Octanuclear {Ln(III)8}(Ln = Gd, Tb, Dy, Ho) Macrocyclic Complexes in a Cyclooctadiene-like Conformation: Manifestation of Slow Relaxation of Magnetization in the Dy(III) Derivative

2013 ◽  
Vol 52 (8) ◽  
pp. 4562-4570 ◽  
Author(s):  
Vadapalli Chandrasekhar ◽  
Prasenjit Bag ◽  
Enrique Colacio
Keyword(s):  
Macrocyclic Complexes ◽  
Slow Relaxation

PHASE TRANSFORMATION AND SLOW RELAXATION IN FLUOSILICATES

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-481-C6-481
Author(s):  
J. CHAPPERT ◽  
G. JEHANNO ◽  
F. VARRET
Keyword(s):  
Phase Transformation ◽  
Slow Relaxation

New dinuclear cobalt(II) octaaza macrocyclic complexes with high oxidation redox potentials: Their crystal structure and unusual magnetic properties

2008 ◽  
Vol 361 (9-10) ◽  
pp. 2747-2758 ◽  
Author(s):  
Jayanthi Narayanan ◽  
Alejandro Solano-Peralta ◽  
Víctor Manuel Ugalde-Saldivar ◽  
Roberto Escudero ◽  
Herbert Höpfl ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Macrocyclic Complexes ◽  
Redox Potentials ◽  
High Oxidation

scholarly journals New Radical Cation Salts Based on BDH-TTP Donor: Two Stable Molecular Metals with a Magnetic [ReF6]2− Anion and a Semiconductor with a [ReO4]− Anion

2021 ◽  
Vol 7 (4) ◽  
pp. 54
Author(s):  
Nataliya D. Kushch ◽  
Gennady V. Shilov ◽  
Lev I. Buravov ◽  
Eduard B. Yagubskii ◽  
Vladimir N. Zverev ◽  
...  
Keyword(s):  
Radical Cation ◽  
Low Temperatures ◽  
Ac Susceptibility ◽  
Slow Relaxation ◽  
Organic Radical ◽  
Inorganic Anion ◽  
Distinctive Features ◽  
Metallic Character ◽  
Radical Cation Salts ◽  
Partial Population

Three radical cation salts of BDH-TTP with the paramagnetic [ReF6]2− and diamagnetic [ReO4]− anions have been synthesized: κ-(BDH-TTP)4ReF6 (1), κ-(BDH-TTP)4ReF6·4.8H2O (2) and pseudo-κ″-(BDH-TTP)3(ReO4)2 (3). The crystal and band structures, as well as the conducting properties of the salts, have been studied. The structures of the three salts are layered and characterized by alternating κ-(1, 2) and κ″-(3) type organic radical cation layers with inorganic anion sheets. Similar to other κ-salts, the conducting layers in the crystals of 1 and 2 are formed by BDH-TTP dimers. The partial population of positions of Re atoms and disorder in the anionic layers of 1–3 are their distinctive features. Compounds 1 and 2 show the metallic character of conductivity down to low temperatures, while 3 is a semiconductor. The ac susceptibility of crystals 1 was investigated in order to test the possible slow relaxation of magnetization associated with the [ReF6]2− anion.

A new molecular building blocks: Synthesis, crystal structure, magnetic and spectroscopic properties of Cu(II) and Ni(II) macrocyclic complexes

Polyhedron ◽  
2011 ◽  
Vol 30 (15) ◽  
pp. 2550-2557 ◽  
Author(s):  
Katarzyna Suracka ◽  
Alina Bieńko ◽  
Jerzy Mroziński ◽  
Rafał Kruszyński ◽  
Dariusz Bieńko ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Building Blocks ◽  
Spectroscopic Properties ◽  
Macrocyclic Complexes ◽  
Molecular Building Blocks

Dinuclear Fe(III) Hydroxypropyl-Appended Macrocyclic Complexes as MRI Probes

2021 ◽  
Author(s):  
Didar Asik ◽  
Samira M. Abozeid ◽  
Steven G. Turowski ◽  
Joseph A. Spernyak ◽  
Janet R. Morrow
Keyword(s):  
Macrocyclic Complexes

The effect of the local pH in the slow relaxation of polyaniline

1996 ◽  
Vol 78 (2) ◽  
pp. 131-135 ◽  
Author(s):  
K. Fraoua ◽  
M. Delamar ◽  
C.P. Andrieux
Keyword(s):  
Slow Relaxation ◽  
Local Ph

Investigation of Polymer Relaxation after Deformation by Positron Annihilation

1992 ◽  
Vol 247 ◽  
Author(s):  
Sergey A. Tishin ◽  
Mihail I. Tsapovestsky ◽  
Vladimir A. Tishin ◽  
Vladimir N. Kestelman
Keyword(s):  
Positron Annihilation ◽  
Angular Correlation ◽  
Life Time ◽  
Slow Relaxation ◽  
Dielectric Losses ◽  
Free Film ◽  
Axial Tension ◽  
Polymer Relaxation ◽  
Sample Density ◽  
Nonmonotonic Change

ABSTRACTThe relaxation of polyimid films after the axial tension has been investigated by measuring life-time of positrons and angular correlation of annihilation photons. The nonmonotonic change of mean life-time while relaxing the free film has been found. Two range of changes of positron-sensitive properties can be seen: “rapid” relaxation for 4–5 hours (characterized by reducing life-time of short-lived component) and “slow” relaxation (characterized by reducing the intensity of long-lived component). The results of this investigation have been compared with those of measuring of sample density and dielectric losses. The possible explanations and the- changes of mechanizms of relaxation with the conditions of deformation and “the rest” of polymers are analyzed.

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