Synthesis and Structure of Ruthenium(IV) Complexes Featuring N-Heterocyclic Ligands with an N–H Group as the Hydrogen-Bond Donor: Hydrogen Interactions in Solution and in the Solid State

2011 ◽  
Vol 50 (11) ◽  
pp. 4868-4881 ◽  
Author(s):  
Josefina Díez ◽  
José Gimeno ◽  
Isabel Merino ◽  
Eduardo Rubio ◽  
Francisco J. Suárez
Keyword(s):  
Hydrogen Bond ◽  
Solid State ◽  
Hydrogen Bond Donor ◽  
Heterocyclic Ligands

scholarly journals ‘Frustrated’ hydrogen bond mediated amphiphile self-assembly – a solid state study

CrystEngComm ◽  
2016 ◽  
Vol 18 (37) ◽  
pp. 7021-7028 ◽  
Author(s):  
Laura R. Blackholly ◽  
Helena J. Shepherd ◽  
Jennifer R. Hiscock
Keyword(s):  
Hydrogen Bond ◽  
Solid State ◽  
Self Assembly ◽  
Hydrogen Bond Donor ◽  
System P ◽  
State Study ◽  
Counter Cation ◽  
Self Assembled ◽  
Hydrogen Bonded

The effects of hydrogen bond donor acidity and counter cation within a ‘frustrated’ self-assembled, hydrogen bonded system.

Rage Against Conformity: Ruthenium(ɪɪ) Bisterpyridine Complexes Respond to Crystal Engineering Instructions with Whelming Results

2017 ◽  
Vol 70 (5) ◽  
pp. 529 ◽  
Author(s):  
Hasti Iranmanesh ◽  
Kasun S. A. Arachchige ◽  
William A. Donald ◽  
Niamh Kyriacou ◽  
Chao Shen ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Solid State ◽  
Single Crystal ◽  
Crystal Engineering ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bond Donor ◽  
One Dimensional ◽  
X Ray ◽  
Hydrogen Bonded

Four heteroleptic ruthenium(ii) complexes of 4′-functionalised 2,2′:6′,2′′-terpyridine are reported, along with their solid-state single-crystal X-ray structures. The complexes feature complementary hydrogen-bond donor (phenol) and acceptor (pyridyl) groups designed to assemble into one-dimensional polymers. In one example, the system obeys the programmed instructions to form a one-dimensional, self-complementary hydrogen-bonded polymer. In one other example, a water-bridged hydrogen-bonded polymer is formed. In the remaining two structures, aryl–aryl interactions dominate the intermolecular interactions, and outweigh the contribution of intermolecular hydrogen bonding.

scholarly journals Diversifying molecular and topological space via a supramolecular solid-state synthesis: a purely organic mok net sustained by hydrogen bonds

IUCrJ ◽  
2019 ◽  
Vol 6 (6) ◽  
pp. 1032-1039 ◽  
Author(s):  
Shalisa M. Oburn ◽  
Michael A. Sinnwell ◽  
Devin P. Ericson ◽  
Eric W. Reinheimer ◽  
Davide M. Proserpio ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Solid State ◽  
Topological Space ◽  
Organic Molecule ◽  
Three Dimensional ◽  
Protecting Group ◽  
Hydrogen Bond Donor ◽  
Hydrogen Bond Acceptor ◽  
Structural Requirements ◽  
Donor And Acceptor

A three-dimensional hydrogen-bonded network based on a rare mok topology has been constructed using an organic molecule synthesized in the solid state. The molecule is obtained using a supramolecular protecting-group strategy that is applied to a solid-state [2+2] photodimerization. The photodimerization affords a novel head-to-head cyclobutane product. The cyclobutane possesses tetrahedrally disposed cis-hydrogen-bond donor (phenolic) and cis-hydrogen-bond acceptor (pyridyl) groups. The product self-assembles in the solid state to form a mok network that exhibits twofold interpenetration. The cyclobutane adopts different conformations to provide combinations of hydrogen-bond donor and acceptor sites to conform to the structural requirements of the mok net.

scholarly journals Investigating the solid-state assembly of pharmaceutically-relevant N,N-dimethyl-O-thiocarbamates in the absence of labile hydrogen bonds

CrystEngComm ◽  
2020 ◽  
Vol 22 (48) ◽  
pp. 8290-8298
Author(s):  
Davin Tan ◽  
Zi Xuan Ng ◽  
Rakesh Ganguly ◽  
Yongxin Li ◽  
Han Sen Soo ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Solid State ◽  
Hydrogen Bonds ◽  
Functional Groups ◽  
Labile Hydrogen ◽  
Active Pharmaceutical Ingredients ◽  
Hydrogen Bond Donor ◽  
Pharmaceutical Ingredients

There are many active pharmaceutical ingredients that lack N–H, O–H and S–H hydrogen-bond donor functional groups.

Aliphatic Carboxylic Acid as Hydrogen-Bond Donor for Converting CO2 and Epoxide into Cyclic Carbonate under Mild Conditions

2021 ◽  
Author(s):  
Zheng Wang ◽  
Yajun Wang ◽  
Qianjie Xie ◽  
Zhiying Fan ◽  
Yehua Shen
Keyword(s):  
Hydrogen Bond ◽  
Carboxylic Acid ◽  
Value Added ◽  
Cyclic Carbonate ◽  
Hydrogen Bond Donor ◽  
Title Reaction ◽  
Aliphatic Carboxylic Acid ◽  
Mild Conditions ◽  
Atmospheric Carbon

The coupling of CO2 and epoxide is promising way to reduce atmospheric carbon by converting it into value-added cyclic carbonate. Pursuing efficient catalysts is highly attractive for the title reaction....

Role of the hydrogen bond donor component for a proper development of novel hydrophobic deep eutectic solvents

2019 ◽  
Vol 281 ◽  
pp. 423-430 ◽  
Author(s):  
Matteo Tiecco ◽  
Federico Cappellini ◽  
Francesco Nicoletti ◽  
Tiziana Del Giacco ◽  
Raimondo Germani ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Deep Eutectic Solvents ◽  
Hydrogen Bond Donor

Identifying Selective Host–Guest Interactions Based on Hydrogen Bond Donor–Acceptor Pattern in Functionalized Al-MIL-53 Metal–Organic Frameworks

2013 ◽  
Vol 117 (39) ◽  
pp. 19991-20001 ◽  
Author(s):  
Julia Wack ◽  
Renée Siegel ◽  
Tim Ahnfeldt ◽  
Norbert Stock ◽  
Luís Mafra ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Metal Organic Frameworks ◽  
Hydrogen Bond Donor ◽  
Donor Acceptor ◽  
Metal Organic

Refinement of hydrogen atomic position in a hydrogen bond using a combination of solid-state NMR and computation

2003 ◽  
pp. 2834 ◽  
Author(s):  
Robin K. Harris ◽  
Phuong Y. Ghi ◽  
Robert B. Hammond ◽  
Cai-Yun Ma ◽  
Kevin J. Roberts
Keyword(s):  
Hydrogen Bond ◽  
Solid State ◽  
Solid State Nmr ◽  
Atomic Position
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