Tuning of the Spin Distribution between Ligand- and Metal-Based Spin: Electron Paramagnetic Resonance of Mixed-Ligand Molybdenum Tris(dithiolene) Complex Anions

2011 ◽  
Vol 50 (18) ◽  
pp. 8685-8687 ◽  
Author(s):  
Ulrich Fekl ◽  
Biprajit Sarkar ◽  
Wolfgang Kaim ◽  
Marco Zimmer-De Iuliis ◽  
Neilson Nguyen
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Mixed Ligand ◽  
Spin Distribution ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic ◽  
Complex Anions

scholarly journals Preparation and Antibacterial Activity of Mixed Ligand Complexes of Co(II), Ni(II), Cu(II) and Cd(II) Derived from 1-Phenylazo-2-naphthol and Salicylaldehyde

2011 ◽  
Vol 8 (1) ◽  
pp. 43-48
Author(s):  
S. A. I. Sharif ◽  
A. N. El-Tajoury ◽  
A. A. Elamari
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Antibacterial Activity ◽  
Spectral Data ◽  
Electronic Absorption ◽  
Molar Conductance ◽  
Mixed Ligand ◽  
Mixed Ligand Complexes ◽  
Central Metal ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic

The mixed ligand complexes of Co(II), Ni(II), Cu(II) and Cd(II) have been synthesized by using 1-phenylazo-2-naphthol as primary ligand and salicylaldehyde as secondary ligand. All the prepared complexes were identified and confirmed by elemental analyses (C, H and N), molar conductance measurements, infrared, electronic absorption and electron paramagnetic resonance. The elemental analysis data suggest that the stoichiometry of the complexes to be 1:1:1[M: L1: L2] ratio. The molar conductance measurements of the complexes indicate their non-electrolytic nature. The infrared spectral data showed the coordination sites of the free ligand with the central metal ion. The electronic absorption spectral data revealed the existence of an octahedral geometry for Co(II) and Cd(II) complexes and a square planar geometry for Ni(II) and Cu(II) complexes. The electron paramagnetic resonance spectra of the Co(II) and Cu(II) complexes showed the existence a paramagnetic phenomenon and supported their geometrical structures which confirmed by the electronic absorption spectra. The ligands and mixed ligand complexes have been tested on antibacterial activity against three strains of pathogenic bacteria such asEscherichia coli, Staphylococcus aureusandPseudomonas aeruginosa

ELECTRON PARAMAGNETIC RESONANCE STUDIES OF PHASE TRANSITIONS IN KCN

1976 ◽  
Vol 37 (C7) ◽  
pp. C7-241-C7-246 ◽  
Author(s):  
J.P. VON DER WEID ◽  
L.C. SCAVARDA DO CARMO ◽  
R. R. DO SANTOS ◽  
B. KOILLER ◽  
S. COSTA RIBEIRO ◽  
...  
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Phase Transitions ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic
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