From a Cycloheptatrienylzirconium Allyl Complex to a Cycloheptatrienylzirconium Imidazolin-2-iminato “Pogo Stick” Complex with Imido-Type Reactivity

2012 ◽  
Vol 51 (7) ◽  
pp. 4368-4378 ◽  
Author(s):  
Andreas Glöckner ◽  
Thomas Bannenberg ◽  
Constantin G. Daniliuc ◽  
Peter G. Jones ◽  
Matthias Tamm
Keyword(s):  
Allyl Complex

ChemInform Abstract: Synthesis, Structure and Catalytic Activity of a Bimacrocyclic NHC Palladium Allyl Complex.

ChemInform ◽  
2008 ◽  
Vol 39 (52) ◽  
Author(s):  
Ole Winkelmann ◽  
Christian Naether ◽  
Ulrich Luening
Keyword(s):  
Catalytic Activity ◽  
Allyl Complex

Bis[1,3-bis(trimethylsilyl)allyl]cobalt(II), a stable electron-deficient allyl complex

2004 ◽  
Vol 60 (10) ◽  
pp. m507-m508 ◽  
Author(s):  
J. Dominic Smith ◽  
Keith T. Quisenberry ◽  
Timothy P. Hanusa ◽  
William W. Brennessel
Keyword(s):  
Allyl Complex

Ruthenium-catalyzed Asymmetric Dehydrative Allylic Cyclization of Chalcogen 5-Membered Heteroaromatics

Synthesis ◽  
2021 ◽  
Author(s):  
Shinji Tanaka ◽  
Shoutaro Iwase ◽  
Sena Kanda ◽  
Marie Kato ◽  
Yutaro Kiriyama ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Bond Formation ◽  
Selection Method ◽  
Allylic Alcohol ◽  
Hydrogen Bond Formation ◽  
Pyridine Carboxylic Acid ◽  
Bicyclic Compounds ◽  
Allyl Complex ◽  
Pyridine Carboxylic ◽  
High Yields

The asymmetric dehydrative intramolecular allylation reactions of furan and thiophene were performed using a cationic cyclopentadienyl-ruthenium (CpRu) complex of a chiral pyridine carboxylic acid, namely Cl-Naph-PyCOOH. Both furan and thiophene tethered with an allylic alcohol gave the corresponding bicyclic compounds in high yields and enantioselectivities using 0.1–5 mol% of catalyst. The reaction was found to proceed via a similar enantioface selection method mechanism to that previously reported by our group, which involved halogen and hydrogen bond formation, in addition to the generation of an intermediate σ-allyl complex.

scholarly journals Remote rearrangement of the metal center in a (η6-C6Me6)Ru(ii) complex

2015 ◽  
Vol 51 (24) ◽  
pp. 4981-4984 ◽  
Author(s):  
Koichi Takano ◽  
Yousuke Ikeda ◽  
Shintaro Kodama ◽  
Youichi Ishii
Keyword(s):  
Metal Center ◽  
Allyl Complex ◽  
Internal Alkynes ◽  
Metal Migration

Reaction of [(η6-C6Me6)Ru(Ph)(PMe3)]+ with internal alkynes gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an η3-allyl complex was observed.

Ligand exchange and stereodynamics in the cationic palladium(II)–π-allyl complex of 2,2′-bis(pyridyl)-1,1′-binaphthalene, a novel atropisomeric N,N-ligand

2000 ◽  
pp. 1723-1732 ◽  
Author(s):  
Jonathan P. H. Charmant ◽  
Ian A. Fallis ◽  
Neil J. Hunt ◽  
Guy C. Lloyd-Jones ◽  
Martin Murray ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Allyl Complex ◽  
Cationic Palladium

scholarly journals A Highly Asymmetric Gold(III) η 3 ‐Allyl Complex

2019 ◽  
Vol 132 (4) ◽  
pp. 1532-1536 ◽  
Author(s):  
Marte Sofie Martinsen Holmsen ◽  
Ainara Nova ◽  
Sigurd Øien‐Ødegaard ◽  
Richard H. Heyn ◽  
Mats Tilset
Keyword(s):  
Allyl Complex

Synthesis, structure and catalytic activity of a bimacrocylic NHC palladium allyl complex

2008 ◽  
Vol 693 (16) ◽  
pp. 2784-2788 ◽  
Author(s):  
Ole Winkelmann ◽  
Christian Näther ◽  
Ulrich Lüning
Keyword(s):  
Catalytic Activity ◽  
Allyl Complex
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