rod. We investigate the macroscopic mechanical properties of assemblies of ferromagnetic spheres by considering chains, rings and chiral cylinders of magnets. Based on energy estimates and simple experiments, we introduce an effective magnetic bending stiffness for a chain of magnets and show that, used in conjunction with classic results for elastic rods, it provides excellent estimates for the buckling and vibration dynamics of magnetic chains. We then use this estimate to understand the dynamic self-assembly of a cylinder from an initially straight chain of magnets.

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